Estabilidade de Grupos T-Butil

Esta é uma pré-visualização de arquivo. Entre para ver o arquivo original

CH₃ CH₃ more stable CH₃ 6.25 The axial destabilization energy of the bulky t-butyl group is so large that it is almost H always equatorial. In this compound, when tBu the t-butyl group is equatorial, the methyl group is axial. H 6.26 CH₃ CH₃ CH₃ OH CH₃CH CH₃ OH CHCH₃ CHCH₃ more stable CH₃ CH₃ menthol CH₃ CH₃ CH₃ CH₃CH CH₃ OH OH CHCH₃ OH CH₃CH more stable CH₃ CH₃ neomenthol 91