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Published by: The Australasian Institute of Mining and Metallurgy Ground Floor, 204 Lygon Street, Carlton Victoria 3053, Australia IRON ORE CONFERENCE 2011 11 - 13 JULY 2011 PERTH, WESTERN AUSTRALIA The Australasian Institute of Mining and Metallurgy Publication Series No 6/2011 © The Australasian Institute of Mining and Metallurgy 2011 All papers published in this volume were refereed prior to publication. The Institute is not responsible as a body for the facts and opinions advanced in any of its publications. ISBN 978 1 921522 43 7 Desktop published by: Kylie McShane, Anthony Salerno and Olivia Tet Fong The Australasian Institute of Mining and Metallurgy Compiled on CD ROM by: Visual Image Processing Pty Ltd PO Box 3180 Doncaster East VIC 3109a Keynote Addresses The Roy Hill Project J M F Clout and B Fitzgerald 3 The SNIM Guelb II Project in Mauritania – Process Design Challenges G Cooper, R Lapointe and J Routhier 11 The Benef ts of Computational Modelling in Improving Iron Ore Production and Processing M P Schwarz and P Cleary 17 Dewatering Marra Mamba – Lessons Learned K Sommerville and B Douglas 19 Recent Iron Making Topics in Japan N Takamatsu 21 Developing the West Pilbara Iron Ore Project K Watters, A Priddy and D Ducler des Rauches 27 Development Options for the Eyre Peninsula Magnetite – An Owner’s Perspective J White and B Hammond 29 Environment Overcoming the Challenges of Managing Tailings from Iron Ore Mining in Western Australia D R Anstey and D A Reid 33 Iron Ore Holdings Ltd – Case Study of the Environmental Approval Challenges for an Emerging Junior H Fletcher and J Moro 43 Using X-Ray Diffraction for Grade Control and Minimising Environmental Impact in Iron and Steel Industries U König, L Gobbo and K Macchiarola 49 Exploration New Ore Types from the Cauê Banded Iron Formation, Quadrilátero Ferrífero, Minas Gerais, Brazil – Responses to the Growing Demand L Q Amorim and F F Alkmim 59 From Banded Iron Formation to Iron Ore – Genetic Models and Their Application in Iron Ore Exploration in the Hamersley Province, Western Australia H J Dalstra 73 CONTENTS Exploration continued... (U-Th)/He Geochronology of Channel Iron Deposits, Robe River, Hamersley Province, Australia – Implications for Ore Genesis M Danišík, E R Ramanaidou, N J Evans, B J McDonald, C Mayers and B I A McInnes 83 Contrasting Styles of High-Grade Iron Mineralisation at Weld Range, Western Australia P Duuring and S G Hagemann 87 Discovery and Geology of the McPhee Creek Iron Deposit, Northern Pilbara, Western Australia J D Goldsworthy, R M Joyce, P Bonato and A D'Hulst 93 Realising the Potential of the Boolgeeda Iron Formation – Stratigraphy and Iron Mineralisation at McCamey’s North, Hamersley Province, Western Australia P J Howard and P Darvall 103 Airborne Gravity Gradiometry and Magnetics in the Search for Economic Iron Ore Deposits R Miller and M Dransf eld 109 Microplaty Haematite of the High-Grade Iron Ores – Its Nature and Genesis R C Morris 117 Channel and Detrital Iron Deposits of the Flinders Mines Pilbara Iron Ore A E Petts, G D McDonald and N J Corlis 125 The Tonkolili Iron Ore Deposits, Sierra Leone M S Reston, H T Baker, R D Elvish, C A Reardon and B J W Young 133 Mapping Quartz, Carbonates and Riebeckite in Banded Iron Formation Iron Ore Drill Core Using CSIRO’s TIR-HyLogging System M C Schodlok and E R Ramanaidou 147 Mining In-Pit Crushing and Conveying Bench Operations T Atchison and D Morrison 157 The Use of Integrated Web-Based Solutions in Productivity Improvement P Cooper 165 Performance Enhancing Blends – Concentrator Feed Blending at Iron Magnet M Darvall 173 Identif cation of Shale and Ore Boundaries Using Gaussian Processes K L Silversides, A Melkumyan, D A Wyman and P J Hatherly 179 Research on the Shape and Particle Size Distribution of Caved Ore Mass in Sublevel Caving G J Zhang 185 Ore Characterisation New Innovations in Field Portable X-Ray Fluorescence for the Iron Ore Industry S Bailey 191 Real-Time Image Analysis of Iron Ore Cores and Drill Chips to Complement Spectral Measures T Belligoi, E R Ramanaidou and E Pirard 207 Comparative Study of Iron Ore Characterisation by Optical Image Analysis and QEMSCANTM E Donskoi, J R Manuel, P Austin, A Poliakov, M J Peterson and S Hapugoda 213 Methodology for Selecting Borehole Samples of Iron Ore for Mineral Processing Characterisation G J I Dos Santos and D T Ribeiro 223 Technological Characterisation of West African Iron Ores in Order to Predict their Performance in the Benef ciation Process L Dubron, E Pirard and A Pirson 229 Use of Metallurgical Test Data in Resource Evaluation for Magnetite Deposits J N Farrell and A D Miller 241 Characterisation of Bedded and Channel Iron Ore Deposits Using CSIRO’s HyLoggingTM Systems M Haest, T Cudahy, C Laukamp, E R Ramanaidou, S Gregory, J C Stark and D Podmore 249 Determination of Iron Ore and Gangue Mineral Associations Using Optical and Backscattered Electron Images with Electron Probe Microanalysis S Hapugoda, J R Manuel, M J Peterson and E Donskoi 257 Quantitative X-Ray Mineralogy of Iron Ore and Scales K Knorr and N Yang 265 Geometallurgy and Ore Processing of the Hibbing Taconite Lake Superior-Type Magnetite Taconite Deposit, Mesabi Iron Range, Minnesota, USA J D Lubben, P K Jongewaard and M E Young 271 The Occurrence of Phosphorus and Other Impurities in Australian Iron Ores C M MacRae, N C Wilson, M I Pownceby and P R Miller 281 The Scratch Test – An Attractive Method to Measure the Strength of Iron Ore Material L Mariano, T Richard and E R Ramanaidou 291 Ore Characterisation continued... Real-Time Online Analysis of Iron Ore, Validation of Material Stockpiles and Roll Out for Overall Elemental Balance as Observed in the Khumani Iron Ore Mine, South Africa D Matthews and T du Toit 297 Geochemical Characterisation of Flinders Mines’ Pilbara Iron Mineralisation G D McDonald 307 Nature and Distribution of Gibbsite in Some Western Australian Iron Ores M Paine, E Ryan and P Mackenzie 315 Measurement of Iron Ore Phases R Pax 321 Particle Size Analysis – Optimising Returns in Iron Ore B Stump and B McPherson 323 Occurrence and Mineralogical Association of Phosphorus in Australian Bedded Iron Ore Deposits M A Wells and E R Ramanaidou 331 Ore Reserve Estimation Resource Estimation Using Reverse Circulation and Blasthole Samples in a Bedded Iron Ore Deposit C Boyle 339 Raman I Do – Raman Spectroscopy for the Mineralogical Characterisation of Banded Iron Formation and Iron Ore E R Ramanaidou and M A Wells 345 Application of Optimisation Technology to Resource Planning Within BHP Billiton Iron Ore D Xu, R Pasyar and O Wang 351 Processing Investigation on Collector Optimisation in the Reverse – Iron Ore Flotation M S Cassola and K U Pedain 361 The Integrative Technology of SLon Magnetic Separator and Centrifugal Separator for Processing Oxidised Iron Ores X Dahe 367 The Effect of Seasonal Variations on the Performance of Mineral Processing Plants – A Case Study of Deposit-10/11A Mine of NMDC Ltd S Das, T Anantharaman, T N S Kumar, P K Satpathy and S Bose 373 Processing continued... Use of an Online Elemental Analyser to Optimise the Sinter Process at ThyssenKrupp Steel Europe, Duisburg, Germany C Delwig, H Fettweis, T Schnitzler, S Wienströer, S Ferguson and G Noble 381 Utilisation Technologies for Australian Iron Ore in China D Duan, H Han and S Wu 389 Bio-Benef ciation of Australian Iron Ores – Potential Applications of Indigenous Bacteria for Flotation, Flocculation and Phosphorous Removal R Dwyer, S Rea, W Bruckard and R Holmes 397 Removal of Phosphorous from Australian Iron Ores C I Edwards, M J Fisher-White, R R Lovel and G J Sparrow 403 Understanding Reactions in Iron Ore Pellets A R Firth, J DDouglas and D Roy 413 Thickening at Karara – The Role of Test Work and Innovative Design G Hart 425 Calculating the Value of Iron Ores in Ironmaking and Steelmaking T Honeyands and L Jelenich 431 Innovative Benef ciation of Iron Ore Fines with allf ux® Two Stage Fluidised Bed Classif ers and gaustec® Wet High Intensity Magnetic Separators A Horn and M Wellsted 437 Dephosphorisation of Limonitic Concentrate by Roasting, Acid Leaching and Magnetic Separation K Ionkov, S Gaydardzhiev, A Correa de Araujo, H Kokal, A Pirson and D Bastin 445 Conversion of a Pelletising Induration Furnace from a Haematite to Magnetite Feed R Jones, M Bannear and R Martin 453 A Study into Bonding within Reduced Titanomagnetite-Coal Compacts R J Longbottom, B J Monaghan, S A Nightingale and J G Mathieson 459 Processing continued... The Dispersion of Kaolinite X Ma 471 Investigation of Mixing and Rolling Drum Performance at Port Kembla’s Sinter Machine Through Full-Scale Sampling and Laboratory Scale Experiments D Maldonado, R Davis, S Haehnel, P Drain and J Heslin 475 Process Control Integration into a Brownf elds Iron Ore Plant as Applied to the Khumani Iron Ore Mine D Matthews 485 Expansion of Iron Ore Processing Plant Using a Modular Design Basis as Applied to the Khumani Iron Ore Mine, South Africa D Matthews and T du Toit 491 Alumina Reduction Challenges in the Benef ciation of Low-Grade Haematite Iron Ores N Murthy and B Karadkal 499 Improving the Fluxed Pellets Performance by Hydrated Lime Instead of Bentonite as Binder J Pan, D Q Zhu, M Emrich, T J Chun and H Chen 509 Oversize Reduction Project at the Iron Ore Company of Canada R Pinksen and J P R Proulx 513 Characterisation of Long-Term Scaling Effects of Ceramic Filter Media Used in the Dewatering of Iron Ore R Salmimies, A Häkkinen, J Kallas, B Ekberg, J P Andreassen and R Beck 521 Unlocking the Value in Waste and Reducing Tailngs – Magnetite Production at Ernest Henry Mining J Siliézar, D Stoll and J Twomey 529 In Situ Diffraction Studies of Phase Formation During Iron Ore Sintering N A S Webster, M I Pownceby, I C Madsen, N V Y Scarlett, L Lu and J R Manuel 537 Benef ciation of Low-Grade Haematite Ores D Wei, Z Guan, S Gao, W Liu, C Han and B Cui 545 Fine Sizing in Magnetite Concentration J Wheeler 557 The Product Quality System at Cliffs Natural Resources – Koolyanobbing Iron Ore Operations A L Wills, K F Jupp and T J Howard 563 Improving the Granulating and Sintering Performance by Pretreating Concentrates Using a Roller Press D Q Zhu, J Pan, T J Chun and D Chen 575 Project Development The Central Eyre Iron Project – Process Selection and Design D Connelly and L Ingle 581 Identify, Convert and Sustain – Resource Development in the Pilbara – The Rio Tinto Way G Danckert and J Masterman 589 A Collaborative Approach to Iron Ore Benef ciation at Assmang Khumani Processing Plant S Döpp, T du Toit and D Ziaja 597 Process Development for the Marampa Iron Ore Tailings Project, Sierra Leone P Dunn, M Nevens, J Pease and R Nardi 607 Razorback Iron Ore Project – A New Iron District to Meet the Growing Demand of an Iron Hungry World M Flis, G England and T Thomas 615 Extension Hill Direct Ship Iron Ore Project – Seven Years in the Making R Forster 625 Development of the Hawsons Low-Grade Magnetite R L Koenig and K T Broekman 633 Cape Lambert Upgrade Project S Russell 639 Solomon Iron Deposits – Continued Growth and Development C Simpson, D Storey, D Kepert, R Boyd and N Nitschke 649 Author Index 661 IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 3 INTRODUCTION The Roy Hill iron ore deposit is located in the Chichester Range on the northern side of the Fortescue River valley, in the Pilbara region of Western Australia. The mine area is located approximately 1300 km north of Perth and 100 km north of the regional centre, Newman. The export facility at Port Hedland is located 342 km by rail from the mine. The iron ore occurrences in the Chichester Range were initially identif ed by Broken Hill Propriety Limited (BHP) in the 1950s during a regional search for manganese. The area was mapped and sampled by the Geological Survey of Western Australia in 1959, and after the export embargo on iron ore in Western Australia was lifted in 1960, BHP was granted a Temporary Reserve 3358 in 1964. Following various tenement changes in the deposit area, two exploration licenses granted to BHP in 1991 over the area were relinquished and picked up by Hancock Prospecting Pty Ltd (HPPL) in 1993 and f nally the last tenement was dropped by Hamersley Iron Pty Ltd and picked up by HPPL in 2005. These three tenements comprise the Roy Hill Mining Area and have subsequently been replaced by Mining Leases M 46/518 and M 46/519, granted to Roy Hill on 1 November 2010. HPPL began an initial drilling program in 1993. The systematic evaluation of the deposit has been underway since 2003, with approximately 98 per cent of drilling taking place in that period. A preliminary feasibility study was concluded in August 2008. The bankable feasibility study (BFS) was commissioned in January 2010 and completed in January 2011 by the project owner’s team in conjunction with a team of experienced consultants on behalf of Roy Hill Holdings Pty Ltd (RHH). The Project is 100 per cent owned by RHH, currently a wholly owned subsidiary of HPPL. The following paper outlines the deposit and project details. MINE Geology The Roy Hill deposit is located in the northern part of the Hamersley Basin. The Hamersley Basin is approximately 400 km × 500 km in areal extent and contains up to a 10 km thickness of metasediments and metavolcanics that includes the banded iron formations (BIF) of the Hamersley Group in which the majority of the iron mineralisation has developed (Figure 1). The Hamersley Basin or Mount Bruce Supergroup is a late Archaean to Palaeoproterozoic platformal cover sequence of low grade metamorphosed sedimentary and volcanic rocks which unconformably overlies the mid Archaean granite – greenstone terrain of the Pilbara Craton (Trendall and Blockley, 1970 and Trendall, 1983). The Mount Bruce Supergoup comprises the regionally conformable Fortescue (ca 2770 to 2630 Ma), Hamersley and Turee Creek Groups. The Roy Hill deposit occurs at the base of the Hamersley Group in the Marra Mamba Iron Formation (MMIF), which conformably overlies the Jeerinah Formation at the top of the Fortescue Group (Harmsworth et al , 1990; Thorne and Trendall, 2001) (Figure 2). In the Roy Hill mine area the MMIF is represented by the lowermost Nammuldi Member which consists of pale chert and cherty BIF interbedded with thin shales. The trace shown on the right of the MMIF column in Figure 2 is the characteristic gamma log trace that re f ects the internal shale/tuff horizons within the BIF. The overall structure of the Roy Hill project area is relatively simple with the stratigraphy dipping very gently at 02° to 5º toward the southwest. The Hamersley Group is unconformably overlain by the Oakover Formation, a sequence of younger Tertiary lacustrine carbonate, silcrete and mudstone rocks that and has been deposited in the palaeodrainage of the Fortescue Valley. The Fortescue Valley is mantled by a thick (up to 50 m) blanket of Quaternary f ood plain alluvial sediments, derived from the erosion of the Hamersley and Chichester Ranges. 1. FAusIMM, John Clout and Associates, 41 Hardy Road, Nedlands WA 6009. Email: jmfclout@gmail.com 2. Executive General Manager, Carbon Steel Materials, Hancock Prospecting Pty Ltd, Level 4, 28-42 Ventnor Avenue, West Perth WA 6005. Email: barry.fi tzgerald@royhill.com.au The Roy Hill Project J M F Clout1 and B Fitzgerald2 ABSTRACT The Roy Hill Project is an independent integrated port, rail and mine development in the Pilbara region of Western Australia. The bankablefeasibility study for the project was completed in January 2011 by Roy Hill Holdings Pty Ltd, a wholly owned subsidiary of Hancock Prospecting Pty Ltd. The Project will deliver 55 Mt/a of premium quality iron ore to a rapidly growing market with a mine life of over 27 years. This study is based on exploiting a 1.2 Bt bedded resource of microplaty haematite-rich Marra Mamba, from which 562 Mt of reserves has been delineated to date. A further 1.1 Bt resource of detritals and low grade bedded is proposed to be mined once the bedded high grade resource is depleted. Roy Hill lump and f ne ore products will compete strongly with other Pilbara products. As a low cost producer, Roy Hill is on track to capture four per cent of the global seaborne traded iron ore market. The project decision to proceed is targeted for Q2 2011 to enable f rst ore on ship by Q2 2014. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 J M F CLOUT AND B FITZGERALD 4 FIG 1 - Location of the proposed Roy Hill mine, rail and port facility. TUREE CREEK GROUP FORTESCUE GROUP Boolgeeda Iron Formation H A M ER SL EY G RO U P Woongarra Volcanics Weeli Wolli Formation Marra Mamba Iron Formation Wittenoom Formation Mount Sylvia Formation Mount McRae Shale Joffre Member Whaleback Shale Member Dales Gorge Member Yandicoogina Shale Member Brockman Iron Formation M et re s 0 200 400 600 800 1000 1200 1400 1600 1800 2000 2200 2400 2600 Banded Iron Formation (BIF), cherty BIF Shale 140 Thickness (m) Hamersley Range Natural Gamma Log W it te no om Fo rm at io n Mo un t N ew m an Me m be r Mt M ac Le od Me m be r Na m m ul di M em be r 50 55 Je er in ah Fo rm at io n Ro y H ill Sh ale Mt Tom Price, Mt Whaleback Fe ore deposits M ar ra M am ba Ir on Fo rm at io n W es t A ng ela Me m be r Hope Downs, Mining Area C, Marandoo, West Angelas Iron ore deposits hosted in Marra Mamba Iron Formation Chichester Range Roy Hill, Christmas Creek, Cloudbreak 0 40 Thickness (m) Ro y H ill Sh ale Na m m ul di M em be r W it te no om Fo rm at io n BIF FIG 2 - Stratigraphy of the Hamersley Group (Harmsworth et al, 1990) and the Marra Mamba Iron Formation in the Hamersley Ranges (Lascelles, 2002) versus the Chichester Range stratigraphy adapted from Hannon, Kepert and Clark (2005) and the Roy Hill Iron deposit. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 THE ROY HILL PROJECT 5 Bedded iron mineralisation is restricted to the base of the Nammuldi Iron Formation and varies from 2 m to 44 m thickness, averaging 12 m and 1 km to 7 km wide by 23 km strike length (Figure 3). The mineralisation is f at lying and dips at between two to ten degrees to the south and south west (Figure 4). The central northwest portion of the deposit consists of a well developed, thick low phosphorous microplaty haematite (mplH) (Figure 5) mineralised core that has been overprinted by later supergene martite-brown goethite mineralisation. The northwest and southeast portions of the deposit consist of a dominant subhorizontal sheet of typical supergene martite-brown goethite replacement of BIF with minor amounts of ochreous goethite. Vertical and lateral ore zonation patterns are similar to those described by Clout (2005) and Clout and Simonson (2005) for other Chichester, Marra Mamba and Brockman iron ore deposits. The Roy Hill deposit is believed to be the most well developed mplH mineralisation hosted by the MMIF outside of the large mplH deposits hosted by the Brockman Iron Formation. Mineral resources and ore reserves More than 8700 vertical RC percussion holes have been drilled (over 460 000 metres) plus 269 HQ3 and PQ3 diamond holes (over 8500 metres), largely since 2006 (Figure 3). Typical drill hole spacing varies between 50 m × 50 m to 400 m × 400 m with location of RC drill holes given in Figures 3 and 4. Chemical analysis was by XRF and grade interpolation was by ordinary kriging. The mineral resource statement in Table 1 has been prepared according to the JORC Code (2004). The total resource of 2.3 Bt comprises: 1.2 Bt of low phosphorus +55 per cent Fe cut-off, mainly Marra Mamba bedded iron ore, with some detritals; and 1.1 Bt of 50 - 55 per cent Fe cut-off low-grade detrital and bedded ore resource. As part of the bankable feasibility study, 562 Mt of reserves were de f ned by the independent mining engineers (Coffey Mining), suff cient to support the f rst ten years of mine life (Table 2). The mining study included examination of all key modifying factors including: mining, plant recovery (80 per cent), economic, marketing, legal, environmental, social, and government approval considerations. The conversion factor from indicated and measured resources to reserves was 80 per cent. The resources given in Table 1 are inclusive of the reserves in Table 2. FIG 3 - The Roy Hill deposit. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 J M F CLOUT AND B FITZGERALD 6 Mining The Roy Hill orebody has simple stratigraphy enabling a conventional, low risk drill, blast, load and haul mining strategy. The mineable resource is more than 991 Mt of bedded ore (55 per cent Fe cut off grade) with a strip ratio of 4.56:1. Total material moved will peak at around 340 Mt/a, excluding rehandle, with 63.5 Mt/a of run-of-mine (ROM) fed to the wet process plant. Mining waste will be returned to the pit after the second year of operations, resulting in a smaller footprint for rehabilitation. Primary and secondary crushing will be carried out at three locations near the pit rim, with overland conveying to a 55 kt stockpile at the process plant to minimise haulage costs (Figure 6). Approximately 70 per cent of the mineable reserve is below the water table. A detailed dewatering strategy and water management plan has been developed to ensure dry mining and to provide the necessary process plant water. No geotechnical issues have been identif ed that will impact on pit design. FIG 5 - Refl ected light photomicrograph of microplaty haematite, RHD 005, 25.6 m. Ore type Resource category Cut-off Tonnes (millions) Fe % SiO 2 % Al 2 O 3 % P % Mn % LOI % S % Density (g/cc) Bedded Measured 55% Fe 143 61.2 4.15 2.21 0.067 0.64 4.36 0.041 2.74 Indicated 55% Fe 505 59 6.01 2.92 0.054 0.88 4.69 0.034 2.73 Inferred 55% Fe 440 58.8 5.67 2.86 0.057 0.79 5.42 0.043 2.74 LG Bedded Inferred 55% Fe 15 55.8 9.92 4.82 0.041 0.46 3.83 0.028 2.67 Detrital Indicated 55% Fe 5 56 5.61 4.76 0.042 0.6 7.8 0.046 2.58 Inferred 55% Fe 120 56.2 4.01 4.07 0.053 0.73 9.62 0.06 2.59 Sub-total 55% Fe 1228 58.8 5.51 2.96 0.056 0.8 5.41 0.041 2.72 Bedded Various 50%-55% 160 52.9 11.71 4.48 0.047 1.08 5.61 0.041 2.58 Detrital Various 50%-55% 935 52.5 7.54 5.74 0.053 0.89 9.31 0.058 2.56 Grand total 2323 55.9 6.74 4.18 0.054 0.85 6.99 0.047 2.65 Note: The resource classifi cation for this estimate was prepared according to JORC (2004) TABLE 1 July 2010 Geological Mineral Resource Estimate for Roy Hill. FIG 4 - Cross-section through the Roy Hill Deposit, looking north. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 THE ROY HILL PROJECT 7 Mining will incorporate in-pit blending supported by detailed mine planning and grade control drilling. This will manage grade variability and enable on-spec product to be loaded on trains, using stockpile blending capability only by exception. The Project includes the infrastructure and services to support construction and operations including accom- modation village, airstrip (Figure 6) and power station. Processing Extensive metallurgical testing has been conducted in Australia and overseas to ensure the process f ow sheet has been optimised for both above and below water table ore. Importantly the f ow sheet is based on technology proven both in the Pilbara and internationally and is designed to producelump and f ne ore products. The wet process plant will have a nominal capacity of 63.5 Mt/a dry of ROM to produce 55 Mt/a wet product with an overall dry mass yield of 80 per cent from ROM. Crushed ore from the live coarse ore stockpile is processed at the plant through a wet front end comprising, six wet scrubbers and wet screening into four size fractions (Figure 7). Tertiary crushing and screening produces lump and f nes product. Material less than 1 mm is wet processed and desanded using a f ow sheet similar to that described for the nearby Cloudbreak process plant by Clout and Rowley (2009) (Figure 8). The desanded f ne product is dewatered before transportation to the f nes blended stockpiles. Tailings will be thickened and the slurry pumped to a tailings storage facility. Up to 46 Ml/day of process water will initially be sourced from mine dewatering bores, and later from a remote bore f eld. A product stockyard of six 150 kt stockpiles will deliver blended and sampled lump and f ne products onto trains. Rail The Roy Hill mine will be linked to Port Hedland by a world class 342 km, standard gauge, heavy haul railway with f ve passing loops, marshalling yard, loops both ends and 14 bridges. The railway has been designed for 32 000 tonne trains of 232 ore cars, 40 tonne axle loads and speeds up to 80 kph. The railway will incorporate a best practice moving block signalling and scheduling system, with in-cab signalling and automatic train protection, and electrically controlled pneumatic braking to manage in-train forces. The railway will be managed by a Train Control Centre located in the integrated Remote Operations Centre in Perth. Classifi cation Mineral Reserves Tonnes Fe SiO 2 Al 2 O 3 P Mt % % % % Proved 127.3 61.0 4.24 2.26 0.066 Probable 434.3 58.8 6.10 3.03 0.052 Total 561.6 59.3 5.68 2.86 0.055 TABLE 2 Proved and probable ore reserves as of December 2010, prepared according to JORC (2004). FIG 6 - Proposed Roy Hill mine and infrastructure layout. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 J M F CLOUT AND B FITZGERALD 8 Port The Roy Hill port facilities will include a world class stockyard facility at the Boodarie Industrial Estate in Port Hedland for receiving, stockpiling and exporting Roy Hill products using the 55 Mt/a port capacity allocated to Roy Hill (Figure 9). The port facility will include: A two-cell rotary car dumper with two positioners, capable of unloading more than f ve trains per day. A stockyard with 2.9 Mt live capacity (equivalent to four weeks of shipping) and a further 3.6 Mt of dead capacity. A lump rescreening plant to remove the less than 6.3 mm undersize from the f nal lump product prior to ship loading. A 4 km overland conveyor from the stockyard to wharf and marine facilities at Stanley Point. Fines and lump buffer storage bins are installed to maintain reclaiming operations during hatch changes. Two berth wharf designed to cater for two 206 000 DWT ships. A 12 000 t/h shiploader capable of achieving an average total time in port of 107 hours. The development of the port will require 7.5 Mm3 of dredging and is intended to commence in mid-2011. REMOTE OPERATIONS CENTRE The Roy Hill Project will minimise on site labour by automating plant and equipment, and controlling operations from a Remote Operations Centre (ROC) located near Perth Airport. This will allow full operational integration of the supply chain. Desanding Section of Roy Hill Processing Plant -1mm Fines Up-Current Classifier Product Dewatering Spirals Tailings Product Cyclone Underflow Cyclone Overflow Middling Concentrate Overflow Concentrate Reject Flowsheet options that give grade/yield flexibility FIG 8 - Proposed wet desanding fl ow sheet. FIG 9 - Proposed Roy Hill port stockyard, wharf and berths at Stanley Point, Port Hedland. Fines Desanding At Mine Lump At Mine Fines 40mm Reject 8mm 1mm ROM Tertiary Crush Satellite Crushing Stations Wet screening 63.4M dmtpa 12.7M dmtpa 24.9M dmtpa 25.8M dmtpa Scrubbing 40mm 8mm FIG 7 - Proposed Roy Hill plant fl ow sheet. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 THE ROY HILL PROJECT 9 At the mine, all mobile equipment will be enabled for maximum remote operation and future automation and driverless operation. The design of the railway and control systems allows for early implementation of Automated Train Operation over the next decade. And the majority of port operations will also be automated and controlled remotely from the ROC in Perth. PRODUCT QUALITY Roy Hill lump and f nes are high quality haematite-dominant products, with very competitive iron grade, low contaminant levels and generally better physical characteristics than other Pilbara products (Table 3). The f nal product split on ship has been simulated from detailed drop test conditioning of PQ and 250 mm wide diameter diamond drill core to be 60 per cent f nes and 40 per cent lump. Unlike other Marra Mamba deposits in the Pilbara, Roy Hill f ne ore product is composed largely (~60 per cent) of the premium microplaty haematite ore type rather goethite (Figure 10). Some sections of Roy Hill may be >90 per cent mplH. Considering the large diversity in mineral composition of the Marra Mamba f ne ore products from goethite-dominate to martite-goethite and microplaty haematite rich, it is far easier to compare different Marra Mamba and Brockman products using the ternary composition diagram in Figure 10. PROJECT EXECUTION AND NEXT STEPS A detailed integrated planning schedule has been prepared and the key milestones are shown in Table 4: Funding has been approved for precommitment expenditure to fast track the Project to June 2011, to achieve f rst ore on Production Dry weight % Calcined weight % Product target grades Mt/a (wet) Fe SiO 2 Al 2 O 3 P Mn S LOI total Fe Lump product 24 61.0 4.5 1.8 0.060 0.70 0.040 5.0 64.2 Fines product 31 61.0 4.5 2.2 0.055 0.70 0.035 4.6 63.9 Weighted mean (Lump + Fine) 55 61.0 4.5 2.0 0.057 0.70 0.037 4.8 64.1 TABLE 3 Lump and fi ne ore product target grades. Hematite Hard Brown Goethite Ochreous Goethite 75 50 25 Roy Hill Roy Hill Hematite Brockman N Brockman P MM-W MM-M MM-F CID-Y2 CID-J Brazil-SS Brazil PF FIG 10 – Ternary mineralogy plot for various iron ore products from the Pilbara and Brazil. Note the normative mineralogy has been calculated from assay and normalised to 100 per cent, with goethite abundance calculated from loss on ignition at 375°C and goethite type from polished section microscopy. Precommitment work including orders for long lead items Q1/2 2011 Commencement of dredging works Q2 2011 Project decision to proceed mid 2011* Start of mining operations Q3 2013* First ore shipment Q2 2014* * Subject to timely approvals and weather. TABLE 4 Key milestones of the integrated planning schedule. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 J M F CLOUT AND B FITZGERALD 10 ship Q2 2014. The Roy Hill Project was granted ‘Major Project Status’ by the Commonwealth Government. Project approvals are either in place or well advanced and the few remaining primary approvals are expected to be in place by Q2 2011. SUMMARY The Roy Hill project bankable feasibility study has been completed and early works has commenced in anticipation of a decision to proceed planned for the second half of 2011. The Roy Hill project will be a large exporter of quality low phosphorous lump and f ne ore products. The project will benef t from independent infrastructure from mine to port. ACKNOWLEDGEMENTS Hancock Prospecting Pty Ltd would like to acknowledge the tireless efforts of its current and former employees as well as strategic project partners POSCO and STX of South Korea. Numerous engineering contractors contributed to the bankable feasibility study including mine planning and ore reserves (Coffey Mining),mine process plant (Lycopodium Minerals), rail and port landside (WorleyParsons), mine infrastructure (GHD) and water management (MWH). REFERENCES Clout, J M F, 2005. Iron formation-hosted iron ores in the Hamersley Province of Western Australia, in Proceedings Iron Ore 2005 Conference, pp 9-19 (The Australasian Institute of Mining and Metallurgy: Melbourne). Clout, J M F and Rowley, W G, 2009. The FMG story – From exploration to the third largest iron ore producer in Australia, in Proceedings Iron Ore 2009 Conference, pp 3-10 (The Australasian Institute of Mining and Metallurgy: Melbourne). Clout, J M F and Simonson, B M, 2005. Precambrian iron formations and iron formation-hosted iron ore deposits (eds: J W Hedenquist, J F H Thompson, R J Goldfarb and J P Richards), Economic Geology 100th Anniversary Volume 1905-2005 , pp 643-679 (Society of Economic Geology). Hannon, E, Kepert, D A and Clark, D, 2005. From target generation to two billion tonnes in 18 months – The reinvention of the Chichester Range, in Proceedings Iron Ore 2005 Conference , pp 73-78 (The Australasian Institute of Mining and Metallurgy: Melbourne). Harmsworth, R A, Kneeshaw, M, Morris, R C, Robinson, C J and Shrivastava, P K, 1990. BIF – Derived iron ores of the Hamersley Province, in Geology of the Mineral Deposits of Australia and Papua New Guinea (ed: F E Hughes), pp 617-642 (The Australasian Institute of Mining and Metallurgy: Melbourne). JORC, 2004. Australasian Code for Reporting of Exploration Results, Mineral Resources and Ore Reserves (The JORC Code) [online]. Available from: <http://www.jorc.org> (The Joint Ore Reserves Committee of The Australasian Institute of Mining and Metallurgy, Australian Institute of Geoscientists and Minerals Council of Australia). Lascelles, D, 2002. A new look at old rocks – An alternative model for the origin of in situ iron ore deposits derived from banded iron formation, in Proceedings Iron Ore 2002 , pp 107-125 (The Australasian Institute of Mining and Metallurgy: Melbourne). Thorne, A M and Trendall, A F, 2001. Geology of the Fortescue Group, Hamersley Basin, Western Australia. GSWA, Bull 144. Trendall, A F, 1983. The Hamersley Basin (eds: A F Trendall and R C Morris) Iron-Formation: Facts and Problems, Developments in Precambrian Geology, 6:69-129 (Elsevier). Trendall, A F and Blockley, J G, 1970. The iron formations of the Precambrian Hamersley Group, Western Australia, with special reference to the associated crocidolite, GSWA, Bull 119. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 11 INTRODUCTION The Société Nationale Industriel et Minière (SNIM) is expanding its ore and concentrate production capacity in Mauritania, West Africa. This government-controlled mining company has been in production since 1963 and currently exports some 12 Mt/a. The operations currently consist of mines producing direct shipping ore in three locations TO14, Mahoudat and Rouessa and an open pit magnetite mine and concentrator called Guelb el Rhein. SNIM is presently doubling its magnetite concentrate production at the Guelb el Rhein mine. An existing processing line of 4 Mt/a will have a second parallel production line of the same capacity added. The mine is located some 600 km inland from the Atlantic coast in the heart of the Sahara desert. Electricity is generated at the site using diesel generators fuelled by heavy fuel oil. Water is provided by a borehole fi eld 60 km away. The site is serviced by a heavy haul railway which takes the products to the port of Nouadhibou on the Atlantic coast (Figure 1). The existing magnetite operation uses primary crushing, Aerofall type dry Semi-Autogenous Grinding (SAG) mills, screening at 1.6 mm and magnetic separation to produce a concentrate containing around fi ve per cent silica. The concentrate is transported to the port by a railway owned and operated by SNIM. The original installation has had some additions over the years. A gravity separation plant uses spiral concentrators to recover haematite from portions of the orebody. High pressure grinding rolls (HPGRs) have been added as pebble crushers in the SAG milling circuit. Recently, a wet magnetic separation plant has been added to recover concentrate from fi ne dust collected from the electrostatic precipitators in the Aerofall circuit. The Guelb II project consists of a new processing line to recover magnetite, and will include new stockpiles, tailings disposal facilities and a train loading station. The electricity generation capacity is being increased, a new borehole fi eld is being added and other infrastructure is being added. SNC-Lavalin is managing the Guelb II project as part of an Engineering, Procurement and Construction Management (EPCM) contract. The open pit mine expansion is being managed by SNIM. The ore is a banded iron formation consisting of magnetite, quartz and minor amounts of other minerals. There is some haematite present which is selectively mined for processing separately from the magnetite. The magnetite ore is classifi ed by the operators into two grades – TS1 with a liberation size of >400 microns, and TS2 with a liberation size of <400 microns. The Guelb II project will treat a blend of equal amounts of the two types with a liberation size of 400 microns and 96 per cent of the iron present as magnetite. The properties of the ore are fairly typical with a crushing work index of 10 kWh/t and a ball mill work index of 18 kWh/t. 1. Senior Process Specialist, Metallurgy, Mining and Metallurgy Division, SNC-Lavalin Inc, 455 René Lévesque Boulevard, West Montreal, Quebec H2Z 1Z3, Canada. Email: gordon.cooper@snclavalin.com 2. Process Engineer, Mining and Metallurgy Division, SNC-Lavalin Inc, 455 René Lévesque Boulevard, West Montreal, Quebec H2Z 1Z3, Canada. Email: remi.lapointe@snclavalin.com 3. Project Area Manager, Mining and Metallurgy Division, SNC-Lavalin Inc, 455 René Lévesque Boulevard, West Montreal, Quebec H2Z 1Z3, Canada. Email: jean.routhier@snclavalin.com The SNIM Guelb II Project in Mauritania – Process Design Challenges G Cooper1, R Lapointe2 and J Routhier3 ABSTRACT The Société Nationale Industriel et Minière (SNIM) is expanding its ore and concentrate production capacity in Mauritania, West Africa. This government-controlled mining company has been in production since 1963 and currently exports some 12 Mt/a. SNIM is presently doubling its magnetite concentrate production at the Guelb el Rhein mine. An existing processing line will have a second parallel production line of 4 Mt/a added. The mine is located some 600 km inland from the Atlantic coast in the heart of the Sahara Desert. The metallurgy of the ore is reasonably straightforward. It is a magnetite banded iron formation that is amenable to magnetic separation. While the existing plant uses semi-autogenous grinding and dry magnetic separation, the new processing line will use HPGRs, dry magnetic separation, and a wet milling and magnetic separation circuit for treating middlings. The process choices refl ect the scarcity of water in the region, the high cost of locally generated power and the operating experience and preferences of SNIM. Dust control in the desert environment has been a particular challenge. The metallurgical design aspects as well as the infl uence of the environmental and commercial aspects of the project are presented. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 G COOPER, R LAPOINTE AND J ROUTHIER 12 The plant extends over a distance of 3 km from the primary crusher to the train loading station. The offi cial languages in Mauritania are Arabic and French. The project is being executed in French, and all documentation is in the French language. The project CAPEX is estimated at US$630 M and the iron ore production is scheduled to start in fi rst quarter of 2013. The project offi ce is located in Montreal and a construction site office is located in Zouérate. All process units were procured via an Engineering, Procurement and Services (EPS) contracting packaging strategy. This EPS strategy was imposed by SNIM to maximise the vendor responsibilities during the project engineering, the construction and start-up of the process units. The EPS strategy requires the vendors to validate the design concepts and take responsibility for the detail engineering, to supply the mechanical equipment, some of the bulk materials and instrumentation required for the complete operation of the plant. The EPS packages also include process performance guarantees such as throughput, particle size distribution, silica content, iron content, dust capture, etc for a 72 hour test executed after the mechanical completion phase. The EPS approach was part of the fi nancing strategy considering diffi culties in previous SNIM projects to meet the design performance. The main EPS packages were divided as follows: crushing plant (to an equipment supplier), crush ore stockpile, dry concentrator (to an engineering/integrator fi rm), wet concentrator (to an equipment supplier), concentrate stockpile, reject stockpile, and train loading. A prequalifi cation period of three months was used to evaluate and identify the bidders for each package. Following the request for tender, nine months passed during the procurement cycle of request for bids, evaluation and issuing the purchase orders. All EPS packages include liquidated damages associated with the performance tests and equipment delivery schedules. The EPCM mandate was centred around the pre-engineering required to prepare the EPS tender packages, evaluation, award and contract follow-up and construction management. The EPCM mandate included the civil, structural, electrical, and control systems engineering as per EPS supplier requirements. The EPCM mandate includes the preparation, evaluation, award and management of a single site erection package to build the new Guelb II plant. The objective is to manage the general contractor with an integrated team (SNC-Lavalin and SNIM) under the leadership of SNC-Lavalin. FIG 1 - Project location. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 THE SNIM GUELB II PROJECT IN MAURITANIA – PROCESS DESIGN CHALLENGES 13 An EPC contract was also awarded to extend the existing power plant with two new 10 MW diesel generators. PROCESS SELECTION The main factors affecting the process selection are: dry processing as much as possible to conserve water, SiO 2 limits in concentrate, high electricity cost because of on-site generation, conservative approach by SNIM to new technology, selection of equipment and practices that is familiar to the plant operators, and water quality available from the boreholes. The basic process was established in an early study. After small scale exploratory testing, pilot testing was done on samples of 10 tonnes taken from the mine. The resulting fl ow sheet and design parameters were carried forward to the preliminary design (Figure 2). A primary gyratory crusher and closed-circuit secondary crushing circuit is used to reduce the ore size to less than 50 mm. The HPGRs feed medium intensity magnetic separators (MIMS) to eliminate about 36 per cent of the feed material as tailings. The magnetic fraction is screened at 1.6 mm to recirculate the oversize material to the HPGRs. The minus 1.6 mm material is fed to two stages of low intensity magnetic separators (LIMS) to produce concentrate (34 per cent of feed), tailings (13 per cent of feed), and middlings fraction (17 per cent of feed). The dry concentrator produces about 80 per cent of the concentrate and 80 per cent of the tailings. The middlings fraction goes to a wet ball mill circuit with a 180 micron screen to close the circuit. This feeds 3-stage magnetic separators to produce more concentrate (55 per cent of feed), and tailings (45 per cent of feed). The wet concentrate goes to a storage tank and is then fi ltered on a belt fi lter and joins the dry concentrate. The tailings are thickened and fi ltered on a belt fi lter and joins the dry tailings. The process packages were sent out for bids to qualifi ed vendors along with new samples of ore from the mine. These packages specifi ed the major process equipment types and the circuit confi gurations. Process guarantee specifi cations were included. Given the limited time for bidding and the vendors’ budgets for preparing bids, a very limited amount of metallurgical testing was performed during the tender period by the vendors to provide process guarantees. Consequently the vendor responses were naturally cautious with respect to performance guarantees and equipment sizing. All bids for the dry concentration process provided process guarantees that were subject to further testing. In the case of the dry concentrator, further testing after the contract award produced some different results in the dry concentration circuit. It was found to be diffi cult to respect the performance guarantees and to replicate the results of the initial test work in the dry magnetic separation. Signifi cantly, the MIMS separation on the HPGR product could not reject as much tailings material as the original pilot testing had shown. The fi nishing LIMS stage of the magnetic separation also showed poor results. The original tests produced concentrate with less than 4.7 per cent of silica while the new test results indicate higher than 6.5 per cent of silica. The equipment supplier was unwilling to guarantee the performance of the original fl ow sheet. Another issue is a technical risk in the use of MIMS as compared to the use of LIMS. LIMS equipment is common in the iron ore industry around the world and achieves good effi ciency. LIMS is also used in the existing SNIM plant at Guelb el Rhein. On the other hand, MIMS equipment is still relatively new in this application. FIG 2 - Original fl ow sheet. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 G COOPER, R LAPOINTE AND J ROUTHIER 14 The concentrate quality results can be explained by the fact that the dry magnetic separation is not effi cient for the very fi ne material (less than 50 microns). During the lab tests, dust removal were done many times on the material tested apparently resulting in the removal of high SiO 2 fi nes to the dust collector. In order to avoid contamination of the concentrate by the high level of silica, a re-design was performed. It was decided to add air separators to remove the SiO 2 fi nes and to treat this fi ne material (representing two per cent of the feed) in the wet concentrate plant where wet magnetic separation is effi cient for the fi ne material. In the fi nal fl ow sheet dust will be removed from the material before production of the fi nal concentrate, and this dust will be treated in the wet plant and all magnetic separation will be made by LIMS and no MIMS will be used (Figure 3). The changes to the dry concentration have eliminated the MIMS separation on the HPGR product. The circuit now uses a type of air classifi er on the <1.6 mm screen underfl ow and only uses LIMS in three stages. The HPGR product is screened into three fractions. The fraction over 10 mm is recycled to the HPGR feed bin. The 1.6 - 10 mm fraction passes through a LIMS separator to reject a tailings stream and the magnetic fraction is returned to the HPGR. The minus 1.6 mm fraction goes to rougher, cleaner and scavenger stages of LIMS. The rougher stage rejects a tailings stream. The cleaner stage produces fi nished concentrate and an intermediate stream which is treated in the scavenger stage to produce a middlings stream and more tailings. The fi rst stage magnetic separators are treating material with narrower size ranges than in the original concept. The MIMS in the original design was treating materialranging from fi nes up to nearly 50 mm. This has changed to size ranges of 0 - 1.6 mm and 1.6 - 10 mm. In principle, this should provide better separation. DUST CONTROL Control of dust is a particular concern to SNIM. The existing operation has problems with dust emissions and dust in the workplace environment. There are concerns that have arisen due to silicosis among the employees as a result of the dusty environment in the plant. The main constraints and principles for the design of the dust control system are: minimise the use of water; minimise the amount of regular inspection and maintenance required; avoid returning dust to the dry process system once it has been removed; robust, reliable, easy to maintain; recovery of iron where practical; and separation of parallel production lines. The limit for ambient levels of respirable silica in the workplace as mandated by the World Bank’s International Finance Corporation is 0.025 mg/m3. During strong winds a value of 0.060 mg/m3 has been measured in the region. Higher levels have been measured within the existing plant. The international development banks involved in fi nancing of the project have mandated the adoption of the World Bank standard of 0.025 mg/m3. While the standard is very low compared to the ambient levels in the Sahara desert, the basic principle is that the plant must meet the best international practices. The standard for stack emissions at 50 mg/m3 is not diffi cult to meet. Conventional baghouses can easily meet that performance standard. This emission limit dates back many years and it appears likely that it will be revised downward in the near future. The approach to dust collection design has followed the guidelines for no adjustments and ease of maintenance. This led to the design where there are no control dampers in the system and no more than six pickup points for each baghouse. This is in contrast to the common approach where a large number of collection points are connected to one large baghouse per building. To provide good air fl ow without fl ow control dampers, non- standard duct diameters are used to balance the fl ows between the branches of the system. Flow balancing is therefore achieved at the design stage and is not left to the discretion of the operators. Wherever possible, parallel production lines or pieces of equipment each have their own baghouse. This avoids imbalance of fl ows when one line is out of service. This also permits a baghouse to be serviced when a production line is down for repairs. Welded construction rather than bolted construction is used for baghouses and ductwork. This is to prevent in-leakage in the equipment when it ages and could otherwise loosen up over the long-term due to thermal cycling and vibration. The ductwork design avoids horizontal ducts. All ducts are either sloping up or down at 60o to prevent accumulation of dust along the bottom and the consequent loss in fl ow. This is considered to be the best approach in an environment where routine inspection and cleaning is diffi cult. FIG 3 - Dry concentration – fi nal fl ow sheet. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 THE SNIM GUELB II PROJECT IN MAURITANIA – PROCESS DESIGN CHALLENGES 15 Conveyors are not covered outside of the process buildings. This is a choice by SNIM resulting from past experience. Instead, conveyor speeds are limited to 2.5 m/s. It is accepted that some material may blow off the conveyors during high winds. However, these high winds also carry sand off the desert which is a much larger source of silica in the air. Conveyor transfer points are designed with extended belt skirts and enclosures to permit the material on the belts to settle properly before exiting from the ventilated area. The result of taking this approach is that there are over 60 individual baghouses. Each of these baghouses has a fan and a stack and is regulated as an emission point. Most of them are relatively small units in the range of 10 000 - 20 000 m3/h. The negative side of this selection is that the plant has a large number of fans to maintain. However, these are small units which are easy to replace and less likely to have problems with impellor balance. Variable speed drives are used instead of dampers on fans over 35 kW to regulate fl ow. These do not have moving parts and so will be more reliable. Water sprays are not used at conveyor transfer points. The quantity of transfers and their widely separated locations has led to the conclusion that this would create a situation that would be diffi cult to maintain. Dust generation on the mine haul roads and the in-plant roads is reduced by spraying with the waste brine from the plant’s reverse osmosis water purifi cation unit. This is supplemented by limited amounts of raw water when required. Dust control on the stockpiles and the tailings pile is the most diffi cult source to control. Water sprays for limited use are included in the current design. It remains to be seen how effective these will be. The concentrate and tailings are blends of about 80 per cent dry material and 20 per cent moist fi lter cake which will give four per cent of moisture in the mixed material. Experience in the existing plant has shown this to be very effective in suppressing dust generation at the conveyor transfer points and the discharge point. There is however considerable dust generation when material ‘avalanches’ down the slopes of the piles. This mainly occurs after some of the moisture has evaporated from the piles. The stackers for crushed ore and concentrate are conventional design with automatically controlled luffi ng booms to limit dust generation. The tailings stacking system is the leach pad type stacker using a long conveyor travelling sideways on crawlers with a tripper and discharge conveyor moving along its length. The discharge conveyor is reversible to stack ahead or behind the travelling conveyor. The stacking height is designed for 15 m ahead of the travel (down-stacking) and 7 m behind (up- stacking) and therefore minimises the avalanche effect. It also means that the dust is generated in a location that is relatively sheltered from the wind. Water sprays are not used (Figure 4). DUST TREATMENT Samples of dust taken from the existing plant showed that wet magnetic separation can easily produce a good quality concentrate. This equates to a small but signifi cant portion of the total production. The dust is sent to the wet concentration plant and combined with the ball mill product as feed to the magnetic separation. Transporting the dust to the wet concentration plant presents some challenges. The collection locations are spread over a length of 1.7 km (excluding the product conveying and loading), the quantities are hard to predict and the fl ows are all intermittent. A number of options were considered: pneumatic conveying, trucking in pneumatic discharge trailers, trucking in concrete mixing trucks, and slurrying and pumping. After a thorough review, the option selected is the slurry pumping system. A circuit with a continuous fl ow of water in a loop around the plant is used. The collected dust is added at several points in mix tanks and pumped to the wet concentration plant. The slurry contains variable amounts of solids in a fi xed amount of water and is discharged into a thickener. The thickener overfl ow is returned to the circulation loop. The thickener underfl ow joins the feed to the wet magnetic separation (Figure 5). PROJECT MANAGEMENT ISSUES Health and safety HSE plan and objectives of zero tolerance was a challenge. The HSE culture was developed during the site preparation phase with the client and the local contractor involved. A training program was prepared by type of construction activities and presented to all workers. Logistics The logistics for the project will be a significant challenge. The traffi c through the port of Nouadhibou will be triple its normal level during a period of six months from November 2011 to May 2012. Additional storage facilities and coordination teams have been planned to achieve three months total delivery time to site. Although all equipment and construction tender packages were prepared in French there was a positive market response. The major equipment suppliers have all submitted a complete offer in French and accepted to execute the contract in French. However, all day to day communication with the vendors is conducted in English. Long procurement schedule The procurement schedule is longer than under a typical EPCM project execution for a number of reasons: A preliminary plant design in substantial detail is required as a basis for the bid packages so all the vendors provide costs on a comparable basis. An extended period is required for preparing detailed bid package specifi cations that match the capabilities of the vendors. Process plant bidders must perform in-house testing, process design, subcontract bidding and cost estimating before producing fi rm bids. This cannot be easily done in three months and is also very costly to the vendors. These costs are indirectly refl ected in the fi nal project overall cost. The bid evaluation time is longer than for bare equipment purchases because of the amount of detail required and the requirement for process guarantees. Detailed engineering for buildings, electrical work, etc cannot proceed until the major packages are awarded and vendor engineering is well advanced. Management of Engineering, Procurement and Services packages Management of the EPS packages has proven to be diffi cult to perform for some of the engineering deliverables such as P&IDs. In general, the vendors have underestimated the time required for design, review, Hazop review and coordination. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 G COOPER, R LAPOINTE AND J ROUTHIER 16 Standardisation of equipment, documentation and design approach is diffi cult to achieve in all aspects. Performance guarantees are diffi cult to negotiate with limited time available, limited samples and laboratory availability. The vendors are unwilling to guarantee performance based on third party test work results. The performance guarantees oblige the equipment vendors to increase their design factors and potentially increase the cost of the project. This is accepted as part of the price paid for the process guarantee. As an example, slurry piping could be overdesigned for high fl ow rates leading to blockage at normal fl ow rates. Suitable compromises must be agreed to make the plant operable and cost-effective. CONCLUSIONS The Guelb II project presents some unique challenges: limited water supply requiring dry processing as much as possible; dust emission control on dry ore with a minimum of water consumption; control of ambient levels of silica in the workplace, given the desert environment; contracting strategy using complete, process-guaranteed equipment packages; and construction in a remote site. A fi nal overall conclusion concerns the use of process- guaranteed equipment and engineering packages. This approach implies certain cost increases but also signifi cantly extends the project schedule, mainly on account of test work required for process guarantees. FIG 5 - Dust collection and treatment. FIG 4 - Tailings down-stacking, up-stacking and prevailing winds. PREVAILING IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 17 The Benefi ts of Computational Modelling in Improving Iron Ore Production and Processing M P Schwarz1 and P Cleary2 ABSTRACT A major issue presently faced by companies producing and processing iron ore is the need to maximise throughput while minimising capital expenditure. While present high demand means this is of prime importance, the perennial issues of maintenance, operating costs, reliability, quality and environmental sustainability are also critical to profi tability. Attempts to address these issues generally require modifi cations to existing equipment, or trials of new equipment when designing plant for new projects. The risk involved can be substantially minimised by testing equipment improvements using advanced computational models prior to implementation. Examples of application of Computational Fluid Dynamics (CFD) and Discrete Element Method (DEM) modelling to sampling, cyclones, conveyor transfers, classifi ers, dust control, banana screens, comminution and smelt-reduction will be given to illustrate the benefi ts of such an approach. 1. MAusIMM, CSIRO Mathematics, Informatics and Statistics, CSIRO Minerals Down Under Flagship, Private Bag 312, Clayton South Vic 3169. Email: phil.schwarz@csiro.au 2. CSIRO Mathematics, Informatics and Statistics, Private Bag 33, Clayton South Vic 3168. Email: paul.cleary@csiro.au IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 19 Dewatering Marra Mamba – Lessons Learned K Sommerville1 and B Douglas2 ABSTRACT BHP Billiton’s Area C iron ore operation has been in production since 2003. During 2010, below water table mining in the Marra Mamba formation commenced and dewatered ore has been successfully processed through the plant. The ability to mine below water table material increases reserves. Pits can be dewatered using a combination of ex-pit and in-pit bores. Critically it is important to allow suffi cient lead time to dewater. For Area C, in-pit bores yield the most water which presents challenges in every day operations when mining around bores. Operationally there are steep learning curves in obtaining equipment, training personnel and setting up infrastructure. Core risks include lifting, refuelling and maintaining gensets. The pipe- work, extraction and re-establishment work can be very manual. The challenges include blasting, mining, stockpiling, processing, water balance and disposal. Maximising up time on bores whilst minimising impacts to blast practices have evolved. Blast practices now align bores to the edge of patterns. Protecting bores have evolved from stemming bores with rock and re-drilling to using gas bags which require no drills. Based on moisture and material properties, mining of dewatered material can be categorised into three groups: 1. normal, 2. sheeting, and 3. sheeting and top loading. Ore can go straight to the plant ore to drying pads where it takes between one and three months to drain. Stock management of these piles is important to ensure effi ciency of the plant. Rules have been established for blending wet material to maintain feed capacity and some modifi cations to plants have been made. Dewatering of pits poses a challenge for water use. Initially turkey’s nests were established to capture water and use for dust suppression. As water abstraction has increased methods of management include using exhausted pits for storage and evaporators. Managed Aquifer recharge and use in potable water are being considered. An over arching coordination of the capacity and use are required. Important elements in dewatering include: capacity models, capital, long to short planning, day to day coordination, and water level monitoring and balances. Success in dewatering requires a cross function team working towards a common goal. 1. FAusIMM(CP), Mine Manager, Area C, 225 St Georges Terrace, Perth WA 6850. Email: kate.m.sommerville@bhpbilliton.com 2. Water Resources Manager, 225 St Georges Terrace, Perth WA 6850. Email: Blair.R.Douglas@bhpbilliton.com IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 21 INTRODUCTION The Japanese steel industry has a long history of introducing innovative technologies in the fi eld of iron making. Technologies adopted during the past ten years include: technologies to use cheaper and lower-grade raw materialsand fuels, measures to prolong the service life of blast furnaces and coke ovens, promotion of energy saving, and solutions to environmental problems. This report outlines the recent technical developments in iron-making and CO 2 reduction technologies being developed. RECENT IRON PRODUCTION AND CHANGES IN NUMBER AND CAPACITY IN BLAST FURNACES The Japanese productions of crude steel and pig iron were about 100 M and 80 Mt, respectively, from the mid-1970s to end of the 1990s. From the start of the 2000s, the production gradually increased to meet the economic growth of the BRICS. However, last year's production fell widely due to the worldwide economic crisis (Figure 1). The number of blast furnaces has been reduced from 65 in 1971 to 28 in 2010, as a result of increasing the production capacity of each blast furnace by increase in its inner volume (Figures 2 to 4). THE PRETREATMENT TECHNOLOGIES AGAINST THE DEGRADATION OF IRON ORE AND COAL RESOURCES Changes in the iron ore resources During the 1990s, the Japanese steel mills increased imports of Australian iron ores to reduce costs. In the 2000s, they gradually began increasing the potion of Brazilian ores to reduce Al 2 O 3 content in sinter to meet needs of high productivity operation of their blast furnaces (Figure 5). Types of the Australian iron ores have changed from hard haematite (Brockman) to goethite (Pisolite) and goethite haematite (Marra Mamba). The average grain size of sinter feed has decreased as ratio of Marra Mamba increased (Table 1). 1. Director, Iron-making Technical Division, Nippon Steel Corporation, 6 - 1 Marunouchi 2-Chome, Chiyoda-ku, Tokyo 100-8071, Japan. Email: miwa.takashi@nsc.co.jp Recent Iron Making Topics in Japan N Takamatsu1 ABSTRACT The environments surrounding the iron and steel industry have changed greatly in recent years. Reported in this paper are the technologies adopted by the Japanese iron and steel industry to fi t itself to change in global steel demands, degradation of iron ore and coal, prolonging service life of the facilities and requirements of energy saving. In addition, innovative technologies for CO 2 emission control in iron making processes are also discussed. 0 20,000 40,000 60,000 80,000 100,000 120,000 140,000 19 51 19 55 19 59 19 63 19 67 19 71 19 75 19 79 19 83 19 87 19 91 19 95 19 99 20 03 20 07 20 08 4 6 20 09 4 20 09 8 20 09 12 20 10 4 Pr od uc ti on (k t/ ) Pig Iron Crude Steel P '08FY(q) '09 10FY(m) S '08FY(q) '09 10FY(m) FIG 1 - Trend of pig iron and crude steel production of Japan. 0 10 20 30 40 50 60 70 0 1000 2000 3000 4000 5000 6000 7000 19 45 19 53 19 57 19 61 19 65 19 69 19 73 19 77 19 81 19 85 19 89 19 93 19 97 20 01 20 05 20 09 Max. IV Min. IV Ave. IV Number of BF Callender year B la st Fu rn ac e IV N um berofB lastFurnaces (n) FIG 2 - Number and size distribution of blast furnace in Japan. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 N TAKAMATSU 22 Process of iron ore pretreatment technologies Degradation in size of sinter feed results in lower productivity of sintering machines. To compensate the loss of productivity, several types of pretreatments for the sintering process have been applied. JFE Steel Corp developed a new granulation process for the sinter feed treatment (Oyama et al, 2005). The technology controls melting behaviours of iron ore and limestone by coating the appropriate amount of coke breeze and limestone on the pseudo-agglomerates of iron ore. The process improves productivity of a sintering machine and the sintered ore's reducibility. The process is applied into four sintering machines at the West Japan Works of JFE Steel Corp and achieves an annual capacity of 19 Mt (Figure 6). MEASURES FOR PROLONGING SERVICE LIFE OF FACILITIES Prolonging of blast furnace life Carbon bricks have been used for the blast furnace hearth refractory for 50 years. Nippon Steel Corp has improved carbon bricks for long years (Nitta, Nakamura and Ishii, 2008) (Figure 7). A brick of the blast furnace hearth needs high corrosion resistance and thermal conductivity to control the self-protective layer. The carbon brick recently developed by Nippon Steel Co is high in corrosion resistance. It is designed to form an adhesion layer at the boundary between the carbon brick and molten iron. Extension of coke oven life A technology is being developed to extend service life of coke ovens. In Japan, many of the coke oven batteries were built ‘92 ‘93 ‘94 ‘95 ‘96 ‘97 ‘98 Nagoya #1 Kimitsu #2 Muroran #2 Kimitsu #3 Oita #2 4,650m3 PW 4,250m3 Bell 4,822m3 PW 3,890 PW 4,403 PW 4,063 Nagoya #3 4,884m3 BellBell 4,158Oita #1 Tobata#1 #4 Kimitsu #4 ‘90 ‘91 ‘99 ‘00 ‘01 ‘02 ‘03 ‘04 ‘05 3,273m3 PWBell 2,884 4,300m3 PWPW 3,424 ‘07 ‘09‘08‘06 ‘10 ‘11 ‘12 2,902m3 PWPW 2,296 5,555m3 PWPW 5,151 5,775m3 BellBell 5,245 ’92/5 ’93/5 ’94/11 ’98/2 ’00/4 ’01/5 ’01/11 ’03/5 ’04/5 ’07/4 ’09/8 ’?/? actual plan Furnace inner volume enhancement 35,514 m3 42,095 m3 3,946 m3 4,677 m3/unit The largest BF in the world 5,775m3 Bell 5,443m3 PW FIG 3 - Size enlargement of blast furnace (NSC). FIG 5 - Changes in the iron-ore sources used by Japanese steel industry (1971 - 2007). Inner Volume The 2rd campaign The 3rd campaign Throat diameter Belly diameter Hearth diameter Tuyeres Tapholes Maximum production design record 5,245m3 10.5m 16.6m 14.9m 40 4 12,550 t/d 13,368 t/d 5,775m3 11.1m 17.2m 15.6m 42 5 13,500 t/d 13,810 t/d Working Volume 4,312m3 4,753m3 132 days 79 days Throat Cast stave Cast stave Relining days Cast stave Copper+cast stave hearth Cast stave High-erosion- resistance type carbon brick Hearth brick Carbon brick Cast stave shaft 14900 15600 17200 10500 11100 I.V.5775m3 W.V.4753m3 O2R(2) O2R(3) 16600 I.V.5245m3 W.V.4312m3 H h FIG 4 - Biggest blast furnace in Japan (NSC Oita #2). A B C (2007) D E Ore type Brockman Brockman Marra Manba Pisolite Pisolite T.Fe % 62.40 61.80 61.78 56.40 58.30 AI 2 O 3 % 2.47 2.24 2.26 2.79 1.52 -0.15 % 12.10 13.10 28.08 3.20 4.58 L0 I % 3.20 5.20 5.98 9.40 10.00 TABLE 1 Alumina component, fi ne particle ratio and LOI of typical iron ores (2008 company data). FIG 6 - Process fl ow of limestone and coke breeze coating granulation technology. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 RECENT IRON MAKING TOPICS IN JAPAN 23 around 1970, and their average age is 36 years. Coke ovens tend to be lower in productivity due to more frequency of high pushing loads and more through holes on the walls as they get older. To overcome this problem, Nippon Steel Corp has developed a technology for diagnosing and repairing damaged fi rebrick walls in the coking chambers quite precisely and effi ciently. The innovated machine, Doctor of Coke Oven (DOC), is of a technology of combination of mechanical engineering, optical sensing and data analysis and processing (Figure 8). MORE EFFICIENT AND MORE STABLE OPERATION Development of hybrid bonded lumpy ore for blast furnaces Kobe Steel, Ltd developed a technology of a new type of feed material for a blast furnace (New Energy and Industrial Technology Development Organization, 2007) (Figure 9). With this technology, the agglomerates, new blast furnace feedstock, are made from low quality ore with help of coking property of mixed coal. Carbon remained in the agglomerates functions as an auxiliary reducing agent in a blast furnace. Its aims are to use iron ore with various qualities and to reduce CO 2 emission. Targets of the research were to make a lumpy material with strength enough to be used in a blast furnace, and to obtain an appropriate control of burden distribution to materialise its highly reactive effi ciency fully in a blast furnace. The target of energy conservation is 72 000 kiloliters/year ofcrude oil equivalent (Fiscal, 2010) by using 30 kg of the hybrid bonded lumpy ore per ton of pig iron. CO 2 reduction in the sintering process by blowing natural gas onto the sinter cake JFE Steel Corp developed Secondary-fuel Injection Technology for Energy Reduction (Super-SINTER)(JFE Steel Co, 2009) (Figure 10). In this process, natural gas injected from nozzles is sucked into the sinter bed. This technology maintains the optimum sintering temperature in the sinter bed for longer time than the conventional technology does. It improves yield of lump sinter and energy effi ciency. Reduction in CO 2 emission by this technology is estimated to be about 60 000 t/a. Start up of SCOPE21 – a new coke oven battery A new coke oven that adopted the SCOPE (Super Coke Oven for Productivity and Environmental enhancement toward the 21st century) technology was in operation on February 2008 at Oita Works of Nippon Steel Corp SCOPE allows high temperature coal charging up to 250°C to improve coking property and coke oven’s productivity. The battery reached a productivity at as high as 1.85 charges per day, and also has maintained a stable operation since the beginning of operation (Doi et al, 2009) (Figure 11). The operation is fully automated and stable operation was confi rmed within four months from the star-up. It took only less than a year to reach the full production capacity. High-speed coal preheating and high bulk density of the charged coal contribute to a high ratio of semi-soft coking coal in total coal as high as 50 per cent or more. Moreover, the coke strength is 2.5 per cent higher than that of the conventional coke ovens. FIG 7 - Development of carbon brick. FIG 8 - Schematic diagram of the quantitative damage information analysis system of Doctor of Coke Oven (Sakaida, Awa and Sugiura, 2006). FIG 9 - The producing process of hybrid bonded lump ore. FIG 10 - Schematic fi gure of Super-SINTER. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 N TAKAMATSU 24 Improvement of production effi ciency of blast furnace New numerical simulation technology adopted in the iron-making processes The discrete element method (DEM) is being used for simulation of the blast furnace process. This is applied to analysis on behaviour of the burden particles when they pile up on top of the burden and when they descend in the furnace shaft. This also applied to analysis on a agglomerating process in drum mixers of raw material preparation processes. This model gives us useful information for operation control (Mio et al, 2009) (Figure 12). Researches and developments for effi cient blast furnace operation with an experimental blast furnace It is important to examine changes in the blast furnace operation when the raw material qualities change. In addition, it is also important to obtain conditions of highly productive and energy efficient operation of blast furnaces. However, such examination with a commercial furnace is diffi cult, and that with a bench scale furnace is not accurate. Therefore, Sumitomo Metal Ind Ltd has conducted various researches using an experimental blast furnace with an inner volume of 3.8 m (Nitta, Nakamura and Ishii, 2008; Ujisawa et al, 2006) (Figure 13). Recently, a series of experiments were conducted to quantify effects of hot briquette iron (HBI) on productivity and rate of the reducing agent in a blast furnace. In the experiments, HBI is found to be as a future source of iron in a blast furnace for high production and lower CO 2 emission. Natural gas injection to blast furnace JFE Steel Corp introduced natural gas (NG) injection to increase productivity of a blast furnace and to reduce CO 2 emission (Yamamoto, Kashiwara and Tsukiji, 2008) (Figure 14). The trial of a commercial plant using No 2 Blast Furnace of JFE Steel’s East Japan Works (Keihin) proved that NG injection improved gas permeability in the furnace and, as a result, increased productivity of a blast furnace. Moreover, because ratio of oxide reduction by hydrogen increased when NG is injected, CO 2 emission was reduced. The blast furnace made the world’s highest productivity of blast furnaces bigger than 5000 m3 during the trial (2.56 t/d-m3). CONSERVATION OF ENERGY AND CO 2 REDUCTION TECHNOLOGY Energy consumption in the iron and steel industry in Japan The Ministry of Economy, Trade and Industry (METI) fi nalised ‘the Cool Earth Energy Innovative Technology Plan’ in March 2008 and have just released it. In May 2007, the prime minister at that time announced the ‘Cool Earth 50’ initiative. The long-term goal of this initiative was a 50 per cent reduction of the world's total greenhouse gas emissions by 2050. The Prime Minister of Japan stated at the United Nations Summit on Climate Change in September, 2009 that Japan will set a middle term target of reduction in CO 2 emission by 25 per cent in 2020 from that in 1990. FIG 11 - The process fl ow and main specifi cations of Oita no 5 coke oven. FIG 12 - An example of burden distribution in the blast furnace simulated by discrete element method. Fluidized bed dryer Hot briquetting machine Pneumatic preheater High temperature coal bin IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 RECENT IRON MAKING TOPICS IN JAPAN 25 The Japanese steel industry exhausts CO 2 about ten per cent of the national emission, and about 70 per cent of its CO 2 emission is from the iron-making processes. Therefore, efforts to reduce CO 2 in the iron-making processes are very important. Developing innovative technologies is essential to fulfi lling this goal. Innovative iron-making process Original iron-making technologies to expand fl exibility in choice of raw materials and to reduce CO 2 emission are sought for keeping competitiveness of the Japanese steel industry. Among various research and development activities, Advanced Research on Innovative Iron-making Process Project has implemented as a government project cooperated by JRCM, the Japanese steel industry and several universities starting in December 2006 (Naito, 2009) (Figure 15). One of the key technologies is a compound material made of ferrous oxide, carbon material and metallic Fe. Target of the research is set as ten per cent reduction in energy consumption, which is comparable to the improvement in the blast furnace shaft effi ciency when the thermal reserve zone temperature drops from 1000°C - 800°C. After three years of the research, important results, understandings of reduction behaviour of the compound material and a new manufacturing process of the compound material, have been obtained. By a high temperature softening test, the compound material showed improvement in the reduction rate and in permeability of the cohesive zone. This technology is still being researched to bring to completion of a new Japanese original technology for energy conservation and CO2 emission control. COURSE 50 (Matsuzaki et al, 2009) The basic idea of COURSE 50 The project of CO 2 Ultimate Reduction in Steelmaking process by innovative technology for cool Earth 50, COURSE 50, was proposed by JIFS with six major steel companies and related companies. The project is composed of two major technical developments. The low carbon, environmentally-accepted iron-making process development (research and development item 1) consists of two parts. One is development of a practical technology applying hydrogen to iron ore reduction, and the other is development of low cost hydrogen production technology (ex by reforming of coke oven gas (COG)). The CO 2 separation and collection technology development (research and development item 2) consists of two parts. One is a technology of CO 2 separation from blast furnace gas, and the other is a utilisation technology of waste energy for CO 2 separation and collection. Possibilityof hydrogen reduction To reduce CO 2 emission, we will examine reformed COG gas (CO 35 per cent, H2 60 per cent) injection through FIG 13 - Schematic picture of experimental blast furnace (BF). FIG 14 - Operation trends of no 2 blast furnace at East Japan Works (Keihin). FIG 15 - The reduction behaviour change by existing carbon composite material. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 N TAKAMATSU 26 conventional tuyeres and also through trial nozzles set on the blast furnace shaft. The basic idea of hydrogen reduction in the blast furnace process using reforming COG is shown in Figure 16. CONCLUSIONS The environment surrounding iron-making is getting severer, and therefore the following issues are getting more important: degradation and imbalance in demand and supply of the iron ore and coal, aging plant facilities, fl exible in production and effi cient operation, and environmental problems. The Japanese steel industry has been improving operations and conserving natural resources, and at the same time coping with aging equipments and long-term environment issues. We are convinced to create a leading edge of technologies to contribute the world’s iron and steel industries and to solve the problems ahead us. REFERENCES Doi, K, Noguchi, T, Fujikawa, H, Shioda, T, Yokomizo, M, Kato, K, Nakajima, Y and Uematsu, H, 2009. CAMP-ISIJ, 22:782. JFE Steel Co, 2009. News release [online]. Available from: <http://www.jfe-steel.co.jp/release/2009/06/090615.html> (in Japanese) [Accessed: 15 June 2009]. Kasai, E, Komarov, S, Nushiro, K and Nakano, M, 2005. ISIJ Int, 45:538. Matsuzaki, S, Yonezawa, K, Saito, K and Naito, M, 2009. CAMP-ISIJ, 22:268. Mio, H, Komatsuki, S, Akashi, M, Shimosaka, A, Shirakawa, Y, Hidaka, J, Kadowaki, M, Matsuzaki, S and Kunitomo, K, 2009. ISIJ Int, 49:479. Naito, M, 2009. JRCM NEWS, 268:1. New Energy and Industrial Technology Development Organization (NEDO), 2007. Outline of NEDO, 2007-2008, October, First Edition, 114. Nitta, M, Nakamura, H and Ishii, A, 2008. Nippon Steel technical report, 388:48. Oyama, N, Sato, H, Takeda, K, Ariyama, T, Matsumoto, S, Jinno, T and Fujii, N, 2005. ISIJ Int, 45:817. Sakaida, M, Awa, Y and Sugiura, M, 2006. Nippon Steel technical report, 384:63. Ujisawa, Y, Snahara, K, Matsukura, Y, Nakano, K and Yamamoto, T, 2006. Tetsu-to-Hagane, 92:591. Yamamoto, K, Kashiwara, Y and Tsukiji, H, 2008. JFE Giho, 22:55. Oven in works Power generation in works Power generation For sale Coke oven Coke Blast furnace COG Reforming COG Gas treatment Reforming COG Hydrogen for society H2;65% Co;35% COG: Coke oven gas H2+CO H2 FIG 16 - Basic idea of hydrogen reduction in the blast furnace process using reforming coke oven gas. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 27 Developing the West Pilbara Iron Ore Project K Watters1, A Priddy2 and D Ducler des Rauches3 ABSTRACT API Management Pty Ltd (API) is currently developing the West Pilbara Iron Project (the ‘Project’). The Project is a substantial greenfi elds mining and infrastructure development proposed for the west Pilbara region of Western Australia. The Project will establish API as a new and independent supplier of direct shipped iron ore. API manages the Australian Premium Iron Joint Venture (APIJV) on behalf of joint venture participants Aquila Resources Ltd and American Metals and Coal International Inc. The APIJV was formed in February 2005 with the objective of developing a long-term iron ore export operation in the west Pilbara region. Development of Stage 1 comprises a 30 million tonne per annum (Mt/a) channel iron deposit (CID) operation scheduled to commence in the second half of 2014 subject to approvals. JORC compliant CID resources total nearly 700 million tonnes and the Stage 1 mining area comprises eight iron ore deposits located between 30 km and 85 km south of Pannawonica. Run-of-mine ore from the eight deposits is transported to a central processing facility for crushing, screening and blending into a sinter fi nes product, which API has named West Pilbara Fines or WPF. Construction of a 282 km main line heavy haulage railway from the Stage 1 mining area to the proposed greenfi elds multi-user port at Anketell Point near Wickham, is capable of accommodating large Capesize bulk carriers and providing export facilities for other third parties. Capital investment in the order of $A6 billion includes essential support infrastructure including power, water, accommodation, roads and an airport at the mine. A feasibility study for the development of the Stage 1 mine, rail and port infrastructure has been completed along with environmental surveys of the mine, rail and port areas with Public Environmental Reviews (PERs) for each submitted for public review by end 2010. Consultation and cooperation with various stakeholders of the Project areas, and early engagement with traditional owners of the respective areas has commenced. Various sampling and metallurgical characterisation programs combined with independent institute and steel mill based testing have confi rmed the positive sintering characteristics of WPF ore, which is higher in alumina (3.37 per cent) than typical Pilbara ores. The installed rail and port infrastructure will be the catalyst for further resource development within the west Pilbara region. There is considerable regional demand for a new multi-user port, given access to existing Pilbara facilities is severely constrained. While the expected Stage 1 mine life is less than 20 years, the infrastructure is planned to have a useful life of at least 50 years. Following on from successful exploration, acquisition and partnering, API plans to continue to develop and open up new mines and associated infrastructure in the west Pilbara. 1. Project Director, API Management Pty Ltd, Level 2, 1 Preston Street, Como WA 6152. Email: kwatters@apijv.com.au 2. General Manager Marketing, API Management Pty Ltd, Level 2, 1 Preston Street, Como WA 6152. Email: apriddy@apijv.com.au 3. Senior Process Engineer, API Management Pty Ltd, Level 2, 1 Preston Street, Como WA 6152. Email: dducler@apijv.com.au IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 29 Development Options for the Eyre Peninsula Magnetite – An Owner’s Perspective J White1 and B Hammond2 ABSTRACT The Eyre Peninsula (EP) has been known for its iron ore for more than a century. Edward John Eyre noted the ironstone outcrop at what is now Iron Knob in the 19th century. Sir Douglas Mawson visited and reported on the geology of the lower EP in 1906, noting the widespread presence of iron stone and the likelihood of copper being associated with the iron stone. Despite this knowledge there has been only one successful iron ore mining region developed on the EP and that is Iron Knob and the Middleback Ranges which have been mined continuously since 1899. The Middleback Ranges can justly lay claim to be birth place of the Australian iron ore and steel industries. The discovery of large scale haematite resources in Western Australia meant that there was no need to seek out iron ore that needed benefi ciation. The low price of iron ore precluded further development of the EP and many other areas in Australia and overseas. This situation changed rapidly in the mid-2000s with the emergence of China as the world’s industrial power house and the soaring demand and price for many resources including iron ore. This triggered a fl urry of activity across Australia and led to the rapid exploration and drives to develop the EP iron ore. A brief examination of the magnetic maps of the EP shows the wide spread presence of magnetite and associated smaller haematite deposits. A closer look reveals the magnetite deposits to vary in formation style and host rock lithology as well as being signifi cantly altered by regional metamorphism. Whilst developers of the traditional directship haematite ores of Australia have had limited control on the physical and chemical characteristics of the product they produce, the developers of benefi ciated magnetite ores such as on the EP must decide what product they will target along a continuum of processing options. These decisions must be made taking both the development constraints of the individual operation and orebody into account while balancing this with the end customer’s needs. Every decision in this respect is a trade-off between process effi ciency and product marketability. A comparison of the key trade-off factors of grind size, DTR recovery and concentrate chemistry (Fe per cent, SiO2 per cent) for the EP against current magnetite projects across Australia can be made showing in particular the potential of EP ores to produce highly saleable products at coarse grind sizes. Infrastructure provision has a large economic impact on magnetite mines and concentrators. Magnetite requires signifi cant amounts of water and power to drive the benefi ciation process and, in common with haematite, transport infrastructure to provide a route to market. The potential exists on the EP to access power from the east coast grid network and to derive the necessary water by using this power to produce desalinated water from the sea. All the EP ore deposits are relatively close to the coast and there are a number of proposals to develop ports close to the mine sites. In the case of the Centrex Metals projects, the port would be less than 100 km from the furthest deposit and slurry pipe lines for product transport preclude the need for extensive rail development and the associated high operating costs. In addition there are existing industrial towns in the region with some social infrastructure already in place. A comparison of the attributes and location of the EP iron ore deposits give promise of the development of high quality magnetite concentrates that complement the large scale haematite developments elsewhere in Australia. 1. Managing Director, Centrex Metals Limited, Unit 1102, 147 Pirie Street, Adelaide SA 5000. Email: jwhite@centrexmetals.com.au 2. MAusIMM, Chief Operating Offi cer, Eyre Iron Pty Ltd, Level 9, 420 King William Street, Adelaide SA 5000. Email: ben.hammond@eyreiron.com.au IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 33 INTRODUCTION The global mining and exploration database Intierra Resource Intelligence (Intierra Mapping, 2010) lists 154 iron ore deposits in Western Australia. Of these 154 deposits, only 34 are currently being mined with most of the remainder at various stages of exploration, feasibility and development. A large proportion of the iron ore deposits expected to commence production in the next fi ve years comprise resources that will require some degree benefi ciation, such as magnetite or Channel Iron Deposits (CID). Presently, there are very few sites around Australia that generate iron ore tailings from their operations. The sites that do generate tailings include Savage River in Tasmania, Middleback Range in South Australia and MESA J in Western Australia. Consequently, operational experience with iron ore tailings in the Australian, and particularly Western Australian, context is limited. Li et al (2010) asserts that iron ore tailings have become one of the most hazardous solid wastes. Indeed, the collapse of one iron ore tailings storage facility in 2008 killed a reported 254 people in China’s Shanxi Province. The failure contributed the largest number of fatalities to a list of not less than 11 major iron ore tailings dam failures that have occurred in the last 35 years (ICOLD, 2001; WISE Uranium, 2011). While the triggers for the geotechnical stability of tailings storage facilities are generally well understood, there are several other aspects of iron ore tailings that present challenges to the proponent. The geology of hard rock iron ore deposits in Australia means that they are often associated with the occurrence of asbestiform and sulfi de minerals. Consequently, the tailings generated by these projects can present a signifi cant hazard to the environment, both in terms of the potential for the liberation of respirable fi bres and the generation of Acid and Metalliferous Drainage (AMD). When coupled with sensitive environmental settings and large production volumes, these factors pose a signifi cant challenge for designers, regulators and producers. Presently, there are several large magnetite mining and processing operations under consideration and development in Western Australia. These projects include the Sino Iron Project, Balmoral South Iron Ore Project, Jack Hills Expansion Project, Karara Iron Ore Project, Ridley Magnetite Project, Cape Lambert Iron Ore Project and Extension Hill Magnetite Project. Publically available information (shareholder announcements, Department of Mines and Petroleum (DMP) publications and company websites) suggests that these projects each have the capacity to generate 1. Senior Tailings Engineer, Golder Associates Pty Ltd, Level 3, 1 Havelock Street, West Perth WA 6005. Email: danstey@golder.com 2. Civil Engineer, Golder Associates Pty Ltd, Level 3, 1 Havelock Street, West Perth WA 6005. Email: dreid@golder.com Overcoming the Challenges of Managing Tailings from Iron Ore Mining in Western Australia D R Anstey1 and D A Reid2 ABSTRACT The growing demand for iron ore from Western Australia has led to an increased focus on the development of magnetite and lower grade iron ore deposits. The need to process and benefi ciate the ore from these projects can result in the generation of signifi cant quantities of iron ore tailings over the life of a project. Over the coming decades, the management of iron ore tailings will become a signifi cant aspect of the mining landscape in Western Australia. The tailings generated from iron ore projects differ signifi cantly from other mineral tailings currently produced in Western Australia. Iron ore tailings are generated on a scale not matched by any other mineral process and can often contain asbestiform or potentially acid forming components. New iron ore projects are coming under increased environmental scrutiny because of their large scale operations and the sensitive environments in which they occur. This combination of factors creates some unique challenges for the management of tailings generated by iron ore mining in Western Australia. This paper presents the fi ndings of two studies conducted in recent years to overcome the challenges posed by iron ore tailings. The paper discusses the role of laboratory testing in the development of management strategies for asbestiform minerals in tailings. It also presents a numerical modelling approach for evaluating the rates of rise in the storage of magnetite tailings. The paper concludes by outlining how the fi ndings of these studies can be applied to reduce tailings management costs, lower risks and improve environmental outcomes for the management of tailings from iron ore mining. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 D R ANSTEY AND D A REID 34 between 18 and 67 Mt/a of iron ore tailings. The fi rst of these projects is scheduled to commence production in mid-2011. The amount of tailings generated by the largest of these new magnetite projects will be more than ten times the amount of tailings currently generated by the largest existing magnetite processing facility in Australia and four times the amount of tailings generated by the ‘Super Pit’ gold mining operations in Kalgoorlie. The implications are that, over the next fi ve years, the rate of iron ore tailings generated in Western Australia will grow exponentially. With this comes the need to understand and manage iron ore tailings in an economically feasible, socially responsible and sustainable manner. This paper describes two innovative approaches that have been recentlybeen used to support the design and environmental permitting of iron ore tailings storage facilities in Western Australia. DESIGNING FOR THE CONTAINMENT OF ASBESTIFORM MINERALS Regulatory context The Western Australian government recently released a guideline on the management of fi brous minerals in Western Australian mining operations (DMP, 2010). The guideline acknowledged that: Increasing demand for minerals has made mining and processing of previously uneconomic orebodies commercially viable. Consequently, fi brous minerals are now encountered in mining operations more frequently than in the past. The DMP guideline makes particular reference to the occurrence of fi brous minerals within the banded iron formations of the Hamersley Basin and goes on to say that: Processed tailings can contain similar concentrations of fi brous minerals to the feed ore, but the fi bre bundles are generally thinner and shorter and therefore more biologically active and more hazardous. Consequently, it is imperative that tailings are properly managed so that fi bres do not become airborne. It is imperative that iron ore miners not only understand the presence and distribution of fi brous minerals in their orebody but also quantify the hazards these materials pose after processing. Where fi brous minerals are present in tailings, it is incumbent on the proponent to demonstrate to the Regulators and other stakeholders that these tailings can be stored safely. One recognised method for the control of fugitive dust emissions from tailings is the use of water to prevent drying of the tailings. The DMP guideline suggests that mines should demonstrate how the tailings will be maintained in a wet state. However, it may not always be possible to maintain tailings in a wet state, particularly when dealing with large tailings areas, raises to tailings storage facilities, or mill shutdowns. Questions are also raised about the effi cacy of moisture control to contain fi bres and what other controls can be implemented to reduce the potential for respirable fi bres. Regulatory approval of mining operations may rest on the ability of the proponent to demonstrate that its proposed respirable fi bre controls are effective. Wind tunnel testing Wind tunnel simulations are a recognised method for estimating fugitive dust emissions generated by tailings (Neuman, Boulton and Sanderson, 2008). As part of the current study, wind tunnel experiments were carried out to examine the potential for iron ore tailings to generate respirable fi bres under several simulated fi eld conditions. The objectives of the study were to: assess the potential for tailings containing asbestiform minerals to generate respirable fi bres under a range of moisture conditions and wind speeds, examine the effect of crusting and crust rupture on respirable fi bre generation, examine the generation of fi bres from a tailings beach as a function of time, and compare the quantity of fi bres generated from a wind tunnel to the National Occupational Health and Safety Commission (NOHSC) guidelines. Apparatus Testing was carried out on a sample of Western Australian magnetite tailings generated from pilot plant testing of a bulk ore sample. The tailings were examined under Polarised Light Microscopy and were confi rmed as containing of both riebeckite and crocidolite particles (blue asbestos). A particle size distribution for the tailings is included as Figure 1. Experiments were carried out in a purpose-built wind tunnel at Golder Associates’ Soils Laboratory in Perth, Western Australia. The wind tunnel has been specifi cally designed for the testing and containment of tailings containing asbestiform minerals. Airfl ow in the tunnel is generated from three variable speed Nilfi sk IVB 3-H vacuums, assembled in parallel. The vacuums are approved for the handling hazardous waste in 0 10 20 30 40 50 60 70 80 90 100 0 1 10 100 1000 C um ul at iv e % P as si ng b y M as s Particle Size (μm) FIG 1 - Tailings particle size distribution. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 OVERCOMING THE CHALLENGES OF MANAGING TAILINGS FROM IRON ORE MINING IN WESTERN AUSTRALIA 35 accordance with AS/NZS 60335.2.69 (2003). Staff involved in the testing wore appropriate personal protective equipment and adhered to strict wash-down, containment, monitoring, handling and waste disposal protocols. The wind tunnel was designed and constructed using guidance from Mehta and Bradshaw (1979). The dimensions of the tunnel were restricted to facilitate testing at wind speeds higher than might otherwise be achievable. The tunnel is constructed from clear Perspex with internal cross-sectional dimensions of 150 mm (width) × 40 mm (height) and a length of 2.4 m. An aluminium condenser (approximately 180 mm × 80 mm) feeds the tunnel and contains three wire mesh screens (each with four openings per 25 mm in lineal length) to assist in the creation of laminar air fl ow. The wind tunnel is capable of achieving maximum wind speeds of approximately 75 km/h (21 m/s). Tailings were deposited directly into purpose built Perspex sample trays that slide into and sit fl ush with the base of the apparatus. The exposed tailings surface in the sample tray has dimensions 128 mm (width) × 325 mm (length) × 10 mm (depth). A photograph of a tailings sample that has been loaded into the wind tunnel in preparation for testing is included as Figure 2. Two air sampling locations were used, one near the wind tunnel intake and another within the wind tunnel, approximately 150 mm downwind of the simulated tailings beach. The wind tunnel intake monitoring location was selected to measure respirable fi bre background concentrations during each test. The sampling location within the wind tunnel was selected as the primary measurement point for the test and comprised a 7.9 mm outer diameter plastic tube fi tted vertically through the top of the wind tunnel, and cut at a 45 degree angle to face the wind tunnel intake. The sampling tube passed through a sample cowl fi tted with a 25 mm membrane fi lter and was connected to an air sampling pump. Air sampling was carried out in accordance with the NOHSC guidelines on the membrane fi lter method for estimating airborne asbestos fi bres (NOHSC:3003, 2005). The air sampling devices were calibrated prior to the commencement of each test. Method Tailings were tested at three different moisture conditions: a wet, intermediate moisture and dry state. The wet tailings simulated freshly deposited tailings, shortly after settlement. There was no free water on the surface of the tailings but the samples maintained a refl ective sheen. The intermediate moisture tailings were selected to simulate tailings that had undergone some drying on the tailings beach. This is typical of the drying that might occur as the result of rotation between the discharge locations during operation. The tailings were allowed to air dry over several days back to a moisture content of between 11 per cent and 18 per cent. The dry tailings samples were dried in a 50°C oven to achieve moisture content of less than one per cent. Air drying tests carried out on the same tailings indicate that the ‘dry’ moisture condition would be achieved after approximate eight days under simulated summer drying conditions. Testing was carried out for each moisture condition at target speeds of 46 km/h and 75 km/h. A fresh tailings sample was used for each test. In addition, testing was carried out on three dry tailings samples that were disturbed prior to testing. Two of the samples were disturbed by crushing the surface of the tailings with a block to simulate the effect of traffi cking. The surface of a third sample was scoured with a metal brush. Prior to each test, the wind velocity in the tunnel was set and measured using a blank sample tray. Theair sampling rate was calibrated for the target wind velocity, before the vacuums were switched off and the blank tray replaced with the test sample. The sample tray was sealed and the air sampling equipment turned on, followed by the vacuums. Each test was run for an air sampling duration of fi ve minutes. Most of the test durations were continuous. However, one test was divided into fi ve time increments to measure changes in fi bre concentrations over time. Air fl ow was stopped after each time increment and a fresh sample cowl inserted into the air sampling device downstream of the tailings. Following the completion of each test, the sample tray was removed from the wind tunnel and the fi nal moisture content of the tailings was measured by oven drying. The wind tunnel was thoroughly cleaned after each test to avoid contamination of subsequent tests. Results and discussion The results of the wind tunnel testing are presented in Table 1. Wind tunnel tests on the wet and dry tailings did not produce fi bres above the reportable detection limit at wind speeds up to 75 km/h. However, the intermediate moisture condition tailings did produce measurable numbers of respirable fi bres at both 46 km/h and 75 km/h wind speeds. This result is consistent with the fi ndings of Neuman, Boulton and Sanderson (2008), who suggest that it is the creation of electrochemical bonds (crusting) and not capillary forces that provide the greatest resistance to the wind erosion of tailings. Airborne particulates were not visible for any of the undisturbed tailings tests, despite the fact that measurable fi bre concentrations were recorded for the intermediate moisture content tests. The implication is that magnetite tailings may be vulnerable to respirable fi bre generation while it is drying, even if dust emissions are not visible. By comparison to the undisturbed samples, airborne particulates were observed for the fi rst few seconds of all of the disturbed tests. Both the crushed and scoured tests produced respirable fi bre emissions that were approximately one order of magnitude higher than for the undisturbed samples tested at intermediate moisture contents. Fibre concentrations were measured over different time intervals for a dry tailings sample, crushed and subjected to 75 km/h wind speeds. The results of the incremental test are presented graphically, on a logarithmic scale, in Figure 3. FIG 2 - Tailings sample loaded within wind tunnel for testing. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 D R ANSTEY AND D A REID 36 The results of the incremental testing support the hypothesis that the measured respirable fi bre concentration is a function of the test duration. For a single sample area and wind speed, fi bre concentrations will decay with time. This is consistent with the PM 10 (dust particles with 1 μm < aerodynamic diameter <10 μm) emissions measured from discrete tailings samples by Neuman, Boulton and Sanderson (2008). The results indicate that the majority of the respirable fi bres become airborne within the fi rst fi ve seconds of being exposed to airfl ow. Comparison with National Occupational Health and Safety Commission guidelines The Australian occupational exposure standard for asbestos NOHSC:2002 (2005), specifi es that the time-weighted average asbestos fi bre concentration of the air breathed by a worker during a working shift should not exceed 0.1 fi bres per millilitre (fi bres/mL) for all forms or mixtures of asbestos. The fi bre concentrations derived from for the current experiments should not be directly compared to the occupational exposure standards. The results must be factored to take account of the relatively short duration of the air sampling and the location of the air sampling intake. The exposure standards relate to sampling within a 300 mm radius the worker’s breathing zone, while the measurements taken from the current tests have been sampled immediately downstream of the emission source. The test results from this study can best be compared to a single exposure event that could occur during a working shift (eg a worker standing near a piece of working machinery on a tailings beach). Applying this logic, an employee working an 8 h shift could be exposed to a single fi ve minute event with a concentration of 9.6 f/mL, without exceeding the Australian occupational exposure standards. Compared on this basis, only the dry crushed tailings sample exposed to 75 km/h wind speeds demonstrated the potential generate fi bre concentrations in excess of the exposure standard. In reality, the fi bre concentrations that workers are exposed to will be infl uenced by several factors. These include the moisture content of the tailings, depth and degree of disturbance, wind gusts and boundary conditions, tailings storage geometry, exposed tailings area, saltation, dispersion and dilution. Notwithstanding limits on the sample size of the test area, the results of testing from the wind tunnel could be incorporated into a dispersion model that would take account of the factors listed above. Such a model could be used to estimate fi bre concentrations downstream of the source, at the location of sensitive receptors. The results of modelling could be compared with the NOHSC guidelines to provide indications of the exposure hazard for workers. Tailings condition Wind speed (km/h) Final moisture content (%) Fibre concentration (fi bres/mL) Background fi bre concentration (fi bres/mL) Wet 48.8 22.7 BDL <0.01 Wet 74.6 24.3 BDL 0.01 Intermediate 45.9 11.4 0.4 0.2 Intermediate 75.0 17.9 1 0.01 Dry 46.2 0.1 BDL <0.01 Dry 75.1 0.2 BDL 0.01 Dry crushed 45.3 0.1 5 0.2 Dry crushed 75.2 0.1 11 0.2 Dry scoured 45.6 0.1 4 <0.01 Note: BDL: below reportable detection limit determined in accordance with NOHSC: 3003 (2005) TABLE 1 Wind tunnel test fi bre concentrations. 1 10 100 1000 0 - 5 s 5 - 20 s 20 s - 1 min 1 - 2.5 min 2.5 - 5 min Fi br es C on ce nt ra tio n (F ib re s/ m L) Time Interval FIG 3 - Comparison of fi bre concentrations measured over diff erent time intervals. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 OVERCOMING THE CHALLENGES OF MANAGING TAILINGS FROM IRON ORE MINING IN WESTERN AUSTRALIA 37 Study outcomes Testing was conducted on tailings in wet, dry and intermediate moisture states, in disturbed and undisturbed conditions, at wind velocities of approximately 46 and 75 km/h. The study makes the following conclusions: wind tunnels can be used to measure respirable fi bre generation from magnetite tailings that contains asbestiform minerals and used to evaluate the relative effectiveness of control measures, such as moisture; tailings tested in both saturated and dry states did not demonstrate the potential to produce fi bres above the recordable detection limit; tailings that have undergone some drying and are in an intermediate moisture state may be vulnerable to the generation of respirable fi bres at high wind speeds; tailings that have been disturbed, whether through pulverisation or abrasion, have the potential to generate respirable fi bres at signifi cantly higher concentrations than undisturbed tailings; fi bre concentrations generated from a single disturbed source and subject to a constant wind speed will decay over time; and fi bre concentrations measured under wind tunnel conditions should not be directly related to national occupational exposure standards. The implications of this study for the mining industry are that, where asbestiform minerals are present in tailings: tailings should not be used as a construction material, it should not be excavated, traffi cked or disturbed by machinery; tailings deposition should be controlled so as to maintain the tailings in a wet state to the extent possible during deposition; and fi xed and personal monitoring should be undertakenaround the tailings storage facility to confi rm that respirable fi bre concentrations do not exceed the national occupational exposure standard. Limitations Tailings properties, their particle size and mineralogy can vary signifi cantly between sites even for the same commodity and region. The results of this testing should, therefore, not be applied directly to other sites. It is recommended that testing be carried out that is specifi c to each project under conditions that best simulate those expected in the fi eld. The current tests have not considered the effects of saltation. Saltation is a recognised mechanism for dust generation and could result in the generation of respirable fi bres that would not be generated in the absence of saltation. Further testing could be carried out using the current wind tunnel, introducing particles to the air intake stream to simulate the effects of saltation. The current tests have concentrated on whole tailings samples. Tailings that have segregated across a tailings beach will have different particle size distributions, which may make them more or less susceptible to drying, wind erosion and respirable fi bre generation. Future tests could be carried out on tailings that are subsampled from a segregated mass, to assess the infl uence of segregation. The dimensions of the wind tunnel and sample trays were limited in the current study because of the wind speeds required and the need to create a closed system, capable of safely containing respirable fi bres. The scale of the wind tunnel will affect the accuracy of the measurements. Ideally the wind tunnel and sample sizes should be as large as is possible within the constraints of the study. Dust concentration has been demonstrated to vary across the vertical profi le downstream of a fl at bed emission source (Neuman, Boulton and Sanderson, 2008). A higher profi le wind tunnel and an increased number of sample points could be used to evaluate the concentration of respirable fi bres in profi le. HIGHER FASTER – REDUCING THE DISTURBANCE FOOTPRINT Current practice It is common practice in Western Australia for tailings storage facilities to be raised using the upstream construction method. Upstream construction is characterised by using fi ll material to construct an embankment on the tailings beach, with the resultant centreline of the embankment moving in an upstream direction with each successive raise. Typically, tailings are deposited from the crest of a starter embankment to form a beach. Once the starter embankment has reached its capacity, fi ll is placed onto the tailings beach, which forms the foundation for the next embankment raise. In many cases, tailings are borrowed from the beach adjacent to the raise footprint and used as fi ll material. This process continues as the embankment increases in height. The major advantage of upstream construction is its low cost, resulting from the small embankment fi ll volume required relative to the tailings storage volume achieved. Upstream construction uses signifi cantly less fi ll than alternative construction methods, such as downstream construction (Vick, 1990). However, it relies on the need for a competent tailings beach on which to construct each embankment raise. To improve foundation conditions, tailings can be mechanically disturbed, dried or compacted to provide suitable conditions for each raise. Upstream embankment construction is used throughout Western Australia for tailings generated from a range of commodities, principally gold and nickel. The physical properties of gold tailings, and the need for the tailings to form a competent foundation, means that the rate of rise of these facilities is typically limited to between 1.5 and 2.5 m/a. This rate of rise is consistent with experience in other semi- arid areas of the world, and guidelines published by the International Committee on Large Dams (ICOLD, 1995). Currently proposed magnetite projects are expected to produce many times more tailings solids per year than the largest gold mining operations in Western Australia. These operations will require the construction of tailings storage facilities on a massive scale. A magnetite mine producing 50 Mt/a of tailings and achieving an average stored density of 1.8 t/m3, would require a minimum active tailings storage area of more than 1100 ha, to maintain an average rate of rise of 2.5 m/a. Many operations do not have an area of this size available for tailings storage. The ability to raise a magnetite tailings storage facility using upstream methods at a rate of rise higher than 2.5 m/a may have signifi cant benefi ts in terms of cost, environmental impact and operational complexity. Study approach Mundle and Chapman (2010) propose a simple indicator test for estimating the rate of rise achievable for different tailings types based on the results of air drying tests. The test provides an indicative rate of rise for tailings but does not consider the effects of consolidation or the potential for the accumulation of excess pore pressures under loading. Excess pore pressure IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 D R ANSTEY AND D A REID 38 accumulation and its effect on stability is the limiting factor when considering upstream raises at high rates of rise. Air drying test results from the magnetite tailings suggest that the tailings can achieve 95 per cent of its maximum air dry density in approximately 3.6 days. Applying the test proposed by Mundle and Chapman (2010), it is estimated that a rate of rise of approximately 5.1 m/a may be achievable for the magnetite tailings. Based on this result, a rate of rise of 5 m/a was selected for evaluation by the current study. Numerical modelling was carried out to assess whether a tailings storage facility containing magnetite tailings could be constructed at a rate of rise of 5 m/a. Modelling was carried out using the two-dimensional fi nite element software code Plaxis v9.0 (Plaxis bv, 2008). Plaxis allows the simulation of non-linear, time-dependent and anisotropic soils. In this specifi c context, the software allows us to approximate the geotechnical stability, accumulation of excess pore water pressures, deformation and settlements of an embankment that is raised in an upstream direction over time. Model geometry The model was developed to simulate an upstream-raised tailings storage facility constructed progressively over a period of 16 years to a maximum height of 80 m. The design concept is based on the rotation of tailings deposition between two active tailings cells to achieve an average rate of rise of 5 M/a. Tailings deposition is periodically diverted into a single cell while fi ll is placed on the fallow cell to construct the embankment raise. The embankment raises and starter embankments are constructed from waste rock, diverted to the tailings storage facilities by the mining operation. The use of waste rock in the embankments allows more rapid and lower cost construction than might otherwise be achievable using borrowed tailings or locally available fi ll materials. The geometry of the embankment raises is based on the need for safe and effi cient access by the mining fl eet. The starter embankment is constructed to a maximum height of 20 m, and is subsequently raised in 10 m increments every two years. The embankments are designed with a minimum crest width of 50 m. The geometry of the modelled perimeter embankment is indicated on Figure 4. The embankments are modelled with 2.5H:1V upstream and downstream slopes, constructed on a horizontal foundation. For simplicity, the tailings beaching has also been modelled as a horizontal plane with no freeboard. This simplifi cation of the model geometry is not expected to signifi cantly infl uence the results. The ‘standard fi xities’ available using Plaxis were applied to the model, with verticalboundaries constrained in the horizontal direction and the base of the model constrained vertically. Material parameters Three discrete material types were modelled: foundation, tailings and waste rock. The self weight, strength, stiffness and permeability parameters of each of the materials were based on the results of laboratory testing and experience with similar materials. The material properties assumed for the analysis are summarised, together with the soil model used for each of the materials, in Table 2. The table includes a summary of equivalent material parameters for a typical gold tailings for comparison (the relevance of the gold tailings properties are discussed later). The Soil Hardening model was used to simulate the behaviour of the tailings. The Soil Hardening model is a hardening-plasticity model that includes both shear and volumetric yield criteria. It allows modelling of the increased shear and volumetric stiffness exhibited by a soil under increasing effective pressures (ie depth). The model also allows modelling of decreasing shear stiffness of a soil under shear loading, and the generation of excess pore water pressures under strain. These particular features of the model allow the simulation of the consolidation and shear of tailings under upstream raises. The one-dimensional consolidation stiffness modulus (E oed ) of the magnetite tailings has been based on the results of consolidation testing, as plotted in Figure 5 for a range of effective stresses. These values are based on oedometer and Rowe Cell testing of the magnetite tailings. The shear stiffness (E 50 ) was based on the results of a series of triaxial tests on the tailings. The E 50 stiffness was generally found to be larger than the E oed , by a factor of about 1.5. This is within the expected range for the relationship between these two parameters as proposed by Vermeer (2001), and validates the results of testing. FIG 4 - Plaxis model geometry. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 OVERCOMING THE CHALLENGES OF MANAGING TAILINGS FROM IRON ORE MINING IN WESTERN AUSTRALIA 39 The Mohr Coulomb model has been used to simulate the behaviour of the waste rock and foundation materials. This model is appropriate for modelling the behaviour stiff materials that are not expected to yield in shear, or undergo signifi cant consolidation, as is the case for these materials. Figures 5 and 6 show the modelled stiffness and permeability relationships for the magnetite tailings. The models are based on oedometer and triaxial test data for a single magnetite tailings sample generated from pilot plant testing. The relationships are compared to those of a typical gold tailings from the Western Australian Goldfi elds. The magnetite tailings are stiffer, and more permeable than the typical gold tailings. This increased stiffness results in reduced displacement under loading, while the higher permeability allows the dissipation of excess pore water pressures to occur more quickly. As a consequence, the magnetite tailings exhibit far better engineering properties as a foundation material than comparable gold tailings. It is Parameter Magnetite tailings Typical WA gold tailings Waste rock Foundation Soil model Soil hardening Mohr-Coulomb Mohr-Coulomb Bulk density (t/m3) 2.0 1.6 to 2.0 2.3 2.5 Friction angle (degrees) 35 30 to 35 40 45 Young’s Modulus (MPa) Varies with eff ective stress, as shown in Figure 5 20 50 Vertical permeability (m/s) Varies with eff ective stress, as shown in Figure 6 1 × 10-5 m/s 1 × 10-6 m/s Horizontal/vertical permeability ratio 5 5 to 10 1 1 TABLE 2 Key model input parameters. 0 5,000 10,000 15,000 20,000 25,000 30,000 0 200 400 600 800 1000 1200 E o ed M od ul us (k P a) Effective Stress (kPa) Modelled Iron Ore Tailings Modelled Gold Tailings Iron Ore Tailings - Consolidation Test Gold Tailings - Consolidation Test FIG 5 - Modelled tailings stiff ness relationship. 1.0E 10 1.0E 09 1.0E 08 1.0E 07 1.0E 06 0 200 400 600 800 Ve rt ic al Pe rm ea bi lit y (m /s ) Effective Pressure (kPa) Modelled Iron Ore Tailings Modelled Gold Tailings Iron Ore Tailings Laboratory Values Select Gold Tailings Laboratory ValuesGold Tailings Laboratory Values FIG 6 - Modelled tailings permeability relationship. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 D R ANSTEY AND D A REID 40 the observation of these superior engineering properties that has prompted the current investigation into the potential for increased rates of construction. Modelling procedure The model is divided into discrete layers, as indicated on Figure 4. Each layer was modelled as a separate construction phase to simulate the development of the facility over time. Tailings were deposited progressively into each 10 m layer over a period of 630 days. Tailings deposition then ceased and the next stage of the embankment was constructed over a period of 100 days. Plaxis linearly increases the loading of new layers over the time interval in which they are placed. In this way, it simulates the progressive increase in loading from the embankments and tailings as they are constructed and deposited, respectively. This is an advantage over some other software codes that have been used to model upstream construction, which require that each new layer of material be placed instantaneously (Dai and Pells, 1999). The model was run in stages up to a fi nal height of 80 m. Excess pore pressures in the model were then allowed to dissipate to simulate post depositional settlement of the landform. As a point of comparison, the model of the staged embankment construction was re-run under the same conditions using the properties from the typical gold tailings. Results and discussion Figure 7 shows the fi nal deformed mesh from the model. The model indicates signifi cant displacements of the waste rock and tailings but has maintained its integrity with no signifi cant shear failure of the materials. The model indicates maximum cumulative settlements of up to 15 per cent (11.7 m) within the waste rock. However, it is predicted that most of this settlement will occur during construction of the embankments and, as a consequence, will be compensated for by the placement of additional fi ll. Some differential vertical settlement may be expected across the upstream wall raises, owing to the lower stiffness of the tailings material underlying the inside of the embankment relative to the stiffness of the waste material underlying the outside of the embankment. It is expected that differential settlements of the magnitude anticipated would be compensated for by use of well graded granular fi ll materials, such as waste rock, and the placement of additional fi ll, as required during construction. By comparison to the magnetite tailings model, the model run using gold tailings parameters experienced signifi cant shear failure during construction of the fi rst raise to the facility. Figure 8 shows the incremental displacements within the model at the time that the embankment failed. Study outcomes The study has examined the material properties of typical magnetite tailings. Finite element modelling has been used to FIG 7 - Deformed mesh for tailings storage facility model. FIG 8 - Failure of embankment raise constructed on gold tailings. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 OVERCOMING THE CHALLENGES OF MANAGING TAILINGS FROM IRON ORE MINING IN WESTERN AUSTRALIA 41 assess the potential to raise magnetite tailings storage facilities at rates of rise greater than those typically experienced for gold tailings storage facilities in Western Australia. The following conclusions can be drawn from the study: magnetite tailings exhibit high stiffness and permeability relative to other tailings types, giving them improved engineering properties as the foundation for upstream raisedembankments; and modelling suggests that it may be possible to construct safe and stable upstream raised embankments on magnetite tailings at a rate of rise at least twice that of the conventional guidance for other tailings types in Western Australia. Limitations Plaxis cannot model the impact of evaporation and desiccation of the deposited tailings on consolidation. Evaporation and desiccation typically lead to improved stiffness and strength characteristics for tailings. By excluding the infl uence of these factors, the results of the model will be conservative. The modelling does not examine the stability of the tailings under earthquake loading conditions. Earthquake loading can induce additional excess pore pressures resulting in a reduction of strength and the potential for liquefaction in tailings. Predicting the liquefaction risk of a tailings material prior to its deposition is challenging. In situ testing of an existing tailings, using experience based screening methods outlined by Youd and Idriss (2001) is generally considered the most reliable method. Cyclic testing is one available method for investigating liquefaction potential, when only tailings samples are available. Further testing could be carried out to provide input parameters to examine the effect of earthquake loading on the tailings using Plaxis. Tailings storage facilities are usually developed over a period of decades. Changes to tailings properties, mine schedules, and the observations and monitoring of the actual behaviour of the materials deposited will necessitate frequent revisions and updates to the type of analysis presented in this study. Regular in situ testing is an essential tool to confi rm and update the inputs required to assess the stability of a tailings storage facility. IMPLEMENTING THE THEORY The studies described in this paper have been undertaken to support feasibility-level studies and environmental permitting of tailings storage facilities in Western Australia. The next step is the implementation and monitoring of these solutions in practice. Wind tunnel testing has been used to demonstrate the conditions under which respirable fi bres can be generated by magnetite tailings. This information can assist designers and operators to make appropriate decisions about the conditions under which a tailings storage facility should be constructed and operated. The potential for release of asbestos fi bres poses a signifi cant risk to workers and the public. It is therefore important that the effi cacy of the controls implemented for respirable fi bres be confi rmed through appropriate monitoring in the fi eld. Personal and low volume sampling should be carried out in accordance with the NOHSC guidelines (NOHSC:2002, 2005) and monitored against Australian occupational exposure standard of 0.1 fi bre/mL (NOHSC:2002, 2005). This information should be supplemented with the results of fi xed location sampling and compared against site records of wind speed, temperature and tailings storage operation. Site monitoring data combined with emission source estimates from wind tunnel testing can be used to develop a particulate emission model for a site. Such a model could act to support an early warning system for respirable fi bres to indicate when site conditions (such as wind speed or temperature) may make working conditions unsafe or when additional controls (such as dust suppressants) may be required. Similar to asbestiform minerals, it is important that appropriate monitoring be put in place to confi rm the safety and stability of tailings storage facility embankments. Vibrating wire and standpipe piezometers should be used to monitor pore pressure accumulation in the tailings and embankments as the as the level of the tailings storage increases. These pore pressures should be compared to trigger levels determined from numerical modelling (such as that undertaken for the current study) to confi rm that the embankment maintains an acceptable factor of safety against failure. Survey monuments and photogrammetry should also be used to confi rm that deformation of the embankment is maintained within acceptable limits and is consistent with the results of modelling. CONCLUSIONS The management of iron ore tailings poses signifi cant risks and challenges to the mining industry. These risks are expected to come into particular focus in Western Australia over the coming decades as several large magnetite and CID deposits commence production. The current study has demonstrated that wind tunnel testing has a role in the measurement of respirable fi bre generation from tailings and the design of appropriate control measures. Tests carried out on a sample of magnetite tailings containing asbestiform minerals indicated little propensity for the material to generate respirable fi bres when in a saturated or dry state. However, tailings that have been disturbed, either through pulverisation or abrasion, have the potential to generate respirable fi bres at signifi cantly higher concentrations than undisturbed tailings. The results of the wind tunnel testing can be applied to the development of operating procedures and control measures for the management of tailings that contain asbestiform minerals. They can also be used in the development of dispersion models to provide confi rmation that emissions will satisfy the national occupational exposure standards. In this way, wind tunnel testing can be used to improve the safety and environmental outcomes for the operation of iron ore tailings storage facilities. Laboratory testing and numerical modelling of magnetite tailings has been carried out to justify acceptable rates of rise for magnetite tailings. The modelling suggests that magnetite tailings storage facilities can be constructed using upstream raises at rates of rise of 5 M/a, twice that of the typical guidance for tailings in Western Australia. The implications are that the footprint area, associated clearing, environmental impacts and construction costs for such a facility could be reduced by half. Where the footprint area available for tailings storage is restricted, the ability to sustain increased rates of rise using upstream construction methods provides signifi cant cost advantages over alternative construction methods, such as downstream construction. It has been demonstrated that the application of two innovative technologies to iron ore tailings can assist in the development of improved environmental and economic outcomes for tailings management in Western Australia. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 D R ANSTEY AND D A REID 42 ACKNOWLEDGEMENTS The authors would like to thank Mr Chad Mundle for the many hours spent designing, assembling and experimenting with the Golder Associates wind tunnel. We would also like to thank Dr Frank Fleer and Mr Peter Chapman for their advice and contribution to our understanding of the concepts presented in this paper. REFERENCES AS/NZS 60335.2.69, 2003. Household and similar electrical appliances – safety – particular requirements for wet and dry vacuum cleaners, including power brush, for industrial and commercial use, Standards Australia, 30 May. Dai, C and Pells, P J N, 1999. Two-dimensional large strain consolidation prediction and incrementally deposited tailings, FLAC and Numerical Modelling in Geomechanics (eds: C Detourney and R Hart), pp 123-131 (Rotterdam). Department of Mines and Petroleum (DMP), 2010. Management of fi brous minerals in Western Australian mining operations, report. International Commission on Large Dams (ICOLD), 1995. Tailings dams, transport placement and decantation, Bulletin 101, 57 p. International Commission on Large Dams (ICOLD), 2001. Tailings dams risk of dangerous occurrences, Bulletin 121, Appendix 4. Intierra Mapping, 2010. Australian iron ore mining and exploration activity,AusIMM Bulletin, No 5 October 2010. Li, C, Sun, H, Bai, J and Li, L, 2010. Innovative methodology for comprehensive utilization of iron ore tailings: Part 1, The recovery of iron from iron ore tailings using magnetic separation after magnetizing roasting, Journal of Hazardous Materials, 174(1-3):71-77. Mehta, R D and Bradshaw, P, 1979. Design rules for small low speed wind tunnels, The Aeronautical Journal of the Royal Aeronautical Society, pp 443-449. Mundle, C A G and Chapman, P J, 2010. Selection of parameters for semi-arid tailings storage facility design, in Proceedings First International Seminar on the Reduction of Risk in the Management of Tailings and Mine Waste (University of Western Australia). National Occupational Health and Safety Commission (NOHSC):2002, 2005. Code of practice for the safe removal of asbestos, second edition, April. National Occupational Health and Safety Commission:3003, 2005. Guidance note on the membrane fi lter method for estimating airborne asbestos fi bres, second edition, April. Neuman, C M, Boulton, J W and Sanderson, S, 2008. Wind tunnel simulation of environmental controls on fugitive dust emissions from mine tailings, Atmospheric Environment, doi:10.1016/j. atmosenv.2008.10.011. Plaxis bv, 2008. Plaxis 9.0 professional version. Vermeer, P A, 2001. On the parameters of the hardening soil model, Experienced Plaxis Users, 26 - 28 March. Vick, S G, 1990. Planning, Design, and Analysis of Tailings Dams (Bitech Publishers: Vancouver). WISE Uranium, 2011. Chronology of major tailings dam failures [online]. Available from: <http://www.wise-uranium.org/mdaf. html> [Accessed: 1 February 2011]. Youd, T L and Idriss, I M, 2001. Liquefaction resistance of soils: summary report from the 1996 NCEER and 1998 NCEER/NSF Workshops on Evaluation of Liquefaction Resistance of Soils, Journal of Geotechnical and Geo-environmental Engineering, ASCE, 127(10):297-313. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 43 INTRODUCTION Iron Ore Holdings Ltd (IOH) is an emerging junior iron ore company based in Perth that is actively exploring tenements in the Central and Western Pilbara region of Western Australia. The company has a number of iron ore deposits in the Pilbara region, and the Phil’s Creek Project was the f rst tenement to undergo the approvals process. The proposal attained approval, but the Project has now been placed on hold by IOH. The Phil’s Creek iron ore resource is located approximately 90 km north-west of Newman and 140 km east of Tom Price in the East Pilbara region of Western Australia. The project was to consist of a shallow open cut mine located above the water table, producing approximately seven million tonnes of crushed and screened iron ore product over a f ve year period (1.5 Mt/a). An ore crushing plant, associated mine infrastructure and a small accommodation village were also to be constructed on-site. URS Australia Pty Ltd (URS) has been assisting IOH since mid-2008 with preparation of environmental assessment documents. IOH has faced several challenges in the environmental assessment process for the Phil’s Creek Project, some of which led to signi f cant delays in f nalising environmental approvals. Two major environmental challenges involved the environmental assessment of potential impacts on troglofauna and vertebrate fauna, and working with State and Commonwealth regulators through these processes. As a result of meeting and overcoming these and other challenges in the environmental assessment process, IOH has gained useful knowledge of the current requirements of regulators, particularly in relation to developing environmental offsets and impact assessment of troglofauna. Using the Phil’s Creek Project as a case study, this paper will discuss the challenges IOH faced in the environmental assessment process and the steps undertaken to overcome them. These challenges are generic to the mining industry and, undoubtedly, all proponents of signif cant developments. BACKGROUND The Phil’s Creek Project is located in close proximity to numerous iron ore mines in operation and exploration phases in the Pilbara region, but is remote from urban settlements. 1. Senior Environmental Scientist, URS Australia Pty Ltd, Level 4, 226 Adelaide Terrace, Perth WA 6000. Email: hannah_fl etcher@urscorp.com 2. Principal Environmental Scientist, URS Australia Pty Ltd, Level 4, 226 Adelaide Terrace, Perth WA 6000. Email: jenny_moro@urscorp.com Iron Ore Holdings Ltd – Case Study of the Environmental Approval Challenges for an Emerging Junior H Fletcher1 and J Moro2 ABSTRACT Iron Ore Holdings Ltd (IOH) is an emerging junior iron ore company that is actively developing projects in the Central and Western Pilbara region of Western Australia. IOH commissioned URS Australia Pty Ltd (URS) in mid-2008 to prepare environmental assessment documents for the Phil’s Creek Project, which was rapidly moving into the development phase. This project comprised a small open cut iron ore mine that was expected to deliver approximately seven million tonnes over a f ve year mine life. IOH faced several challenges in the environmental assessment process for the Phil’s Creek Project. Although the Phil’s Creek Project attained approval but has now been placed on hold, it is a useful case study to discuss these challenges and how IOH addressed them. Several important lessons were learned through this process that can assist other proponents in addressing environmental challenges in a constructive and proactive manner. One major challenge faced by IOH related to the endangered northern quoll ( Dasyurus hallucatus). Another challenge was the unusually high species richness of troglofauna recorded within the project area, with several species initially known only from within the proposed pit footprint. Meeting and overcoming these challenges has provided IOH with an increased understanding of the level of input required for consultation with government departments regarding environmental assessments, and this should stand the company in good stead for developing future tenements. Challenges in regards to the environmental assessment process may be faced during future developments, but IOH’s experiences to date and the lessons learned from the Phil’s Creek Project, will help pave the way for successfully overcoming them. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 H FLETCHER AND J MORO 44 The iron ore deposit is located within a green f elds site which is typical for the East Pilbara region, being characterised by rocky hills, small gorges, seasonal watercourses and gravelly loams. The current land use is pastoral and approximately 100 ha of vegetation was proposed be cleared within a 170 ha envelope for the Project. In order for IOH to construct and operate the Phil’s Creek Project, IOH was required to seek environmental approval under the Environmental Protection Act 1986 (EP Act) and the Environmental Protection and Biodiversity Conservation Act 1999 (EPBC Act). A number of baseline environmental studies were undertaken for the Project for the environmental impact assessment, ranging from biological baseline studies of f ora and fauna, to noise and waste characterisation assessments. Projects that are likely to have a signi f cant impact on a number of environmental factors or where there is strong public or community interest in the project, usually require formal assessment under Part IV of the EP Act. During initial scoping of the Project, it was thought unlikely that the Project would meet the criteria for formal assessment; however this needs to be determined via referral to the Western Australian Environmental Protection Authority (EPA). The EPA determined that the Project did not require formal assessment, instead requiring assessment under Part V of the EP Act as a works approval and licence, a clearing permit and assessment under theMining Act 1978 as a Mining Proposal. IOH also undertook a desktop EPBC Act protected matters search in order to determine the requirement for referral under the EPBC Act. Whilst the protected matters search identif ed that a number of threatened species may occur in the vicinity of the Project area, (including the endangered northern quoll [ Dasyurus hallucatus]) the size and scope of the Project, as well as identi f cation of minimal impact on known northern quoll habitat, suggested that Project impacts would not be signi f cant. Nevertheless, IOH decided to refer the Project to the DSEWPaC in order to provide company certainty that IOH would not contravene the EPBC Act if a referral was not made, and also to mitigate against time delays if a third party referred the Project before IOH. The Commonwealth Minister for Environment determined that the potential presence of the northern quoll was suff cient to make the Project a controlled action and require assessment under the EPBC Act. This decision was unexpected, and highlights the low level of tolerance of the DSEWPaC to even potential impacts on species having an endangered status at the Commonwealth level. This assessment became one of the major challenges of the Phil’s Creek Project in meeting company timelines. APPROVAL CHALLENGES AND SOLUTIONS IOH faced a variety of challenges during the environmental assessment process of the Phil’s Creek Project. The challenges discussed in this paper are: scoping environmental assessment studies at a time when the proposal is still under development, regulator perception of a new operator into the iron ore industry, ensuring that all project team members understand their contribution to facilitating the environmental assessment process, the State environmental assessment process in regards to potential impacts on subterranean fauna (troglofauna), and the Commonwealth environmental assessment process in regards to potential impacts on an endangered species (the northern quoll). This section details how these challenges impacted IOH in regards to the Phil’s Creek Project, and the steps that IOH undertook to reach a solution to each of these challenges. Challenge 1: project scoping The f rst challenge of the Phil’s Creek Project was to scope the environmental assessment of the Project, at a stage when the Project description was not fully developed. IOH also required price certainty in relation to study costs and a relatively f rm assessment timeline in order for the Project to be ready for construction by a set date. All projects are challenged by the need to initiate the environmental assessment process while the project engineering design is still being completed, and the two processes often occur in parallel. IOH commissioned URS to prepare an environmental scoping study to identify what the environmental factors of greatest risk to the Project were likely to be, as well as potential risks to the Project associated with obtaining environmental approval. The purpose of the environmental scoping study was to provide IOH with an initial understanding of the key environmental factors that needed to be addressed early in Project development. It also provided IOH with indicative costs and timing for a range of baseline studies to be undertaken. A preliminary risk assessment was undertaken to identify all risks to the Project including, but not limited to, environmental approvals. The risk assessment was held as a workshop with personnel from different disciplines participating, which encouraged information sharing amongst the wider Project team. A bene f t of the risk workshop was that it identi f ed what the greatest time and budget constraints of the Project were likely to be and enabled IOH to establish which studies were on the critical path for development. Importantly, the risk assessment identi f ed that both subterranean fauna and vertebrate fauna posed a high to medium risk to the Project. These are discussed below as additional challenges to the Project. Early identi f cation of costs enabled IOH to budget appropriately for the baseline studies as part of the overall Project costs. IOH also recognised during Project scoping that as the study of subterranean fauna is still a new science, additional budget for this baseline study may be required. In the event, additional troglofauna studies were subsequently required and the provision of a budget contingency by IOH allowed the assessment to proceed without delay. The project scoping phase and risk assessment provides benef t to all companies as a f rst step in developing a project, even at an early stage of the project description, as it identif es key risks and establishes the critical path for development. The project scoping phase should identify the likely project environmental costs and timing to enable early budget planning and project scheduling. It is recommended that a budget and timing contingency is established for high risk environmental factors in case additional studies are required at a later date. Challenge 2: company track record Lack of track record in managing environmental issues is a challenge that is dif f cult for any new company to overcome; especially as environmental assessment documentation seeks information from companies regarding their environmental reputation and compliance record. For example, the DSEWPaC IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 IRON ORE HOLDINGS LTD – CASE STUDY OF THE ENVIRONMENTAL APPROVAL CHALLENGES FOR AN EMERGING JUNIOR 45 referral form requires the company proposing to develop a project to provide information regarding their environmental history. This includes whether the company has a satisfactory record of responsible environmental management, if the company has ever been subject to proceedings under a Commonwealth law for the protection of the environment, and if the company will ensure that the project is undertaken in accordance with its environmental policy and planning framework. In the absence of any existing environmental record, IOH engaged URS to prepare environmental assessment documents and to initiate consultation with government regulators until IOH established relationships with key personnel. IOH fostered its relationship with government regulators by attending key meetings, which also showed the company’s commitment to the environmental assessment process. The role of experienced environmental professionals is essential to introducing a new proponent to environmental regulators and to facilitating the approvals process. A strong co-operative partnership that seeks contributions from all appropriate disciplines can foster better environmental outcomes. During preparation of the Mining Proposal for assessment by the Department of Mines and Petroleum (DMP), the IOH Project team took the lead in developing environmental commitments for the Project. The involvement of IOH’s geology and engineering personnel in this process enhanced corporate understanding of the role that other disciplines can have in fostering better environmental outcomes. This contribution ensured that the environmental commitments which IOH developed were realistic and achievable for the company. The commitments also demonstrated that IOH was taking environmental matters seriously and took into account prior agreements with stakeholders. The involvement by other disciplines in this process can also encourage positive environmental attitudes that are carried forward into the development and operational phases of a project. Ultimately, a company track record and reputation for responsible environmental management is built by involvement of the company project team, with support at management level. Management needs to demonstrate that environmental commitments will be taken seriously and these attitudes f lter down to other levels of an organisation.An added bene f t from the Phil’s Creek Project was that management were part of the Project team and therefore gained a f rst-hand experience of regulatory processes and regulator expectations. Challenge 3: environmental knowledge As a junior mining company moving from exploration to project development, IOH had a small exploration and development team with mainly geology and engineering backgrounds, but no in-house environmental team. This was a challenge to IOH because following completion of the scoping study the Project was rapidly progressing beyond exploration, and baseline studies were ready to be commenced. To address this challenge, IOH engaged a single consultant to manage baseline surveys and commence preparation of the Project environmental assessment documents in order to f ll the gap in company environmental knowledge. By engaging URS who has experience with undertaking environmental assessments for mining projects, IOH was able to utilise URS’s prior experience with preparing environmental impact assessments for iron ore projects. URS was also able to initiate consultation with government regulators until IOH established a relationship with government staff. During the early stages of commencement of baseline studies, IOH chose to second two URS environmental personnel to work full time on the Project. A secondment can provide many bene f ts, such as creating a team environment where environmental information is shared, and enable Project tasks to be re-prioritised according to changing business needs. Throughout this Project, the IOH Project team sought advice from URS on any changes to regulatory requirements that could affect the Project. This gave IOH an early and ongoing understanding of the complexities within the environmental assessment process and the changing level of effort required to meet regulators expectations. A key aspect of the success of this approach is for proponents to select a single consultant as their environmental project manager. Experience during the previous mining boom was that a number of proponents retained multiple environmental consultants but without clear accountability. This meant that as project delays or cost overruns occurred it was sometimes diff cult to determine which consultant was accountable. By selecting a single consultant to project manage environmental approvals IOH were always able to establish for a single point of contact regarding any project delays or cost over-runs. Understanding environmental constraints and requirements is an ongoing challenge, but seconding environmental consultants can f ll a gap in client knowledge, especially in the early stages of a project. For a small company, the incorporation of the wider project team in key meetings and workshops can lessen the likelihood of oversights in project design and creates a greater awareness of key environmental constraints. It can also be an opportunity to think about how a change to the project design could impact upon the environment and vice versa. It is important for proponents to be mindful that the environmental assessment process is typically a dynamic process, and does not always follow a logical pathway like engineering. This can be a challenge to new companies, and requires a f exible approach by the project team as well as good communication between the project teams and management. Challenge 4: State environmental assessment of troglofauna Troglofauna are air-breathing subterranean fauna living underground in the air spaces within small f ssures and cavities of the underground matrix, and differ from the other type of subterranean fauna, stygofauna (Bennelongia, 2009). Stygofauna are aquatic and live in air spaces in the small f ssures and cavities in groundwater aquifers (Bennelongia, 2009). Troglofauna are most signif cantly impacted by loss of habitat (excavation and mining of an ore deposit), whilst stygofauna and are predominately impacted by changes to groundwater such as from mine dewatering. A troglofauna assessment was deemed necessary for this Project due to excavation of the pit which would remove and disturb troglofauna habitat. As no groundwater is proposed to be abstracted for this Project, a stygofauna assessment was not required. Obtaining an approval decision from the State regulators in regards to potential impacts on troglofauna was a major environmental challenge to the Phil’s Creek Project proceeding. This is because the study and assessment of subterranean fauna (particularly troglofauna), is still a relatively new science and there is often uncertainly about what level of sampling effort is acceptable to regulators. There is also the additional challenge that proponents often require troglofauna studies to be initiated while the project description is still being developed. This may result in a change to the IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 H FLETCHER AND J MORO 46 project footprint and therefore a change in potential impacts to troglofauna later on in the project. The EPA has issued a guidance statement that advises proponents on what time of year to undertake troglofauna surveys and the minimum number of samples required (Environmental Protection Authority, 2007). If sampling is undertaken in accordance with this guidance statement, the level of effort is usually accepted by the EPA as an adequate initial investigation of troglofauna. However, the body of scientif c data on troglofauna is still relatively small and there is uncertainty at the project scoping stage on whether or not a particular project site will encounter troglofauna conservation issues. This often leads to the requirement for multiple sampling phases over months or years. For the Phil’s Creek Project, the initial troglofauna sampling recorded an unusually high species richness within the Project area, with several species known only from within the proposed pit footprint. IOH consulted with the Department of Environment and Conservation (DEC) after the preliminary troglofauna results and sought advice on how to proceed. IOH encountered a few site issues with the additional troglofauna sampling, such as exploration boreholes that were unsuitable for sampling and constraints imposed on sampling locations due to existing Aboriginal heritage agreements. However, consultation with the DEC resulted in agreement being given to IOH to obtain further samples from other IOH tenements within close proximity of Phil’s Creek, in order to support the environmental impact assessment. This challenge was f nally addressed when the DEC advised that no further sampling was required. Troglofauna is currently a key environmental issue for regulators and in order for a company to undertake an acceptable troglofauna survey, early and ongoing consultation with the DEC is required. The DEC provides advice on whether the survey methodology is acceptable before time and money is spent, and provides comment on survey reports prior to inclusion in environmental assessment documents. Proponents need to be aware at project scoping that subterranean fauna surveys, and troglofauna surveys in particular, can take considerable effort in order to demonstrate that a project will be environmentally acceptable. Studies should commence early in project development as sampling may take greater than a year to collect the required data – for example six rounds of sampling occurred over a 16 month period for the Phil’s Creek Project. The best case scenario is that initial troglofauna studies commence as early as possible; then if additional studies are undertaken they are able to be undertaken concurrently with other baseline studies, to ensure the overall timing of the project is not compromised. Adequate money also needs to be allocated by proponents to undertake troglofauna sampling and consult with regulators. It is recommended that a contingencybudget is put aside in the event that additional studies are required, as was the case for the Phil’s Creek Project. Challenge 5: Commonwealth environmental assessment of the northern quoll Obtaining an approval decision from the Commonwealth regulators in regards to vertebrate fauna (the northern quoll) was another major environmental challenge to this Project proceeding. During Project scoping, IOH identif ed that there was a high risk that a third party (such as a stakeholder) may refer the Project to the DSEWPaC following referral to the EPA, and this would lead to Project delays. Following a legal review, IOH chose to refer the Project to the DSEWPaC even though the Project did not appear to meet the criteria for assessment under the EPBC Act as a controlled action. IOH referred the Project to the DSEWPaC at the same time as the referral to the EPA was submitted. The decision for making the referral was both to ensure a greater level of company certainty that the Project did not require assessment by the DSEWPaC, and to avoid the risk of a third party referring the Project before IOH had to a chance to make a referral. As discussed above, the EPA determined that the Project did not require formal assessment under Part IV of the EP Act and could be assessed under a lower level of assessment by the DMP and DEC. Projects that require assessment by the EPA are more likely to also be controlled actions requiring assessment under the EPBC Act. Such projects are usually large-scale developments with a greater likelihood of having signif cant environmental impacts. For the Phil’s Creek Project, however, the assessment levels were different between the EP Act and the EPBC Act. The controlled action decision by the DSEWPaC was based on the likelihood of the Project having a signi f cant impact on the endangered northern quoll ( Dasyurus hallucatus ). The decision was appealed because the northern quoll was not recorded in or around the Project area during the baseline f eld survey and the vertebrate fauna report stated that there were no vertebrate fauna habitats of local signif cance present within the Project area (Western Wildlife, 2009). However, the decision was upheld and IOH was required to development a speci f c research plan to minimise, manage, mitigate and offset potential impacts on the northern quoll. The decision to make the Project a controlled action was not foreseen by IOH or URS and this presented challenges to the approvals timeline. IOH sought clari f cation from the DSEWPaC during the assessment process regarding the Project’s potential impact on the northern quoll, as the 100 ha proposed to be disturbed for the Project did not appear to constitute a signi f cant impact on a species that was not known to occur in the vicinity of the Project area. IOH assessed that only f ve ha of potential northern quoll habitat was present in the Project area (and therefore potentially disturbed), and sought comment from the DSEWPaC if this constituted a signi f cant impact. However, the DSEWPaC determined that the entire area of disturbance of the Project had the potential to impact upon the northern quoll. The DSEWPaC further advised during consultation that it was concerned about impacts on the northern quoll in the entire Pilbara region due to a retraction in the species range over the north of Australia, from impacts such as predation from the cane toad, infectious diseases and inappropriate burning regimes, which were threatening the species survival. After the Project was approved, IOH and URS became aware of a draft internal DSEWPaC guideline for signi f cant impacts on the northern quoll, which likely formed the basis for the DSEWPaC’s decision. Although not published, it is highly likely that all future projects in the Pilbara region will be affected by this guideline as the DSEWPaC has determined that the entire Pilbara region is potential northern quoll habitat. The outcome of this decision identif es that the DSEWPaC is exhibiting a low level of tolerance on impacts to endangered species from the development of projects. The DSEWPaC appears to be taking a conservative approach in regards to potential impacts to endangered species that may only IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 IRON ORE HOLDINGS LTD – CASE STUDY OF THE ENVIRONMENTAL APPROVAL CHALLENGES FOR AN EMERGING JUNIOR 47 potentially occur in an area, and making its assessment decision accordingly. Therefore, proponents should be aware that regardless of the scale of a development, if a project is located in the Pilbara region, it may meet the criteria to be a controlled action under the EPBC Act and this should be factored into project timing and cost. Indeed, wherever the desktop EPBC Act protected matters search identi f es the possible presence of endangered species, proponents should be aware of the potential for the project to be assessed as a controlled action regardless of the extent of any impact. A contributing factor during environmental impact assessment was that the DSEWPaC identif ed a relatively high degree of uncertainty as to the behaviour and habitat of the northern quoll in the Pilbara. Therefore even though only f ve per cent of the disturbance area was identi f ed as being probable northern quoll habitat, the DSEWPaC recommended a precautionary approach to the other 95 per cent of the Project area in making their recommendation to the Minister. The DSEWPaC also advised IOH that the baseline vertebrate fauna survey undertaken for the Project did not meet its preferred timing, even though the survey was undertaken in accordance with the EPA’s guidance statement timing and methodology. It will therefore be important for proponents to discuss the proposed timing for vertebrate fauna surveys with the DEC and/or the DSEWPaC prior to undertaking any f eld work, to ensure that it also meets the DSEWPaC’s preferred timing. Further challenges were met during assessment under the EPBC Act, with the greatest challenge being uncertainty regarding the total time that the assessment would take. IOH had to re-prioritise some other tasks undertaken by the Project team in order to focus on the assessment process. Also, some aspects of the assessment under the EPBC Act do not have statutory time frames, such as IOH being responsible for preparing advertisement of the Project for public comment, which took additional time. To try and limit the time this assessment would take, IOH and URS followed up the DSEWPaC assessment of f cer on a regular basis to ensure that progress was being made on the Project and to address any issues at early stage. A win-win of the assessment process was that the DSEWPaC sought feedback from IOH and URS on the recommended draft conditions. Although this took some time to negotiate, it was benef cial to IOH to be given the opportunity to comment and make revisions on the draft recommended conditions for the Project. IOH was able to seek amendments to the wording of some approval conditions to ensure that the conditions of the Project did not unreasonably constrain the company, whilst still meeting the DSEWPaC’s expectations. Importantly, the environmental offset required as conditional approval of the Project by the DSEWPaC did not involve a like-for-like land swap, and involved a number of actions to be undertaken throughout the life of the Project. The offset conditions required a f nancial commitment over a three-year period to implement a research study on the northern quoll speci f cally in the Pilbara region, as well as undertaking staff induction and environmental awareness programs, maintaining a threatened species register, and retaining buffers of undisturbed land along drainage lines (potential northern quoll habitat). Proponents therefore need to consult with regulators and species experts in order to determine the key factorsthat may be addressed as part of the offsetting process. Overall, the main challenge of being assessed by the Commonwealth was that it was identi f ed during the project scoping phase that assessment under the EPBC was unlikely, as the Project did not appear to meet the EPBC Act assessment criteria. Although the Project was assessed at the lowest level of assessment by the DSEWPaC, the process was time consuming and took a total of ten months, which ultimately impacted on Project timelines. However, IOH could not have taken the risk that a third party would refer the Project to the DSEWPaC and could not have been aware of the DSEWPaC’s internal position on the northern quoll. For future projects, IOH will consult with the DSEWPaC early in the scoping process after having undertaken a desktop EPBC Act protected matters search. Where DSEWPaC advise that a controlled action may be required, IOH will allow appropriate time and budget for assessment under the EPBC Act, regardless of size and potential impacts. LESSONS LEARNT This paper has used the Phil’s Creek Project as a case study to discuss the challenges facing an emerging iron ore company. Through meeting the challenges that IOH has faced, the company has attained key lessons regarding the complexities of the Western Australian and Commonwealth environmental assessment processes, and identi f ed how to proactively and eff ciently overcome these challenges for future projects. These lessons gained are not unique to the Phil’s Creek Project or to IOH, and apply to all iron ore companies. They include the following: Undertake an early multi-disciplinary risk assessment for all factors, including environmental, at the project scoping stage. Ensure appropriate time and budget contingencies are allocated. The use of established consultants and involvement of key project team members in consultation with government regulators can assist to allay regulator concerns. Consult early and often with regulators as this promotes buy- in of the environmental aspects of the project to the government regulators, and builds the relationship with key government staff for future projects. It also ensures that the government assessment of f cer remains familiar with the project when future discussions are held. Proponents cannot pre-empt a regulator’s decision on whether or not to assess a project, and need to factors in contingencies. However, early proactive consultation with regulators especially following identi f cation of key environmental factors, should help to quantify contingency requirements. Where a proponent does not have internal expertise it is recommended that they appoint a single consultant as their environmental project manager. Secondment of consulting staff at an early stage allows project dedicated staff to build strong relationships with the company’s team. Maintain awareness that emerging environmental factors (such as species being placed on the endangered species list) may lead to project delays, until a suf f cient body of knowledge is available to allow some level of predictability in assessment outcomes. Develop environmental commitments at a company level with the support of environmental specialists where required, to ensure that the commitments are realistic and achievable for the company. Build a positive environmental awareness company-wide from project concept to development. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 H FLETCHER AND J MORO 48 Proponents need to be adaptable to project changes following the development phase, such as modifying the project design at the suggestion of regulators during consultation or recommendations from subconsultants in baseline reports. Proactively consult with regulators and topic experts in order to understand key environmental factors. This will provide proponents with an understanding of the potential options for management, mitigation and offset of these key environmental factors. It has been discussed that during the environmental assessment process there are often competing project demands. A proponent needs to design a project in enough detail in order for it to be acceptable for environmental assessment, as well as being f exible enough to make design changes as business demands change or as required during consultation with regulators and other stakeholders. Adaptive management therefore became a solution to many of IOH’s Project challenges. If proponents adequately scope a project for the required environmental studies and assessments, allow for realistic costs and time frames for undertaking studies and preparing assessment documents, and are f exible enough to modify aspects of the project design as potential environmental issues arise, this can ultimately streamline the environmental assessment process. The challenges discussed are ones that exist for all mining companies, particularly in the Pilbara region, and the lessons learnt are intended to help all proponents successfully overcome these and other challenges. ACKNOWLEDGEMENTS The authors would like thank a number of people for their valuable assistance in helping to get this paper submitted. Firstly, past and current members of the IOH Project team for being supportive of this paper and their willingness to assist with the wording of the paper. Thank you to the current URS Project team, many of who assisted with developing the structure of the paper and conducting reviews, particularly Karen Ariyaratnam, Donna Pershke, Mark Goldstone, Madolyn Morel and Beverley Turner. Thanks also to the previous members of the URS Project team for suggesting paper topics and undertaking reviews of information, particularly Diana Oates, Tanya Carpenter and Blair Hardman. REFERENCES Bennelongia Pty Ltd , 2009. Iron Ore Holdings Ltd Phil’s Creek Project: Troglofauna Assessment, report 2009/70, prepared for URS Australia Pty Ltd on behalf of Iron Ore Holdings Ltd, December 2009. Environmental Protection Authority , 2007. Guidance for the assessment of environmental factors: sampling methods and survey considerations for subterranean fauna in Western Australia (draft) No 54Aa, technical appendix to Guidance Statement No 54 (Environmental Protection Authority, August 2007). Western Wildlife , 2009. Phil’s Creek Project Area: fauna survey 2008, prepared for URS Australia Pty Ltd on behalf of Iron Ore Holdings Ltd, May 2009. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 49 INTRODUCTION Reserves of high-grade iron ores are reducing all over the world; a result of the increase in demand for steel historically from Japan, India and more recently China. Benefi ciation techniques for iron ores are receiving world-wide attention due to development of new deposits of lower grade ore to satisfy the demand. The recovery of mineral value from the low-grade ores is more expensive than selling direct shipping ores (DSO) ores, due to higher energy costs of liberation and separation as well as capital costs, requiring the use of benefi ciation to produce high-grade concentrates from low grade ores. Benefi ciation can be defi ned as a variety of processes whereby extracted ore is separated, by physical means, into mineral and waste streams. Most benefi ciation operations will result in the production of three materials: 1. a saleable concentrate; 2. a middlings product (a low-grade stream that is either reprocessed or stockpiled); and 3. a tailing stream, which is discarded. To maintain a constant quality ore, companies need to differentiate ore grades more carefully and upgrade and blend grades produced in the mines. Because of the more diffi cult processing of this lower grade compared to the iron ores currently being processed, more modern technology will have to be considered. The most energy intensive stage, the reduction step in the blast furnace, is mainly drivenby the requirement of carbon as a reducing agent. In order to diminish the environmental impact, careful control of the phases involved in the process is important for minimising the energy consumption. Elemental analysis such as XRF or wet chemistry of samples are essential in the characterisation of iron ore feedstocks (and their sintered products), but since the metallurgist is almost always faced with the task of separating and concentrating minerals rather than elements, the mineralogy assumes great importance at an early stage. However, the mineralogy of the sample is often not considered or at best inferred from visual geological logging of the sampled material. As such, mineral contaminants that cannot be identifi ed visually and/or by chemical analysis alone are often not quantifi ed. For example the identifi cation of gibbsite via chemical data is typically problematic, being complicated by the co-occurrence of kaolinite and aluminous goethite. The correct identifi cation of gibbsite is important as gibbsite can have a signifi cantly adverse impact on sinter effi ciency of the iron ore with gibbsite-bearing ores being likely to require longer sintering times and higher sintering temperatures to promote melt formation. This is due to the poor reactivity of this type of alumina and the high viscosity of the primary melt formed. As a result fuel rate is reported to increase and the sintering productivity to decrease as the alumina content increases (Yamaoka, 1974; Lu, Holmes and Manuel, 2007). A further benefi t of resolving the mineralogical composition of iron ore is to optimise concentrator feed. Four gangue-related minerals are common to iron ores; kaolinite (Al 2 Si 2 O 5 [OH] 4 ), quartz (SiO 2 ), Gibbsite Al(OH) 3 and aluminous goethite ([Fe 1-2 Al 2 ]O[OH]). Kaolinite, being typically hosted by shales within the ore, is the typical mineral liberated during typical wet concentration. Quartz and aluminous goethite are much less susceptible. It is therefore important to determine the 1. Application Specialist XRD, PANalytical BV, Lelyweg 1, 7600 AA Almelo, The Netherlands. Email: uwe.konig@panalytical.com 2. Application Specialist XRD, PANalytical BV, Rua Jose de Carvalho, 55 04714-020 Sao Paulo SP, Brazil. Email: luciano.gobbo@panalytical.com 3. PANalytical BV, 1117 Flanders Road, Weatborough MA 01581, USA. Email: Kathy.macchiarola@panalytical.com Using X-Ray Diff raction for Grade Control and Minimising Environmental Impact in Iron and Steel Industries U König1, L Gobbo2 and K Macchiarola3 ABSTRACT The use of high speed detectors made X-ray diffraction (XRD) an important tool for quality and process control in the mining industries. Besides knowledge about the mineralogy of a sample it provides useful information in terms of quantifi cation of the crystalline phases and the amorphous content. Cluster analysis of XRD data can facilitate multi-dimensional mapping of ore deposits and drill cores, identifying regions of favourable mineral compositions. The studies of this paper demonstrate how XRD and data clustering can be used for grade control, process optimisation and quality control of iron ores and iron ore sinters. These new developments have an enormous potential as an inexpensive, reliable tool, useful in the characterisation of iron and sinter materials implemented in an industrial environment. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 U KÖNIG, L GOBBO AND K MACCHIAROLA 50 proportions of kaolinite, quartz, gibbsite and aluminous goethite in the iron ore so that certain phases do not separate in the concentrator. METHODS X-ray powder diffraction (XRD) is a versatile, non-destructive analytical method for identifi cation and quantitative determination of crystalline phases present in powdered and bulk samples. The identifi cation of phases is achieved by comparing measured diffraction data to a reference database, the most comprehensive database is maintained by the International Centre for Diffraction Data (ICDD). This is a standard technique for qualitative analysis of mineralogical phases, but quantitative methods were often diffi cult since they require pure phase standards. Modern quantifi cation analysis techniques such as Rietveld analysis are attractive alternatives, as they do not require any standards or monitors (Rietveld, 1969). These methods offer impressive accuracy and speed of analysis. Modern XRD equipment is also capable of producing data of suffi cient quality for Rietveld analysis in just minutes, instead of an hour or more with traditional detectors, making it more amenable to process control, Macchiarola et al (2007). A typical Bragg-Brentano confi guration as it is used for the analysis powder materials is show in Figure 1. The set- up consist of an X-ray source, a spinning sample stage for optimising counting statistics, a high speed linear detector and several optics for optimising the quality of the data output. To handle the large amount of data coming from the rapid data collection using the X’Celerator detector, ‘cluster analysis’ is a useful tool to group different grades of ore or materials into groups (clusters). This statistical method simplifi es the analysis of the data by: automatically sorting all scans from one or more ore samplings experiments into classes of closely related scans (clusters), identifying the most representative scan of each class, identifying the two scans of each class that differs most, and identifying outliers not fi tting into any class (non- members). The method can be used for sorting different grades of materials, such as ores with different mineralogy and thus predicted process behaviour. In the current study, in order to determine the crystalline phase content of the iron ore feed and iron ore sinter samples analysed, pressed powder pellets were prepared. Sample preparation is an important issue to obtain correct results as it is a primary source of errors in the quantifi cation (Klug and Alexander, 1954). For that reason all samples were prepared using automatic sample preparation equipment for minimised preferred orientation and to maintain a constant preparation for all samples. All powder samples were milled for 30 seconds and pressed 30 seconds with ten ton into steel ring sample holders. For the studies presented in this paper, a CubiX3 Minerals industrial diffractometer with Co anode and high-speed X’Celerator detector was used, featuring measurement times of less than ten minutes per scan generally. Grade control of iron ores – analysis of iron ore feed Over 300 minerals contain iron but there are only fi ve minerals considered commercial sources of iron: 1. magnetite (Fe 3 O 4 ), 2. haematite (Fe 2 O 3 ), 3. goethite (FeOOH), 4. siderite (FeCO 3 ), and 5. pyrite (FeS 2 ). The best iron ore does not always have the highest iron content, but rather may have the least amount of impurities that are diffi cult to remove. Common impurities present in an iron ore are: silica (SiO 2 ) (almost always present), phosphorous (P), alumina (Al 2 O 3 ), sulfur (S), calcium carbonate (CaCO 3 ), and manganese oxide (MnO 2 ) (especially in haematite). The quality of iron ore is defi ned by the total iron content as well as the above mentioned impurities, but also the quantitative content of iron containing phases and gangue minerals such as quartz (SiO 2 ), kaolinite (Al 2 Si 2 O 5 (OH) 4 ), gibbsite (Al(OH) 3 ) or calcite (CaCO 3 ). Quantifi cation of these minerals gives important information for downstream processing treatments (eg sintering). The analysis of Al containing phases, especially of Al containing goethite, are useful for the grade differentiation since the removal of Al from the ore is time, energy and cost intensive depending on which mineral the Al is bound. Figure 2 shows a magnifi ed view of themeasurement of 60 iron ore samples from one deposit in Western Australia. Besides different amounts of the main ore minerals haematite FIG 1 - X-ray diff raction setup for powder measurements, Bragg-Brentano geometry. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 USING X-RAY DIFFRACTION FOR GRADE CONTROL AND MINIMISING ENVIRONMENTAL IMPACT IN IRON AND STEEL INDUSTRIES 51 and goethite some samples also contain signifi cant amounts of kaolinite, quartz, gibbsite and calcite. Before quantitative Rietveld analysis was applied on these samples, the data set was used for a cluster analysis to fi lter the different ore grades with varying mineralogy. The Principle Component Analysis (PCA) plot in Figure 3 indicates clearly three different clusters and some outliers. Together with the results of the Rietveld quantifi cation of all samples three different grades of iron ore material could be defi ned. Table 1 shows the minimum, maximum and average modal abundances of the samples analysed. The three ore grades are: 1. high-grade – medium haematite, high goethite, low gibbsite, kaolinite, quartz; 2. low-grade – medium haematite, low goethite, high gibbsite, kaolinite, quartz; and 3. medium-grade – low haematite, high goethite, medium gibbsite, kaolinite, quartz. The results of the quantifi cation of all 60 samples are plotted against the cluster number to visualise the different grades (Figure 4). The defi nition of the different clusters with different ore materials and phase contents can be used for a quick automated grade control (pass/fail analysis). Once the cluster defi nitions are set-up, a new measurement can be sorted into one of the cluster and the corresponding material can be put on the corresponding stock pile in the mine. An other problem for the processing of iron ores is the substitution of Fe with other cations in the crystal structure. Goethite is the best studied example of an isomorphously substituted iron oxide and of the various possible impurities that it can contain in natural samples. For example, although Al is 17 per cent smaller then Fe3+, up to one-third of the Fe3+ in goethite can be replaced by Al. The full range of substitution up to 33 mol per cent is found in natural goethites and up to 16 mol per cent in natural haematite. One reason for this is the abundance of Al in rocks and soils and its mobilisation together with Fe during weathering (Cornell and Schwertmann, 1996). The Al-for Fe substitution was originally discovered with XRD in Jurassic, marine, oolitic iron ores (Correns and von Engelhart, 1941) and 20 years later found in soils by Norrish and Taylor (1961). Aluminium located in the structure of goethite and haematite in natural iron ores and bauxites cannot be extracted, both for Al metal production and iron ore benefi ciation. A linear relationship exists between the Al substitution and the b and c parameters of the unit cell of goethite (Thiel, 1963; Schulze, 1984) and subsequently on the peak position measured during a XRD experiment. According to Schulze (1984), the c parameter can be used to determine the amount of Al substitution. The estimation of the Al substitution can be calculated from the relationship: mol per cent Al = 1730 - 572.0 c. The unit cell parameters are refi ned during the quantitative Rietveld calculations and were used to estimate the amount of Al within the goethite of the 60 samples. The calculated concentration for the Al substitution in the analysed goethite varies from 1 - 6 mol per cent. FIG 2 - Magnifi ed view on the main peaks of the ore minerals and impurities for 60 samples from one drill hole of an iron ore deposit. FIG 3 - Principle Component Analysis plot of 60 iron ore samples from one deposit divided into three diff erent clusters (grades) with diff erent mineralogy (red = outlier), the three axes represent principle component 1, 2 and 3. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 U KÖNIG, L GOBBO AND K MACCHIAROLA 52 Figure 5 demonstrates the shift if the (111) refl ection of goethite with different amounts of Al substituted in the range from 0 - 35 mol per cent, whereas the (040) refl ection is not affected by the substitution of Al. ANALYSIS OF IRON ORE SINTER Iron ore sinter materials are an important feedstock material for the steel industry. Sintering is a high temperature agglomeration process. Since fi nes cannot be used in conventional blast furnaces because they impair the upward gas fl ow, fi nes are agglomerated in sinter plants (Ghosh et al , 1999). As a result of increased quality requirements, optimal energy use and minimum CO 2 emissions, the phase composition and chemistry of iron ore sinters are important. Especially the analysis of haematite and magnetite and subsequently the Fe2+/Fe3+ ratio affects the control of Cluster Haematite (%) Goethite (%) Gibbsite (%) Kaolinite (%) Quartz (%) Magnetite (%) Mol % Al in Goethite 1 High-grade Min 3.1 56.1 0.0 0.0 0.0 0.0 <5 Max 23.1 94.3 1.1 4.6 0.8 2.2 <5 Average 16.9 75.3 0.6 2.2 0.1 0.7 <5 2 Low-grade Min 15.7 37.4 1.9 4.3 0.0 0.0 <5 Max 49.5 76.8 4.9 16.2 3.7 0.0 5 to 12 Average 30.3 55.2 3.0 9.9 1.6 0.0 5 to 12 3 Medium-grade Min 5.9 50.7 0.5 0.0 0.0 0.0 <5 Max 39.1 91.2 4.1 8.8 4.8 0.0 <5 Average 19.5 74.2 1.9 3.5 0.9 0.0 <5 TABLE 1 Concentration ranges of the phase content of 60 iron ore samples obtained by Rietveld refi nement. Goethite 0 10 20 30 40 50 60 70 80 90 100 0 1 2 3 Cluster % Hematite 0 10 20 30 40 50 60 0 1 2 3 Cluster % Kaolinite 0 2 4 6 8 10 12 14 16 18 0 1 2 3 Cluster % Gibbsite 0 1 2 3 4 5 6 0 1 2 3 Cluster % FIG 4 - Phase concentration of the main phases versus the cluster number for 60 analysed iron ore samples. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 USING X-RAY DIFFRACTION FOR GRADE CONTROL AND MINIMISING ENVIRONMENTAL IMPACT IN IRON AND STEEL INDUSTRIES 53 the energy consumption and thereby the CO 2 emissions. Magnetite is oxidised to haematite in an exothermic chemical reaction which produces heat and reduces the energy needed. Annually about 6.5 Mt of iron ore sinter are produced. The fuel consumption is approximately 60 kg coke or anthracite per tonne iron ore sinter. Small fuel saving (typically -1 kg/ tonne of sinter) already represents a signifi cant saving in energy and cost (Devitt, 1968). Main minerals present in the sinter are haematite (Fe 2 3+O 3 ), magnetite (Fe 2 3+Fe2+O 4 ), wuestite (Fe2+O), larnite (Ca 2 SiO 4 ), silico ferrites of calcium and aluminium (SFCA) and possibly a glass phase. The properties of an ideal iron ore sinter depend on these mineral phases. SFCA must be a major phase to ensure reducibility and strength. Magnetite is preferred to haematite because of volume changes during the reduction (Ghosh et al, 1999). The larnite content should be as low as possible since β-γ transformations can occur (Ishikawa et al, 1983). The process parameters for common sinter plants that need to be controlled are: the basicity CaO/SiO 2 (usually 1.2 - 2.4), the return fi nes rate (usually 20 - 30 per cent), and the FeO content (usually 5 - 9 per cent). In a f rst step 55 samples from iron ore sinter plant over a production time of 100 days were measured using a CubiX3 Minerals diffractometer. All scans are plotted together in Figure 6 to get an overview of the changes in the sinter produced over the time. Only minor differences are visible in the range of 72 - 74°2θ. In a second step, before further qualitative and quantitative investigations, a cluster analysis of all measured scans was applied. Two different groups of sinter material can be identifi ed in the PCA plot shown in Figure 7. One cluster represents a relatively stable sinter product since the scans in the PCA plot are very close to each other. The other cluster shows a wider spread that indicates ahigher variation of the analysed sinter samples. FIG 5 - Simulated shifts in peak position and intensity for Al substituted goethite. 0 5000 10000 Counts Position [°2Theta] (Cobalt (Co)) 65 70 75 FIG 6 - Zoomed view on 55 measurements of iron ore sinters over a production period of 100 days. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 U KÖNIG, L GOBBO AND K MACCHIAROLA 54 The most representative scans from each cluster were further analysed by X-ray fl uorescence spectroscopy (XRF) to compare the basicity CaO/SiO 2 obtained and calculated from the XRF data, Figure 8. It was found that the two types of sinter correspond with two different levels of basicity, 1.7 and 2.4. This refl ects a change in the composition of the sinter feed processed during the 100 days, later attributed to a change in supplier of one of the key raw materials. This example demonstrated that simply by statistical evaluation of the scan, the type of the sinter produced can be identifi ed. Changes in sinter composition that refl ect a different processing can be monitored and if necessary adjusted. Since this can be done within minutes after the sinter was produced, it has a major impact on the energy consumption and sinter quality. The third step of the analysis contains the Rietveld quant- ifi cation on all samples measured (Figure 9). All crystalline phases present such as haematite, magnetite, wuestite, larnite and the SFCA phases. SFCA-a refers to SFCA according to Hamilton et al (1989). SFCA-b is describes as SFCA-I by Mumme (Clout and Gable, 1998). From the phase concentrations the total FeO content can be calculated, as shown in Table 2. The amount of SFCA phase gives an indication for the hardness and subsequently the return of fi nes rate of the sinter material produced (Patrick and Pownceby, 2002). The two groups of sinter material show differences in the amount of total metal iron. Also the Fe2+ (as FeO) content seem to be a bit higher in the sinter material of cluster 1. The amount of SFCA phase and wuestite is clearly increased in sinter material of cluster 2 whereas the haematite and magnetite content is lower compared to the samples of cluster 1. CONCLUSIONS In this article it is shown how X-ray diffraction can be used to provide valuable information for iron ore mining and iron ore sinter process control through standard-less quantifi cation and fast, statistical evaluation of large data sets through cluster analysis. Today’s optics, detectors, and software can provide rapid (within minutes) and accurate analyses, suitable for process control environments as well as research. FIG 7 - Principle Component Analysis plot of 55 iron ore sinter samples representing two groups of sinter materials. FIG 8 - Results of the data clustering versus the basicity CaO/SiO 2 . Position [°2Theta] (Cobalt (Co)) 35 40 45 Counts 0 5000 10000 Hematite 21.9 % Magnetite 29.1 % C2S - Belite 5.6 % SFCA-a 25.1 % SFCA-b 17.0 % Wuestite-FeO 1.4 % FIG 9 - Rietveld quantifi cation of the crystalline phase content of an iron ore sinter sample. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 USING X-RAY DIFFRACTION FOR GRADE CONTROL AND MINIMISING ENVIRONMENTAL IMPACT IN IRON AND STEEL INDUSTRIES 55 Cluster Haem % Mag % Lar % SFCA % Wue % Fe2+ Fe met 1 39.7 33.3 4.7 21.9 0.4 10.7 63.0 1 37.3 33.7 5.9 22.6 0.5 10.9 61.9 1 32.7 37.6 5.6 23.6 0.5 12.2 62.1 1 33.5 36.6 6.3 23.2 0.4 11.8 61.7 1 30.6 41.2 5.0 22.8 0.4 13.2 62.8 1 33.6 39.7 4.5 21.9 0.4 12.7 63.3 1 36.0 34.4 5.4 23.8 0.3 11.0 62.1 1 37.8 34.1 4.5 23.2 0.4 11.0 62.9 1 36.2 30.7 4.6 27.8 0.6 10.1 61.7 1 31.9 37.0 4.5 26.0 0.5 12.0 62.3 1 34.2 34.3 3.8 27.2 0.6 11.2 62.5 1 44.1 32.0 6.5 17.3 0.2 10.1 62.7 1 40.3 33.1 6.5 19.6 0.4 10.6 62.1 1 34.8 34.5 5.5 24.8 0.5 11.2 61.9 1 39.4 33.3 6.7 20.4 0.4 10.7 61.9 1 36.8 38.0 6.2 18.8 0.3 12.1 62.7 1 39.0 34.0 6.5 20.3 0.3 10.8 62.1 1 39.1 33.0 7.3 20.3 0.4 10.6 61.5 1 41.8 32.1 5.9 20.0 0.3 10.2 62.5 1 40.3 33.4 7.0 18.9 0.3 10.7 61.9 1 44.1 27.8 6.5 21.4 0.3 8.9 61.7 1 42.7 30.7 6.2 20.1 0.3 9.8 62.2 1 39.9 31.4 6.4 21.9 0.4 10.1 61.8 1 34.2 40.9 6.7 18.0 0.3 13.0 62.6 1 40.7 33.4 6.7 18.9 0.3 10.7 62.1 1 36.1 35.1 6.6 21.7 0.5 11.4 61.7 1 39.9 35.0 6.8 18.1 0.3 11.1 62.3 1 37.3 32.3 6.7 23.3 0.4 10.4 61.2 1 40.4 32.3 6.3 20.8 0.3 10.3 62.1 Min 30.6 27.8 3.8 17.3 0.2 8.9 61.2 Max 44.1 41.2 7.3 27.8 0.6 13.2 63.3 Average 37.7 34.3 5.9 21.7 0.4 11.0 62.2 2 19.9 35.8 6.8 36.3 1.2 12.3 58.5 2 21.9 29.1 5.6 42.1 1.4 10.4 58.1 2 19.3 31.7 8.1 39.4 1.5 11.3 56.9 2 20.8 31.2 7.8 39.0 1.3 10.9 57.2 2 24.2 26.1 6.2 42.2 1.3 9.4 57.5 2 21.3 33.4 6.4 37.7 1.2 11.6 58.5 2 22.2 29.4 5.8 41.3 1.3 10.4 58.1 2 23.3 28.2 6.4 40.9 1.3 10.0 57.7 2 21.2 29.9 5.9 41.7 1.3 10.5 57.9 2 18.2 30.8 7.2 42.4 1.4 10.9 56.9 2 20.4 31.6 6.2 40.6 1.3 11.0 58.0 2 18.9 34.5 5.4 39.9 1.4 12.0 58.8 TABLE 2 Results of the quantitative Rietveld analysis of 55 iron ore sinter samples (Haem = haematite, Mag = magnetite, Wue = wuestite, Lar = larnite) and calculated Fe2+ (as FeO) and total metal Fe content, data is separated into the two diff erent clusters identifi ed by the Principle Component Analysis. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 U KÖNIG, L GOBBO AND K MACCHIAROLA 56 REFERENCES Cornell, R M and Schwertmann, U, 1996. The Iron Oxides , 573 p (Wiley). Correns, C W and von Engelhart, W, 1941. Roentgenographische Untersuchungen ueber den Mineralbestand sedimentaerer Eisenerze, Nachr Akad Wiss Goettingen, Math Phys Kl, 2:131-137. Devitt, T W, 1968. The integrated iron and steel industry air pollution problem, US department of health, education and welfare. Ghosh, A and Chatterjee, A, 2008. Ironmaking and Steel Making: Theory and Practice, 492 p (Prentice Hall). Hamilton, J D G, Hoskins, B F, Mumme, W G, Borbidge, W E and Montague, M A, 1989. The crystal structure and crystal chemistry of Ca2.3 Mg0.8 Al1.5 Si1.1 Fe8.3 O20 /SFCA): Solid solution limits and selected phase relationships of SFCA in the Si O2-Fe2 O3-CaO-(Al2 O3) system, Neues Jahrbuch Miner Abh, 161(1):1-26. Ishikawa, Y, Shimomura, Y, Sasaki, M and Toda, H, 1983. Improvement of sinter quality based on the mineralogical properties of ores, in Proceedings 42nd Ironmaking Conference, 42:17-92. Klug, H P and Alexander, L E, 1954. X-Ray Diffraction Procedures for Polycrystalline and Amorphous Materials , 992 p (Wiley- Blackwell). Lu, L, Holmes, J and Manuel, J R, 2007. Effects of alumina on sintering performance of hematite iron ores, ISIJ International, 47(3):349-358. Macchiarola, K, Koenig, U, Gobbo, L, Campbell, I, McDonald, A M and Cirelli, J, 2007. Modern X-ray diffraction techniques for exploration and analysis of ore bodies, in Proceedings Fifth Decennial International Conference on Mineral Exploration , Toronto. Mumme, W G, Clout, J M F and Gable, R W, 1998. The crystal structure of SFCA-I, Ca3.18 Fe3+14.66Al1.34Fe2+0.82O28, a homologue of the aenigmatite structure type and new crystal structure refi nements of beta-CFF, Neues Jahrbuch Miner Abh , 173(1):93-117. Norrish, K and Taylor, R M, 1961. The isomorphous replacement of iron by aluminium in soil goethites, Journal of Soil Science , 12:294-306. Patrick, T R C and Pownceby, M I, 2002. Stability of SFCA in air solid solution limits between 1240 and 1390C and phase relationships within FCAS system, Metallurgical and Materials Transactions B, 33B:79-89. Rietveld, H M, 1969. A profi le refi nement method for nuclear and magnetic structures, Journal of Applied Crystallography, 2:65-71. Schulze, G D, 1984. The infl uence of aluminium on iron oxides VIII: Unit cell dimensions of Al-substituted goethite and the estimation of Al from them, Clays and Clay Minerals, 32(1):36-44. Thiel, R, 1963. Zum System FeOOH-AlOOH, Z Anorg, Allg Chem , 326:70-78. Yamaoka, Y, 1974. Effects of gibbsite on sinter properties and quality, Transactions of the Iron and Steel Instituteof Japan , 14:185-193. Cluster Hem % Mag % Lar % SFCA % Wue % Fe2+ Fe met 2 19.4 33.2 6.2 40.0 1.3 11.5 58.1 2 20.2 30.1 6.3 42.0 1.4 10.7 57.6 2 22.7 27.7 6.7 41.6 1.3 9.9 57.3 2 24.2 25.4 6.4 42.7 1.4 9.3 57.3 2 25.2 25.2 6.4 42.0 1.2 9.0 57.4 2 23.1 28.1 6.9 40.8 1.2 9.9 57.4 2 22.1 26.2 6.7 43.6 1.3 9.4 56.8 2 20.8 31.5 7.5 38.9 1.4 11.1 57.4 2 23.2 29.4 6.4 39.8 1.2 10.3 57.9 2 21.7 29.2 7.1 40.7 1.3 10.4 57.3 2 21.0 30.2 6.6 40.9 1.3 10.7 57.6 2 18.4 32.2 7.4 40.7 1.4 11.3 57.1 2 18.5 29.6 7.3 43.2 1.5 10.6 56.6 2 18.2 32.8 7.5 40.2 1.3 11.5 57.2 Min 18.2 25.2 5.4 36.3 1.2 9.0 56.6 Max 25.2 35.8 8.1 43.6 1.5 12.3 58.8 Average 21.2 30.1 6.7 40.8 1.3 10.6 57.6 TABLE 2 CONT... IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 59 INTRODUCTION Famous for its gold and high grade iron ores, the mining district of the southeastern Brazilian highlands known as Quadrilátero Ferrífero (QF) or Iron Quadrangle (Dorr, 1969) extends over an area of around 7500 km2, highlighted by ridges of Paleoproterozoic banded iron formation (Figure 1). Large scale iron ore production started in the QF after the World War II in the mid-1950s and has experienced a continuous growth ever since. The QF mining industry is today responsible for ca 70 per cent of the Brazilian and ca ten per cent of world iron ore production. The iron ores so far exploited in the QF were in general of higher grade (>55 per cent Fe) and, except for one category, the so-called hard haematite, derived from supergene enrichment of itabirites of the Paleoproterozoic Cauê Formation (Eichler, 1968; Dorr, 1964, 1965, 1969; Melfi et al, 1976; Ramanaidou et al, 1996; Spier, Oliveira and Rosière, 2003, 2007; Rosière et al, 2008; Ramanaidou and Morris, 2010). Fresh, unenriched itabirite, viewed as protore, was never incorporated in the benefi ciation plants. However, the high current demand and consequent depletion of soft ores will cause a fast increment of 1. Superintendent of Geology, Mine Planning and Environment, Mineração Usiminas Ltda, Rua Professor José Vieira de Mendonça, 3011, bairro Engenho Nogueira, Belo Horizonte, Minas Gerais, 31310-260, Brazil. Email: leandro.amorim@usiminas.com 2. Professor, Escola de Minas, Universidade Federal de Ouro Preto, Departamento de Geologia, Morro do Cruzeiro, Ouro Preto Minas Gerais 35.400-000, Brazil. Email: ff alkmim@gmail.com New Ore Types from the Cauê Banded Iron Formation, Quadrilátero Ferrífero, Minas Gerais, Brazil – Responses to the Growing Demand L Q Amorim1 and F F Alkmim2 ABSTRACT The mining district of the Quadrilátero Ferrífero (QF) in southeastern Brazil contributes to 70 per cent of the Brazilian iron ore production, which reached 370 Mt in 2010. Traditionally, four iron ore types were mined in the QF region: 1. soft haematite, 2. hard haematite, 3. friable ‘itabirite’ (the Brazilian name for metamorphosed banded iron formation), and 4. canga (an indurated iron-rich crust). With the exception of the hard haematite, these categories derive from supergene enrichment of the Paleoproterozoic Cauê Itabirite. High current iron ore demand means that the QF high grade supergene ores will be depleted in a few decades. Consequently, several mining projects are being developed to exploit unenriched, fresh itabirite. Among them, the Mineração Usiminas Serra Azul project in northwestern QF is one of the most advanced. Four major itabirite types occur in the QF region: 1. siliceous (or standard), 2. dolomitic, 3. amphibolitic, and 4. magnetitic. The dominant type in Serra Azul region is a fresh siliceous itabirite, composed essentially of haematite, martite and quartz that averages 36 per cent Fe (51.5 per cent Fe 2 O 3 ) and 47 per cent SiO 2 . The second type, the magnetitic itabirite, consisting of magnetite, martite, grunerite- cummingtonite, quartz, dolomite, stilpnomelane, and subordinate haematite, is typically a strongly magnetic greenish banded iron formation with the iron grade varying between 25 and 35 per cent. Chemically, it differs from the siliceous itabirite due to the relatively high CaO, MgO and, consequently, high LOI contents. Together with supergene ores, fresh itabirites have been included in the ore reserves of the Serra Azul project. We anticipate that all the four types of fresh itabirite will be incorporated as ore in the QF region, causing a huge increase on the iron ore resources of the district, and representing enormous environmental and technological challenges for the local iron ore industry. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 L Q AMORIM AND F F ALKMIM 60 iron ore production from fresh itabirite, which represents the new trend in the QF mining industry. Since fresh BIF was so far considered to be waste in the QF region, the unweathered section of the Cauê Formation was not drilled and investigated on a routine basis in the exploration programs carried out in the QF. As a fi rst in the region, Mineração Usiminas performed a comprehensive exploration program for hard itabirites in the locality named ‘Serra Azul ‘, western QF (Figure 1), which included 67 km of drilling distributed in 542 boreholes. The new data obtained in this program forms the base for the descriptions and discussions presented in this paper. THE GROWING DEMAND ON IRON ORES The trend of the world’s iron ore demand through time can be easiest visualised using crude steel production curves. Figure 2 shows the total crude steel production of the world in the last 100 years, plotted together with the sum of blast furnace iron (BFI) and directly reduced iron (DRI) productions. This sum represents the amount of steel produced from iron ore and the difference between the two curves corresponds to the amount of steel derived from scrap (Figure 2). At fi rst glance, the curves of Figure 2 record only the historical steel production growth based on iron ore consumption. This general tendency includes two major production increments, separated by a period relatively stability between the mid-1970s and the mid-1990s of the last century. A more careful examination of the plots reveals, however, that major events affecting the world in the last 100 years are reproduced by the curves. Critical periods – the 1929 crash, the World War II in the mid-1940s, the fi rst and second oil crisis, respectively in the mid-1970s and 1980s, the end of the USRR in the beginning of the 1990s, as well as the very recent 2008 economic crisis – are represented by lows followed by recoveries in the years after. In the aftermath of the World War II, the steel production experienced an enormous growth, rising from 200 Mt in 1950 to 600 Mt in 1970. This increment was a consequence of several developments, but mainly of the further industrialisation of the fi rst world countries, the cold war, and reconstruction of Europe and Japan. In the following three decades, from 1970 - 2000, the steel production underwent only a vegetative growth, going from 600 - 800 Mt/a. Without any other historic equivalent, the second largest steel production increment, starting in the fi rst decade or the 21st century and reaching the present day, represents the economic booming FIG 1 - Digital topography model of the QF region showing the locations of the Curral Ridge and Serra Azul. 0 200 400 600 800 1000 1200 1400 1600 1910 1920 1930 1940 1950 1960 1970 1980 1990 2000 2010 m ill io n to nn es BFI+DRI crude steel FIG 2 - World crude steel production in the last 100 years (data source: International Iron and Steel Institute – IISI; http://www.worldsteel.org). IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 NEW ORE TYPES FROM THE CAUÊ BANDED IRON FORMATION, QUADRILÁTERO FERRÍFERO, MINAS GERAIS, BRAZIL 61 of China. The world steel production reached 1.4 Bt in 2010, a level that corresponds to the extraordinary increase of 600 Mt/a in ten years. From the 1.4 Bt of crudesteel produced in 2010, around 1.1 Bt correspond to BFI plus DRI, which caused a consumption of 1.7 Bt of iron ore in one single year. Brazilian iron ore production continuously increased after the mid-1950s, reaching 52 Mt in 1973 and the peak of 94 Mt in 1976 (Figure 3). Several iron ore projects were implemented in Brazil in the late 1960s and early 1970s, leading to a production of almost to 100 Mt in the mid-1980s (Figure 3). All of these projects were developed in the Quadrilátero Ferrífero, the only signifi cant source of iron ore in Brazil until 1986, when Carajás, the second largest mining district of the country, start also to produce iron ores. During the 25 years period of the mid-1970s to the year 2000, the Brazilian iron ore production rose from near 100 Mt/a to approximately 200 Mt/a (150 Mt/a from the QF and 50 Mt/a from Carajás). From 2001 to 2008, the annual production of the QF grew from 150 Mt to 250 Mt. The production of other regions in the country (mostly from Carajás, northern Brazil) increased from 50 - 100 Mt/a, leading a national production of 351 Mt in 2008 (Figure 3) as reported by the Brazilian National Department of Mineral Production (DNPM). According to United States Geological Survey statistics, the 2010 Brazilian iron ore production was 370 Mt. The fi rst iron ore concentration plant of Brazil was set in the town of Itabira, Minas Gerais (QF), in 1973. Up to that time, only high grade iron ores were exploited in the QF. Immediately after, the Brazilian iron ore industry underwent signifi cant changes with the introduction of several other concentration plants, and the consequent incorporation of new iron types such as soft enriched BIF. Due to the enormous rise of the production in the last years, even the soft and rich BIF resources will be depleted in the QF in a few decades. Thus, as a response to present level of demand, new ore types, this time represented by former protores, ie fresh and hard itabirites, are to be introduced in the production system of the QF. The incorporation of these new ore types will result in an extraordinary increase of the QF iron ore resources, but also in new benefi ciation process and considerable smaller mass recovery, implying in larger tailings dams, larger pits and consequently greater environmental impacts. THE QUADRILÁTERO FERRÍFERO AND ITS IRON ORES Geological setting of the Quadrilátero Ferrífero Geologically, the Quadrilátero Ferrífero is located in the southeast border of the São Francisco Craton, an Archean/ Paleoproterozoic stable block, surrounded by Neoproterozoic orogenic belts (Almeida, 1977; Alkmim and Marshak, 1998). The district is underlain by fi ve major lithostratigraphic units: 1. the Archean basement, 2. the Archean Rio das Velhas Supergroup, 3. the Paleoproterozoic Minas Supergroup, 4. the Itacolomi Group, and 5. mafi c intrusive (Figure 4). 0 50 100 150 200 250 300 350 400 1950 1960 1970 1980 1990 2000 2010 m ill io n to nn es Brazil Minas Gerais FIG 3 - Brazilian iron ore production 1950 - 2008 (data source: National Department of Mineral Production – DNPM; http://www.dnpm.gov.br/). FIG 4 - Simplifi ed geologic map of the QF, emphasising the distribution of the main lithostratigraphic units and structures (Based on Dorr, 1969; Romano, 1989). IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 L Q AMORIM AND F F ALKMIM 62 The Archean basement is made up of 3.2 - 2.9 Ga old gneiss complexes and two generations of Late Archean granitoids (Machado et al, 1992; Carneiro, Teixeira and Machado, 1994; Noce, 1995). The 2.78 - 2.61 Ga old Rio das Velhas Supergroup, a classical greenstone belt succession, comprises a volcano- sedimentary package, mainly composed of komatiite, basalt and ryolitic lavas, intercalated and overlain by sedimentary units, including carbonate facies banded iron formations (Dorr, 1969; Machado et al, 1992; Zucchetti, Baltazar and Raposo, 1998; Noce et al, 2005). The Minas Supergroup, accumulated in a passive to convergent margin setting between 2.6 - 2.0 Ga, records the operation of a full Wilson cycle on the southern edge of the São Francisco craton (Alkmim and Marshak, 1998). Separated from the Rio das Velhas greenstone belt by a pronounced unconformity, the basal Caraça Group consists of alluvial conglomerates and sandstones that grade upwards into shallow marine pelites. Caraça sediments are overlain by the transgressive Itabira Group that contains the Cauê Banded Iron Formation, the marker bed of the QF that hosts all of its iron ore resources. The Cauê Formation grades upward into the shallow water carbonates of the Gandarela Formation, which is in turn overlain by a thick transgressive succession of sandstones and pelites of the Piracicaba Group. The youngest unit of the Minas Supergroup, the Sabará Group, made up of turbiditic conglomerates, sandstones and pelites, records the conversion of the Minas passive margin into a syn-orogenic (fl ysch) basin at ca 2.1 Ga (Dorr, 1969; Machado et al, 1996; Renger et al, 1995; Hartmann et al, 2006). Probably representing an intermontane molassa, the quartzites and conglomerates of the Itacolomi Group unconformably overlie Minas Supergroup strata in the southern QF (Dorr, 1969) (Figure 4). Intrusions cutting the previous units include mainly mafi c dykes, which dominantly trend N-S to NW-SE. One of these dykes was dated at 1.714 Ma (Silva et al, 1995). The regional geologic map pattern of the QF defi nes a dome-and-keel architecture, in which the Archean basement occurs in form of domes surrounded by ‘keels ‘ containing the metasedimentary units. Keels include fi rst-order synclines, such as the Moeda and Dom Bosco synclines, as well as the large Serra do Curral homocline (Marshak et al, 1992; Alkmim and Marshak, 1998) (Figure 4). Rocks of the supracrustal sequence adjacent to the domes contain a distinct high-T/ low-P metamorphic aureole (Herz, 1978; Jordt-Evangelista, Alkmim and Marshak, 1992; Marshak et al, 1992). The rocks of the Rio das Velhas Supergroup have been strongly deformed prior to the deposition of the Minas Supergroup (Dorr, 1969). Furthermore, two sets of pronounced post-Minas structures that apparently do not show any relationship with the dominant dome-and-keel structure can be recognised in the region. One set trends NE-SW and comprises the Gandarela syncline, the Serra do Curral homocline, as well as the synclinoria of the Itabira and Monlevade regions (Figure 4). The second set includes a series of west-verging thrusts, which are particularly well developed in the eastern QF (Dorr, 1969; Chemale Jr, Rosière and Endo, 1994; Chauvet et al, 1994; Alkmim and Marshak, 1998). Second-order mesoscopic folds associated to penetrative tectonic fabrics (ie schistosity, mylonitic foliation, stretching lineation) also occur throughout the region. The stretching lineation and the mesoscopic fold hinges plunge preferentially towards S80°E with 30° (Dorr, 1969; Chemale Jr, Rosière and Endo, 1994; Chauvet et al, 1994; Alkmim and Marshak, 1998). A regional, syn-kinematic metamorphism affecting all units exposed in the QF region varies from lower greenschist to the west to upper amphibolite facies to the east (Dorr, 1969; Herz, 1978; Pires, 1995). The Cauê banded iron formation and associated ores The Cauê Formation is composed of a variety of metamorphosed BIF currently referred to as ‘itabirite’, iron ores, and subordinated dolomites (Dorr, 1969; Pires, 1979; Pires, Aranha and Cabral, 2005; Rosière and Chemale Jr, 2006, Rosière et al, 2008; Spier, Oliveira and Rosière, 2003, Spier et al, 2007). The name itabirite (Eschwege, 1833) is used to designate: ... a laminated, metamorphosed oxide-facies iron formation in which the original chert or jasper bands have been recrystallised into granular quartz and the iron is present as haematite, magnetite or martite ... (Dorr, 1964). Accordingto their mineralogical composition, the QF itabirites, as fresh rock, are classifi ed into four main types: 1. siliceous (or standard), 2. dolomitic, 3. amphibolitic, and 4. magnetitic itabirite. The fi rst three types were described by several authors (Dorr, 1969; Pires, Aranha and Cabral, 2005; Rosière and Chemale Jr, 2006; Rosière et al, 2008, Spier et al, 2007). The last one, as a fresh rock, is described in the present paper. Their chemical and mineralogical compositions are presented on Table 1. The standard itabirite is the dominant type in the QF. The other types occur as beds or lenses within the Cauê Formation. Dolomitic itabirites are more frequent in the western part of the QF, whilst the amphibolitic itabirites are more common in the eastern part of the district. Magnetitic itabirites normally occur as a deeply weathered, ochreous, goethitic iron formation (‘yellow magnetitic iron formation’ according to Pires (1979). Fresh magnetitic itabirite, as recently found in the western portion of the QF, is a green banded iron formation, containing magnetite, martite, grunerite-cummingtonite, quartz, dolomite, stilpnomelane, and subordinate haematite (Alkmim, 2009). According to Pires, Aranha and Cabral (2005), chemical composition and observed macroscopic structures point towards a volcanic origin for the magnetitic itabirite. The presence of stilpnomelane in this type of itabirite is indeed an indicator for contamination with volcanic material (eg Pickard, 2002, 2003). The maximum original thickness of the Cauê Formation is estimated to be 350 m (Dorr, 1964). However, as emphasised by this author, due to the plastic behaviour of Cauê BIF in the deformation processes affecting the QF region, the fi nal thickness of the unit exceeds 1500 m in many places. The metamorphic conditions experienced by the Cauê Formation can be expressed by temperatures obtained in oxygen isotope studies. The metamorphic temperatures show a general increase from west to east, varying from a minimum of 394°C in the Moeda syncline to a maximum of 780°C in the Itabira synclinorium (Müller, Schuster and Hoefs, 1982) (Figure 4). These values are in agreement with the metamorphic facies zoning of the QF, as described by Herz (1978) and Pires (1995). No direct age determinations are available for the Cauê Formation. Babinski, Chemale and Van Schmus (1995) obtained a Pb-Pb age of 2.42 Ga for the basal limestones of the overlaying Gandarela Formation. Considering that the maximum depositional age of the basal quartzites of the Minas Supergroup is 2.58 Ga (Hartmann et al, 2006), the accumulation of the Cauê BIF must be occurred between IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 NEW ORE TYPES FROM THE CAUÊ BANDED IRON FORMATION, QUADRILÁTERO FERRÍFERO, MINAS GERAIS, BRAZIL 63 2.58 and 2.42 Ga, a time interval that encompasses most of the Paleoproterozoic BIF deposition ages (Gole and Klein, 1981; Trendall, 2002). The iron ores so far exploited in the QF belong to two genetic classes: hypogene and supergene. The fi rst category, also referred to as hard or compact haematite, comprise very rich (Fe >66 per cent), massive, banded or foliated haematitic orebodies. Exhibiting linear or less frequent tabular shapes, the haematite bodies can vary from less than fi ve to more than 50 Mt. Their origin is matter of a long standing debate among various authors (for discussion see Guild, 1953; Dorr 1965, 1969; Varajão et al, 1997; Rosière and Chemale Jr, 2006; Hagemann et al, 2006; Rosière et al, 2008; Rosière and Rios, 2004; Clout and Simonson, 2005). After the benefi ciation, the hard ores produce a high proportion of lumps (more than 50 per cent), making it a quite valuable material. The QF ores generated by supergene processes include soft haematite, enriched itabirites, and laterite crusts. Morphotectonic processes acting upon the QF region probably at the beginning of the Paleocene (Spier, Vasconcelos and Oliveira, 2006) created conditions for vertical and lateral water circulation within the Cauê Formation layers, causing the leaching of silica and dolomite from the itabirites and thus forming supergene ores (Dorr, 1964, 1965; Eichler, 1968; Melfi et al, 1976; Ramanaidou et al, 1996; Spier et al, 2003). This process generated bodies of almost pure soft haematite (Fe ≥ 64 per cent) and an enormous volume friable itabirites. Two subtypes of laterite crusts, known as ‘canga’ in Brazil, occur in the QF region: 1. the in situ; and 2. the detrital canga (Dorr, 1969). The in situ or structural canga occurs in form of up to 30 m hard caps on top of the Cauê itabirites and associated orebodies (Dorr, 1965, Ramanaidou et al, 1996, Ramanaidou and Morris, 2010), especially in high elevations (1200 m to 1600 m above the sea level) (Varajão, 1994). Covering the Cauê Formation and adjacent units along hill slopes and small basins, the detrital canga corresponds to breccias or less frequent to conglomerates containing hard haematite and BIF clasts. Usually associated with high alumina (four per cent Al2O3 or more) and phosphorous (0.12 per cent P or more), both types of canga are iron rich (usually Fe >50 per cent) and contain, besides haematite, goethite, and limonite (Dorr, 1969, Melfi et al, 1976; Varajão, 1994, Ramanaidou, 2009). Due to the depletion of most of the high grade deposits, many projects considering the exploitation of the unenriched hard itabirites (former protores) are already launched in the QF, among them the Serra Azul project discussed in the next section. The new category of fresh rock ores (Figure 5) includes all types of previously mentioned itabirites that average around 36 per cent iron (approximately 50 per cent Fe2O3). In order to produce pellet feed fi nes, their main use, the fresh rock ores must be grinded before concentration. THE SERRA AZUL PROJECT Geologic outline of the Serra Azul The Mineração Usiminas mineral claims are located along the western segment of Curral ridge, locally referred to as the Serra Azul (literally Blue Ridge) (Figures 3 and 6). The Serra Azul, extending for ca 30 km in the NE-SW, is underlain by a Siliceous itabirite Dolomitic itabirite Amphibolitic itabirite Magnetitic itabirite Major components Accessories Major components Accessories Major components Accessories Major components Accessories M in er al og y Dark bands haematite, martite mt, se, qz, py, mnox haematite, martite mt, qz, dl, mnox hornblend, grunerite hm, ma, mt, qz, dl, af magnetite, haematite, martite, grunerite hm, ma, qz, af, ca, cl, bi, sp, tc Light bands quartz hm, ma, cl, se, dl, py, mnox dolomite hm, ma, qz, py, tc, mnox tremolite, actinolite hm, ma, mt, qz, dl quartz, carbonate mt, hm, ma, qz, af, ca, cl, bi, sp, tc Ty pi ca l c h em ic al co m po si ti on Fe 30 - 40% 35% 35% 25 - 35% SiO 2 40 - 60% <1% 45% 35 - 55% CaO <0.1% 15% <1% 2 - 10% MgO <0.1% 10% <1% 2 - 10% LOI 1 - 2% >5% 1 - 2% >5% af = amphibole, cl = chlorite, dl = dolomite, hm = haematite, mt = magnetite, ma = martite, Mnox = manganese oxide, py = pyrophyllite, qz = quartz, se = sericite, tc = talc, ca = carbonate, sp = stilpnomelane, bi = biotite. TABLE 1 Chemical and mineralogical characteristics of the fresh itabirites. FIG 5 - Genetic classifi cation of the Serra Azul iron ores, including the new category of fresh rock ores (unrenriched BIF) (modifi ed from Dorr, 1964). IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 L Q AMORIM AND F F ALKMIM 64 continuous outcrop belt of the Cauê Formation, which hosts several iron ore deposits (Simmons, 1968; Romano, 1989; Romano et al, 1991; Alkmim, 2009), including the Western, Central and Eastern mines, as well as the Camargos and Pau de Vinho deposits of the Mineração Usiminas (Figure 6). As part of the Curral ridge, the Serra Azul is the morphologic expression of an overturned,SE-dipping homocline that involves Rio das Velhas and Minas strata (Dorr, 1969). Along the Serra Azul, the basal units of the Minas supergroup are very thin and Gandarela Dolomite is absent for over almost its whole length (Simmons, 1968; Alkmim, 2009) (Figure 6). The Serra Azul overturned homocline can be subdivided into three structural domains (Alkmim 2009) (Figure 6). Along the structural domain I, which encompasses the Western Mine and the major part of the Central Mine, the thickness of the overturned Cauê Iron Formation increases from west to east, varying from around 50 m, at the western end of the ridge, to 250 m at the Central Mine. The dips also increase from west to east, being 20o at Ponta da Serra and reaching 45o at Central Mine (Figures 6, 7 and 8). Standard itabirites and their weathering products are the more abundant ore types in this domain. The amount of fresh magnetitic itabirite is negligible. However, its weathering product, a magnetite- rich, ochreous itabirite occurs as a continuous layer on top (stratigraphic base) of the iron formation, especially in the Western Mine. A small lens of hard haematite was identifi ed near to the base (stratigraphic top) of the Cauê Formation in the Western Mine (Figure 7). The ca 15 km long domain II (Figure 6) encompasses the central portion of Serra Azul, including the Camargos deposit. Minas Supergroup strata strike ENE-WSW and dip 40o to 80o to SSE. NW-verging folds and faults give rise to local structural complexities. Magnetitic itabirites occur in form of layers or lenses intercalated with siliceous itabirite, which in turn grades laterally into dolomites. A clay-rich, deeply weathered itabirite (called by the miners AIF, for ‘argillaceous iron formation’) is quite frequent close to the contact with the Cercadinho Formation, the basal unit of the Piracicaba Group (Figure 9). Along the structural domain III, which hosts the Pau de Vinho deposit (Figure 6), layers of the Minas Supergroup describe a large curve with the concave side facing north. On the easternmost sector of the curve, the strata dip NW, a change probably caused by the uplift of the adjacent the Bação Dome (Figure 6). NW-trending sinistral to reverse-sinistral shear zones cut the homocline along its whole length. One of the largest sinistral faults runs along the border of a large dyke (~300 m wide) of gabbro that divided the domain (as well as the Pau de Vinho deposit) in two sectors (Figure 6). To the southwest of the dyke, layers of NW-striking fresh itabirites predominate along the ca 500 m-thick Cauê Formation. To southeast of the dyke, the Cauê Formation consists of a sequence of magnetitic itabirite, dolomite, friable ore and argillaceous iron formation (AIF) (Figures 6 and 10). Serra Azul iron ores During the Serra Azul exploration program, two basic criteria were used to classify the iron ores: 1. the iron grade; and 2. the ‘W1’ parameter, which represents the mass percentage above 6.35 mm after crushing the sample in 31.5 mm. According to the second variable, the itabirite (or haematite) is classifi ed as: FIG 6 - Digital terrain model and geologic map of the Serra Azul region (based on Simmons, 1968; Romano, 1989; Alkmim, 2009). IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 NEW ORE TYPES FROM THE CAUÊ BANDED IRON FORMATION, QUADRILÁTERO FERRÍFERO, MINAS GERAIS, BRAZIL 65 FIG 7 - Cross-section 5100 – Western Mine (for location see Figure 6). FIG 8 - Cross-section 8500 – Central Mine (for location see Figure 6). FIG 9 - Cross-section 568 000 – Camargos Deposit (for location see Figure 6). IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 L Q AMORIM AND F F ALKMIM 66 ‘friable’, for W1 minor or equal to 30 per cent; ‘semi-compact’ for W1 between 30 per cent and 55 per cent; ‘compact’ for W1 between 55 and 70 per cent; and ‘hard compact’ for W1 greater that 70 per cent. According to these criteria, three major iron ore types have been discriminated in Serra Azul mineral claims: 1. haematite and standard itabirite, 2. magnetitic itabirite, and 3. argillaceous iron formation (AIF). Haematites and standard itabirites The iron grades and W1 values for 6385 itabirite and haematite core samples from Serra Azul are shown on the diagrams of Figure 11, which indicate a clear dominance of compact and hard compact ores in respect to other ore types. As consequence of the supergene enrichment process, the softer the material, the richer it is in average. Histograms of the iron grade for the different ore types as well as their statistics are shown on Figure 12 and Table 2. Under increasing degrees of weathering, the ore changes from hard compact, to compact, to semi-compact, and fi nally to friable. Accordingly, the iron grade increases and the ores become progressively heterogeneous. The iron grade of hard compact itabirite (fresh itabirite) from Serra Azul typically varies between 30 and 40 per cent, averaging 36 per cent, which corresponds to a haematite/ FIG 10 - Cross-section 2200 – Pau de Vinho Deposit (for location see Figure 6). 0,0% 0,0% 0,2% 0,4% 1,3% 6,5% 23,7% 27,4% 13,9% 8,6% 6,8% 6,9% 3,9% 0,5% 0% 10% 20% 30% Relative frequency 2% 3, 5% 4 ,3 % 4, 9% 4, 5% 3, 8% 3, 4% 3, 3% 3, 0% 2, 8% 3, 4% 4 ,2 % 4, 6% 6, 6% 9, 5% 12 ,5 % 1 4, 5% 7, 8% 1, 1% 0, 1% 0% 2% 4% 6% 8% 10% 12% 14% 16% re la ti ve fr eq ue nc y 0 10 20 30 40 50 60 70 0 20 40 60 80 100 % Fe % > 6,35 mm FIG 11 - Distribution of W1 and iron grade of the siliceous (standard) itabirites and haematites. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 NEW ORE TYPES FROM THE CAUÊ BANDED IRON FORMATION, QUADRILÁTERO FERRÍFERO, MINAS GERAIS, BRAZIL 67 martite (Fe 2 O 3 ) content of around 50 per cent. The average silica content is 47 per cent, meaning that the hard compact itabirite is a rock composed basically of haematite/martite and quartz, with very low amounts of other components, which may include phosphorous, alumina and loss on ignition (Table 3). Magnetitic itabirite Less frequent in the western half of Serra Azul (Western and Central Mines), the magnetitic itabirite occurs mainly in the Eastern Mine, Camargos and Pau de Vinho deposits (Figure 6). The distribution of the iron grade and W1 for 375 core samples of the magnetitic itabirite is shown in the diagrams of Figure 13. Typically, the magnetitic itabirite it is a hard rock (W1 >80 per cent) with iron grade between 25 and 35 per cent. The iron bearing minerals are magnetite, haematite, goethite and grunerite. Calcite and dolomite are also present, as well as quartz. The presence of carbonates implies in relatively high contents of CaO and MgO and, consequently, high loss on ignition (LOI) (Table 4). The distribution of CaO, MgO and LOI is shown on Figure 14. The contents of these components tend to be similar, as indicated by the concentration of the plots in the centre of the diagram. Field and drill core observations indicate that the weathering product of the magnetitic itabirite is the goethitic, phosphorous-rich, ochreous (Dorr, 1969) or yellow iron formation (Pires, 1979, Pires, Aranha and Cabral, 2005) widely known in the QF region. Argillaceous iron formation A soft, iron bearing rock that looks like a phyllite occurs near to the stratigraphic top (close to the footwall, since the sequence is overturned) of the Cauê Formation in the eastern 0, 0% 0, 3% 0, 6% 1, 2% 2, 2% 5 ,5 % 1 0, 6% 14 ,0 % 16 ,2 % 17 ,7 % 19 ,6 % 11 ,3 % 0, 8% 0% 10% 20% 30% 40% 50% < 10 10 _1 5 15 _2 0 20 _2 5 25 _3 0 30 _3 5 35 _4 0 40 _4 5 45 _5 0 50 _5 5 55 _6 0 60 _6 5 > 65 re la ti ve fr eq ue nc y % Fe Friable 0, 0% 0, 1% 0, 7% 1, 3% 5, 9% 13 ,8 % 17 ,7 % 20 ,5 % 15 ,3 % 10 ,4 % 9, 4% 4, 9% 0, 0% 0% 10% 20% 30% 40% 50% < 10 10 _1 5 15 _2 0 20 _2 5 25 _3 0 30 _3 5 35 _4 0 40 _45 45 _5 0 50 _5 5 55 _6 0 60 _6 5 > 65 re la ti ve fr eq ue nc y % Fe Semi compact 0, 0% 0, 2% 0, 3% 1, 8% 8, 2% 22 ,9 % 30 ,6 % 19 ,4 % 8, 3% 4, 1% 2, 4% 1, 5% 0, 2% 0% 10% 20% 30% 40% 50% < 10 10 _1 5 15 _2 0 20 _2 5 25 _3 0 30 _3 5 35 _4 0 40 _4 5 45 _5 0 50 _5 5 55 _6 0 60 _6 5 > 65 re la ti ve fr eq ue nc y % Fe Compact 0, 0% 0, 2% 0, 3% 1, 1% 8, 2% 36 ,8 % 38 ,3 % 9, 6% 2, 3% 1, 0% 1, 1% 0, 7% 0, 5% 0% 10% 20% 30% 40% 50% < 10 10 _1 5 15 _2 0 20 _2 5 25 _3 0 30 _3 5 35 _4 0 40 _4 5 45 _5 0 50 _5 5 55 _6 0 60 _6 5 > 65 re la ti ve fr eq ue nc y % Fe Hard Compact FIG 12 - Histograms of the iron grade for diff erent ore types of the standard itabirites and haematites. Friable Semi-compact Compact Hard compact n 1.478 1.018 984 2.905 Maximum 68.9 64.9 65.4 68.4 Percentile 95% 62.5 60.0 53.8 45.7 3rd quartile 56.6 49.9 42.3 38.3 Average 48.6 43.2 38.5 36.0 1st quartile 42.0 36.2 33.6 32.7 Percentile 5% 30.9 28.4 27.7 28.1 Minimum 10.6 11.3 13.2 11.7 Standard deviation (SD) 10.09 9.80 7.73 6.19 Variance 101.83 95.96 59.76 38.29 TABLE 2 Statistics of the iron grade for the diff erent types of haematite and standard itabirites (in per cent). IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 L Q AMORIM AND F F ALKMIM 68 n = 2905 w1 Fe SiO 2 P Al 2 O 3 LOI CaO MgO Maximum 97.7 68.4 81.5 0.440 7.84 11.19 1.37 1.22 Percentile 95% 88.6 45.7 58.7 0.077 1.17 3.66 0.12 0.18 3rd quartile 84.3 38.3 52.3 0.036 0.42 0.99 0.03 0.05 Average 80.2 36.0 47.0 0.030 0.37 0.87 0.03 0.07 1st quartile 75.9 32.7 43.5 0.014 0.14 0.17 0.01 0.05 Percentile 5% 71.4 28.1 32.0 0.007 0.05 0.03 0.01 0.05 Minimum 70.1 11.7 1.1 0.003 0.05 0.00 0.01 0.05 SD 5.4 6.2 9.2 0.028 0.49 1.22 0.07 0.09 Variance 29.3 38.3 85.2 0.001 0.24 1.49 0.00 0.01 TABLE 3 Statistics of the chemical characteristics of the hard compact itabirite (in per cent). 0,0% 0,3% 0,3% 2,4% 9,1% 26,7% 48,3% 10,4% 2,1% 0,0% 0,5% 0,0% 0,0% 0,0% 0% 20% 40% 60% Relative frequency 0, 3% 0, 5% 0, 8% 0, 8% 0, 8% 0, 0% 0, 3% 0, 8% 0, 0% 0, 3% 0, 5% 0, 5% 0, 5% 0, 5% 6, 7% 11 ,5 % 34 ,7 % 35 ,2 % 4, 0% 1, 3% 0% 5% 10% 15% 20% 25% 30% 35% 40% Re la ti ve fr eq ue nc y 0 10 20 30 40 50 60 70 0 20 40 60 80 100 % Fe % > 6,35 mm FIG 13 - Distribution of W1 and iron grade for the magnetitic itabirite. n = 375 w1 Fe SiO 2 P Al 2 O 3 LOI CaO MgO Maximum 98.3 53.2 71.4 0.242 6.96 32.22 20.53 14.30 Percentile 95% 90.6 38.4 47.1 0.043 1.02 16.34 11.18 7.84 3rd quartile 86.6 33.5 40.7 0.029 0.24 10.19 7.13 5.23 Average 80.4 30.7 38.2 0.028 0.30 7.70 5.11 4.34 1st quartile 80.3 28.3 35.5 0.021 0.05 4.55 2.68 3.02 Percentile 5% 57.0 22.2 29.0 0.014 0.05 1.29 0.22 1.34 Minimum 0.0 9.4 16.6 0.003 0.05 0.16 0.01 0.05 SD 14.7 5.1 5.6 0.022 0.65 4.81 3.40 2.04 Variance 215.9 26.4 31.4 0.000 0.42 23.14 11.57 4.17 TABLE 4 Statistics of the chemical characteristics of the magnetitic itabirite (in per cent). IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 NEW ORE TYPES FROM THE CAUÊ BANDED IRON FORMATION, QUADRILÁTERO FERRÍFERO, MINAS GERAIS, BRAZIL 69 half of Serra Azul (Eastern Mine, Camargos and Pau de Vinho deposits). The statistics of 441 core samples of this ore type is shown on Table 5 and the distribution of iron grade and W1 parameter on Figure 15. Differently from the hard itabirites, more than 50 per cent of the iron grades are smaller than 30 per cent, typically averaging 29 per cent Fe. Comparison between the three major ore types The SiO 2 , Fe, and CaO+MgO contents of the hard compact itabirite, magnetitic itabirite and AIF are represented in the triangular diagram of Figure 16. Due to the absence of CaO and MgO in the hard compact itabirite and argillaceous iron formation, they plot along the Fe-SiO 2 axis. Thus, an increase in Fe in these rock types implies in a decrease in SiO 2 and vice versa. The magnetitic itabirite, on the other hand, containing CaO and MgO, plot in central sector of the diagram. Its distribution shows that an increase in the CaO+MgO content implies in an approximately equal decrease in both Fe and SiO 2 . LOI CaO MgO FIG 14 - Triangular diagram CaO-MgO-LOI for the magnetitic itabirite. n = 441 w1 Fe SiO 2 P Al 2 O 3 LOI CaO MgO Maximum 78.7 57.1 83.0 0.620 16.66 12.92 0.15 1.44 Percentile 95% 55.3 45.6 73.8 0.203 6.58 7.78 0.06 0.44 3rd quartile 24.7 36.0 58.2 0.125 3.38 5.30 0.03 0.21 Average 17.5 28.6 48.5 0.097 2.81 4.21 0.03 0.18 1st quartile 4.7 21.5 40.1 0.054 1.54 2.90 0.02 0.05 Percentile 5% 0.8 11.7 21.9 0.028 0.65 1.24 0.01 0.05 Minimum 0.0 7.5 5.7 0.011 0.33 0.60 0.01 0.05 SD 16.9 10.5 14.9 0.069 2.16 2.09 0.02 0.18 Variance 284.4 109.7 222.6 0.005 4.66 4.37 0.00 0.03 TABLE 5 Statistics of the chemical characteristics of the argillaceous iron formation (in per cent). 0,0% 2,5% 10,7% 9,5% 12,5% 18,6% 19,0% 14,1% 7,3% 3,2% 1,8% 0,9% 0,0% 0,0% 0% 5% 10% 15% 20% Relative frequence 27 ,0 % 15 ,9 % 13 ,8 % 10 ,7 % 8, 4% 6, 3% 3, 6% 4, 1% 1, 1% 1, 8% 2, 0% 1, 4% 1, 4% 1, 4% 0, 2% 0, 9% 0, 0% 0, 0% 0, 0% 0, 0% 0% 5% 10% 15% 20% 25% 30% Re la ti ve fr eq ue nc y 0 10 20 30 40 50 60 70 0 20 40 60 80 100 % Fe % > 6,35 mm FIG 15 - Distribution of W1 and iron grade for the argillaceous iron formation. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 L Q AMORIM AND F F ALKMIM 70 CONCLUSIONS The enormous demand for iron ore in the last ten years is causing a rapid depletion of the ores traditionally exploited in the QF. In order to maintain the present status of the QF as global iron ore producing area, exploitation of low grade and compact ores, so far considered waste, will be necessary. In this scenario, the Mineração Usiminas project conducted in Serra Azul is pioneer in increasing the knowledge on fresh itabirites and incorporating them in the category of ore. Three new types of lower grade ores (~36 per cent Fe), namely standard itabirite, magnetitic itabirite and argillaceous iron formation, have been include in the Serra Azul reserves. The project is being very successful, even considering all technological, economic and environmental challenges to be faced in the next years. ACKNOWLEDGEMENTS L Q Amorim is grateful to the Mineração Usiminas for permitting the publication of the Serra Azul project data. F F Alkmim benefi ted from the Conselho Nacional de Desenvolvimento Científi co e Tecnológico – CNPq research grant #307531/2009- 0. The manuscript of this paper benefi ted from comments and constructive criticism by an anonymous reviewer. REFERENCES Alkmim, F F, 2009. Geologic outline of the Curral ridge between the Paraopeba valley and Ponta da Serra. Mineração Usiminas, 54 p, unpublished technical report. Alkmim, F F and Marshak, S, 1998. Transamazonian Orogeny in the southern São Francisco craton region, Brazil: Evidence for Paleoproterozoic collision and collapse in the Quadrilátero Ferrífero, Precambrian Research, 90:29-58. Babinski, M, Chemale Jr, F and Van Schmus, W R, 1995. The Pb/ Pb age of the Minas Supergroup carbonate rocks, Quadrilátero Ferrífero, Brazil, Precambrian Research, 72:235-245. Carneiro, M A, Teixeira, W and Machado, N, 1994. 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Zucchetti, M, Baltazar, O F and Raposo, F O, (eds), 1998. Rio das Velhas Project – Explanatory note of the geologic map, 1:100.000 scale, DNPM/CPRM Brazilian Geological Survey, 157 p. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 73 INTRODUCTION Five fundamentally different processes can yield high-grade iron ore products from unmineralised iron formation, or its precursor sediment (Figure 1). From these, four are natural processes and one is industrial. Iron ore formation through syngenetic or early diagenetic processes Syngenetic iron ore genesis models postulate that iron enrichment is either a primary depositional feature or an early diagenetic modifi cation of iron formation. A syn-diagenetic- supergene concept of ore formation is best described in recent papers by Lascelles (2006a, 2006b) who advocates formation of a ‘chert free BIF’ during diagenesis (summarised in Figure 2). In this model, density currents, with ultra-fi ne colloidal iron oxides, iron silicates and minor iron carbonates deposited iron-rich sediments on to an unstable sea fl oor. Chert formed from the diagenetic dissociation of unstable iron-silicates into hydrous iron oxides and gelatinous silica. Unstable conditions induced fracturing of the iron oxide bands and the forced escape of gelatinous silica under pressure of the overlying iron-rich sediments. Subsequent collapse of the overlying sediment induced further fracturing with a ‘domino-effect’ to the top of the sediment, producing large volumes of chert- free BIF, however with the original carbonates and some iron silicates preserved (Lascelles, 2006a, 2006b). Subsequently the iron formations and early ore deposits were completely oxidised and further leached, to depths exceeding the current mine and drilling depths. This deep oxidation gives the early ore deposits their high goethite contents. The silica that was removed from the orebodies could form cappings over high-grade ores, or occur on the contact of overlying shales. The location of syngenetic ore concentrations could also be controlled by syn-sedimentary structures, since these are the main cause of unstability in the sedimentary pile. 1. Principal Geologist, Rio Tinto Exploration Pty Ltd, 37 Belmont Avenue, Belmont WA 6104. Email: hilke.dalstra@riotinto.com From Banded Iron Formation to Iron Ore – Genetic Models and Their Application in Iron Ore Exploration in the Hamersley Province, Western Australia H J Dalstra1 ABSTRACT High-grade iron ore may be derived from banded iron formation (BIF) through four fundamentally different processes: 1. syngenetic precipitation of chert free BIF, 2. residual enrichment by removal of gangue minerals from BIF to form bedded (residual) iron ore, 3. mechanical erosion of iron oxide and chert from bedded iron ore or BIF and re-deposition and upgrading as detrital iron ore, and 4. chemical removal of iron from BIF and precipitation elsewhere as a secondary (channel) iron deposit. Finally, the BIF itself may constitute iron ore if a high-grade concentrate utilised for pellets or sinters can be derived from it through mechanical (industrial) separation of iron oxide by means of crushing/milling and mineral separation. Historically, exploration for high-grade BIF hosted iron ores was focused on the residual (bedded) deposits and driven by supergene concepts. Exploration for detrital and channel type iron ores was mostly secondary to exploration for bedded deposits, but recently, a more focused exploration effort has led to the discovery of enormous moderate to low iron grade deposits in the Pilbara region of Western Australia. Exploration for high-grade iron ores using syngenetic concepts has been limited, but together with exploration using hypogene concepts offers the best hope of fi nding concealed deposits. Exploration for BIF sources suitable for concentrate ores commenced in the ‘old’ iron ore provinces after the high-grade resources were depleted and has only recently gained importance in Australian BIF provinces, mainly as a result of high iron ore prices in the last decade. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 H J DALSTRA 74 Exploration using syngenetic concepts has been modest in the Hamersley province. Early exploration in the Hamersley province based on these concepts focused on the presence of syn-sedimentary structures which could have triggered the collapse of the sedimentary pile and on the presence of anomalous concentrations of silica above the target iron formations. Application of this concept led to the discovery of signifi cant concealed, high-grade, low P mineralisation, named Lens 2 and Lens 3 deep below the outcropping ores at Paraburdoo. However, mineralisation at these sites occurs within the weathered zone, and shows abundant wall rock alteration so supergene and hypogene concepts cannot be excluded for its origin. Syngenetic concepts offer possibly the best hope of fi nding large, concealed moderate to high-grade iron ore deposits in the Hamersley province. The syngenetic concept of Lascelles (2006b) postulates the presence of large moderate to high- grade magnetite orebodies with small amounts of diagenetic carbonate and silicates below the weathered surface. Because of their early formation, these orebodies should have low porosities (comparable to primary BIF) and therefore high densities and should show signifi cant reduction in thickness compared to the unmodifi ed iron formation. However, they would not have signifi cant alteration haloes. Exploration targeting for such orebodies would be diffi cult, because they would have very little geological or geochemical surface expression. Geophysical methods, particularly gravity could be utilised to target zones of anomalously high density although the thinning of the host BIF at the site of mineralisation would probably obliterate much of the expected anomaly. Residual iron ore formation through removal of gangue minerals – bedded ores Residual ore formation means removal of all-, or most gangue minerals from the BIF, while preserving the iron oxides to form a high-grade residual or bedded iron ore. Although ore genesis models vary in fundamental aspects of the fl uids involved, and the timing and sequence of the removal of the gangue minerals, most agree that iron enrichment was predominantly the result of residual concentration, rather than iron addition to the mineralised sites. Hypogene genetic models propose that gangue minerals were mostly removed by ascending fl uids, either warm basinal brines (eg Taylor et al , 2001; Thorne, Hagemann and Barley, 2004) or hotter magmatic fl uids (Lobato et al, 2008). Supergene models postulate that descending meteoric or modifi ed meteoric waters were largely responsible for gangue removal (eg McLeod, 1966; Morris, 1985). Several models propose multistage ore formation through sequential removal of gangue minerals from the BIF by a combination of supergene and hypogene processes (eg Taylor et al, 2001). Supergene models for residual iron ore formation offer limited hope for discovery of concealed deposits. The prerequisite of the supergene concept, that ores are formed by descending solutions, implies that all orebodiesshould have a surface expression. The only exceptions are ancient supergene deposits which could occur below palaeo-unconformity surfaces, which are particularly prominent in the southern Hamersley province (eg the lower and upper Wyloo unconformities). Exploration on the basis of recent supergene concepts led to rapid delineation of outcropping iron ore resources Precipitation as oxide-only BIF or diagenetic removal of silica BANDED IRON FORMATION Magnetite or hematite concentrate Mining, milling and mineral separation Chemical removal or replacement of gangue minerals from BIF Supergene Hypogene Hematite-goethite ores Soft hematite ores Enriched BIF ores Magnetite-hematite ores Magnetite-hematite-carbonate proto-ores Supergene overprinting Hematite (goethite) ores Pellets or sinter Burial Hematite ores Erosion Detrital ore Cementation Canga BIF precursor sediment Burial, diagenesis, metamorphism and deformation Chert free BIF Burial Hematite conglomerate Weathering Chemical removal of iron oxide from BIF iron in solution Transport and reprecipitation Channel Iron Deposit BIF gravel Supergene overprinting Detrital ore Canga Physical Chemical Pisolitic soil Transport and cementation Supergene overprinting Hematite-(goethite) ores Channel Iron Deposit Processing FIG 1 - Schematic presentation of processes leading from banded iron formation to high-grade iron ore. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 FROM BANDED IRON FORMATION TO IRON ORE – GENETIC MODELS AND THEIR APPLICATION IN IRON ORE EXPLORATION 75 in the Hamersley Province in the early 1960 ties. However, applying recent supergene concepts to iron ore exploration led to serious underestimation of the size of some deposits, particularly at Mount Whaleback. Although the deposit was discovered in 1957 by prospector Stan Hilditch, and brought to the attention of several mining companies including Rio Tinto, even after a considerable amount of drilling was carried out the resource was estimated at a modest 225 Mt (MacLeod, 1966). Outcropping iron ore at Mt Whaleback occurred in relatively narrow bands up to 20 m in width, with signifi cant areas of unmineralised iron formation in between. Only after deep drilling was carried out, the presence of continuous and deep mineralisation below the narrow outcrops was recognised. Morris’s refi ned supergene-metamorphic model allows for deeper, semi-concealed orebodies like Mt Whaleback, but postulates that, unless the deposits have gone through a post- metamorphic leaching stage to remove the remnant goethite, and with it, the bulk of the phosphorous, the ores may not reach the quality to counter the economic problems of deep overburden (Morris, 1997). This model formed the backbone of a concealed orebody search (COBS) by Hamersley Iron from 1980 to 1994. Critical aspects of the exploration model were the presence of structural zones of permeability (faults, dykes, cross folds, etc) extending from surface to a possible mineralisation site at depth, and proximity to a major Palaeoproterozoic topographic feature, in this case the Mt McGrath Trough. This allowed for supergene upgrading of BIF in early Proterozoic times. Although the program was unsuccessful in delineating a new large high-grade haematite resource in the Hamersley Province, several small occurrences of microplaty haematite were discovered in the Paraburdoo Western Ranges. These deposits occur underneath palaeoproterozoic unconformities deep below the present land surface, and are overlain by unmineralised BIF. Supergene concepts offer little hope of fi nding large new deposits in areas of outcropping iron formation. However, signifi cant potential still exists in areas with abundant post-ore cover. Signifi cant recent discoveries along the margins of the Fortescue Valley including the down dip mineralisation in the Marra Mamba BIF along the Chichester Range, concealed mineralisation in the Brockman BIF at Iron Valley and Nyidinghu, and concealed mineralisation in the Boolgeeda BIF north of Newman testify to the exploration potential below cover. H O2 H O + SiO2 2 H O2 A: Deposition of BIF as nontronite- Fe-hydroxide turbiditic mud B: Breakdown of nontronite to Fe-oxide and colloidal silica D: De-watering and escape of silica leads to localized formation of chert-free BIF Cherty BIF Cherty BIF Chert-free BIF E: Erosion exposes chert-free BIF, supergene processes form weathered cherty BIF and hematite or hematite-goethite ore C: Settling of Fe-oxide Nontronite Fe-hydroxide Silica Fe-oxide FIG 2 - Syngenetic/diagenetic ore genesis model presenting development of high-grade iron ore from banded iron formation (Lascelles, 2006b). IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 H J DALSTRA 76 A hypogene concept for the genesis of residual, high- grade haematite deposits was introduced by the Hamersley Iron Resources Task Force in 1995 (Figure 3). Fundamental aspects of this model were the presence of early normal faults to link deep carbonate aquifers with BIF, and the presence of alteration signatures in BIF (carbonate, microplaty haematite) and shales, dolerites or basalts (chlorite and talc), as well as evidence for deep weathering (Taylor et al, 2001). The latter is necessary for the fi nal upgrading of apatite and carbonate bearing protore to high-grade haematite ore. As for the COBS, application of this model was largely unsuccessful in the search for another large, high-grade haematite deposit in the Hamersley Province. In the period from 1996 to 2005 approximately 65 targets for high- grade haematite had been generated and drill tested. This resulted in the intersection of high-grade (microplaty) haematite mineralisation at fi ve targets. Most signifi cant is the Wellthandalthaluna deposit (45 Mt @ 63.4 per cent Fe), a deposit which shares many characteristics with the Mt Tom Price deposit, particularly North deposit, be it on a much reduced scale. The deposit occurs in a faulted block of Brockman iron formation and contains microplaty haematite as well as magnetite-rich sections in the outcropping mineralisation. Across the main controlling structure, carbonate and talc alteration is common in protore in the base of the Dales Gorge member, in a downfaulted part of the deposit (Figure 4). This geometry is very similar to that of Mt Tom Price Southern Ridge or North Deposits, albeit in mirror image. A much larger fault juxtaposes mineralisation against unmineralised Fortescue Group rocks, resulting in a set-up with much less ore preserved than at Mt Tom Price. Even though by now most outcrops of microplaty haematite in the Pilbara have been identifi ed and drill tested, hypogene concepts still offer signifi cant potential for discovery of large concealed deposits. Such deposits would be situated below unmineralised iron formation or below the Proterozoic EROSION AND WEATHERING STAGE: Deep weathering results in removal of apatite Microplaty hematite-martite ore OXIDATION STAGE: Oxidized low salinity meteoric fluids Overprint by microplaty hematite Microplaty hematite-martite-ankerite (apatite) mineralization HYPOGENE STAGE: Upward migration of brines magnetite-carbonate (apatite) mineralization Joffre Member Dales Gorge Member Whaleback Shale Member MT MCRAE SHALE MT SYLVIA FORMATION BROCKMAN IRON FORMATION Stratigraphy WEELI WOLLI FORMATION Bee Gorge Member Paraburdoo Member WITTENOOM FORMATION Fault Material Types Hematite- (carbonate) apatite Magnetite -carbonate -apatite Hematite Southern Ridge meteoric fluids Depth of weathering Fluid flow FIG 3 - Hypogene ore genesis model presenting development of high-grade iron ore from banded iron formation (modifi ed from Taylor et al, 2001). IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 FROM BANDED IRON FORMATION TO IRON ORE – GENETIC MODELS AND THEIR APPLICATIONIN IRON ORE EXPLORATION 77 unconformities. The only geological indication for their existence could be in the form of a prospective geological structure or the presence of alteration minerals in outcropping BIF, shales or mafi c rocks. Iron ore formation through redeposition – detrital ores Until today, high-grade detrital iron ores have generally been mined as a by product of the much larger residual or bedded iron ore deposits. Canga (cemented haematite detrital) deposits of modest size, but of acceptable grade often immediately overlie residual deposits, and sometimes provide the fi rst iron ore in a new mining operation. Recently enormous (billions of tonnes) low to medium grade detrital iron deposits have been discovered in the central Hamersley province, an area with relatively few bedded high-grade deposits. It is possible that these will soon provide a signifi cant part of iron ore production from the province. Despite this imminent importance of detrital iron ores, they remain one of the least understood ore types of the province. Detrital iron ores of the Hamersley province can be subdivided into three distinct types: 1. Hard microplaty haematite conglomerates associated with the palaeoproterozoic Upper Wyloo unconformity. These are generally believed to be breakdown products of Proterozoic microplaty haematite deposits, and are generally too small to form economic deposits. 2. Canga associated with the Tertiary Hamersley Surface: cangas are goethite or limonite cemented haematite conglomerates, mostly well sorted, and often displaying crude bedding. These have been mined economically in for example the Brockman detrital deposit. 3. Loose haematite gravels: these gravels are moderate to well sorted masses consisting of rounded haematite pebbles in a silt or clay matrix. Bedding is generally absent. They are subclassed into mature (>60 per cent Fe) and immature (<60 per cent Fe) detrital mineralisation. A distinct group are the red-ochre detritals which are relatively fi ne grained iron-rich gravels characterised by abundant ochrous haematite. Excluding the hematite conglomerates, red ochre detritals are considered the oldest form of detrital material in the province, and often underlie channel iron deposits (CID). Mature, high-grade detrital ore was also mined in the Brockman detrital deposit. Although the genesis of the Proterozoic haematite conglomerates as breakdown products of microplaty haematite deposits is considered relatively straightforward, the genesis of the latter two styles is less clear. Detrital iron ore deposits generally share a set of common features discussed below (see also Figure 5). Canga is the second oldest form of detrital material and overlies deeply weathered bedrock at the base of the detrital pile. Canga’s were deposited on relatively steep topography, signifi cantly steeper than the slopes on which younger mature detritals were deposited. This may suggest that the terrain was stabilised by dense vegetation in a wetter climate. Rare collapse breccias or landslides formed when larger rock masses collapsed during erosion of the palaeo range fronts. The hard canga formed by cementation of a clay matrix (Killick, Churchward and Anand, 2008), and transformation of the clays to goethite and limonite. The contact between canga and overlying uncemented mature detritals is generally unconformable, suggesting that this canga surface began to break down before deposition of the mature detritals. The canga surface was incised, and boulders of eroded canga, together with haematite pebbles from another high-grade haematite source, were deposited to form the mature detrital fans. The mature detrital fans are unique among normal alluvial fan systems in that they have a relatively uniform grain size, a monomineralic (Fe-rich) composition, a general absence of silty or sandy layers and a very homogeneous (non-bedded) HG WS DG3 DG2 DG1 FWZ ENE RL 350m DDHWLT08 qtz veining abundant J6 J5 J4 J3 J2 J1 FWZ HG HG DDHWLT01 DDHWLT02 HG HG FOR Depth of Weathering WSW Joffre Member Dales Gorge Member Whaleback Shale Member MT MCRAE SHALE MT SYLVIA FORMATION BROCKMAN IRON FORMATION WITTENOOM FORMATION Hematite (magnetite) Hematite-goethite (magnetite) Dolerite Dyke N o rth e rn F a u lt FORTESCUE GROUP Pillow lava & dolerite Sheared rocks Metres 0 50 100 150 200 MARRA MAMBA FORMATION Diamond drillhole Hematite/ magnetite carbonate (talc) DDHWLT01 B o o lg e e d a C re e k F a u lt VV V V V V V V V V V V VV V DDHWLT07 (proj.) DDHWLT05 DDHWLT09 (proj.) WESTERN AUSTRALIA Perth Section Area FIG 4 - Cross-section through the Wellthandalthaluna deposit showing outcropping high-grade haematite (goethite, magnetite) ore and concealed magnetite-carbonate-talc protore. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 H J DALSTRA 78 character. This suggests that they formed under special conditions, and that they have a very restricted source region. They are probably sheet wash deposits or seeve fans. Sporadic fl ash fl oods with a low mud and sand content fl owed evenly over previous deposited sediments on the fans. Due to the high porosity of the underlying detritals, water was quickly extracted from these fl oods, with the remaining gravels forming an evenly thick sheet over the entire fan. Low sediment loads of these fl oodwaters may indicate a dense cover of vegetation during deposition of the mature detritals. Ancient ValleyAncient Valley Bedded iron ore Hamersley Surface Erosion products forming mature detrital fan on steep slope Erosion of bedded ore and Hamersley Surface material Cementation and upgrading of detritals to form canga Further erosion of bedded ore and canga Erosion products forming mature detrital fan in trap site Rapid incision of BIF bedrock Erosion products forming colluvial cover Canga outcrop >45Ma <5Ma Oligocene to Miocene Late Miocene to Pliocene hardcap Wittenoom Formation (dolomite) MCRae/ Mt Sylvia Formations (shale) Brockman Iron Formation Mature detritals (concealed) Hamersley surface partly preserved below detrital sequence FIG 5 - Six stage ore genesis model showing the formation of Brockman type high-grade detrital iron ore. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 FROM BANDED IRON FORMATION TO IRON ORE – GENETIC MODELS AND THEIR APPLICATION IN IRON ORE EXPLORATION 79 After deposition of the mature detritals, a renewed period of exposure and erosion started. This resulted in the formation of a hard cap on the detrital surface. The partly eroded mature detritals were subsequently overlain by lower grade detritals and colluvium. These formed more typical alluvial fan systems, with localised channels (fi ning up) and a predominance of mass-fl ow deposits or olistostromes which were generated by fl ood waters with higher mud content. The resulting sediments are mostly coarsening up conglomerates and pebbly mudstones. The last (and presently continuing) stage of geological activity is intersection and erosion of the detrital and colluvium deposits, and continued erosion of the cangas as a result of a recent base-level drop. There are two possible origins for the iron rich pebbles in detrital deposits: 1. mechanical breakdown of pre-existing residual (bedded) iron ores and redeposition of the ore clasts as high-grade detrital deposits; and 2. mechanical breakdown of BIF, redeposition of the clasts as BIF gravels, followed by in situ upgrading of these deposits to high-grade detrital ores (see also Figure 5). In the Hamersley province the largest detrital deposits occur in the north, an area with relatively few residual iron ore deposits. Although some deposits may be spatially associated with bedded iron ore, many do not show this relationship. Explorationby Rio Tinto for detrital iron ores in the Hamersley Province was initially focused on drilling of outcropping canga mineralisation, and scout drilling of cover sequences adjacent to these canga outcrops to target the concealed mature detrital fans. The presence of outcropping bedded mineralisation was not a signifi cant factor in targeting. Later the signifi cance of trap sites for hosting high- grade detrital ores was recognised. These trap sites can form by erosion along suitable structures such as synclines or fault zones and can often result in narrow but deep ‘channels’ or pods of detrital material. Targeting for detrital ores was often assisted by narrow spaced ground gravity, because the detrital pods have good density contrast with the shaly host rocks (Flis, Butt and Hawke, 1998). Only recently the signifi cance of more widespread, lower grade detrital mineralisation in the northern parts of the Hamersley province has been recognised. These deposits often overlie channel iron deposits in the major drainage channels of the central Hamersley Province. Signifi cant new resources totalling several billions of tonnes have been identifi ed recently at Caliwingina, Serenity and Kings (Clarke et al, 2009; Dalstra et al, 2010), and in the Fortescue Valley at Koodaiderie and Marilana. Exploration for this style of mineralisation is currently still happening, and it is likely that more resources will be added in the near future. Iron ore formation through secondary precipitation – channel iron deposits Although secondary precipitation of iron at the site of the ore deposits is part of many ore genesis models, only in the formation of channel iron deposits it may have played a dominant role. For example, replacement of gangue minerals by goethite is part of the supergene metamorphic model of Morris (1985), but leaching of gangue resulting in volume loss and porosity increase appears to be the dominant factor of generating the bedded ore from BIF. Along the same line of arguing, some iron addition must have taken place during cementation of matrix material in canga by goethite. The currently favoured ore genesis models see the genesis of CID as a combination of detrital and secondary enrichment processes (Harms and Morgan, 1964; Macleod, 1966; Morris and Ramanaidou, 2007; Dalstra et al, 2010) (see also Figure 6). The models propose that iron enrichment occurred as a result of normal weathering processes of the iron rich B: replacement stage in headwaters iron in solution: 3+ 2+ Fe + organic = Fe (aq) A: channel fill stage silica taken out of the system: 0 SiO (am)+ 2H O + organic = H SiO2 2 4 4 in regolith: pisoide formation mechanical transport of pisoids to channel replacement of matrix and wood in sediment: 2+ Fe (aq) = Fe + e 3+ + Fe + 3H O = Fe(OH) + 3H2 3 3+ - C: inversion e.g. Robe, Beasley C: concealment e.g. Bungaroo, Caliwingina, Kings basaltic or shaly basement colluviumdetrital ores alluvium, clay, calcrete basal conglomerate vv vv vvv v v vvvvv vvv vv vv v v v vvv vv vv BIF basement FIG 6 - Three-stage ore genesis model presenting the formation of channel iron deposits type iron ore. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 H J DALSTRA 80 country rocks producing a deep regolith. During this phase, iron was transported in solution from the bedrock to the overlying soil profi le where it redeposited in the form of iron- rich pelletoids. Erosion stripped these from this surface and slowly transported them to the channels, where they were redeposited. The initial channel fi ll was probably an iron rich mud, comprising pisoids, iron rich peloids and wood fragments, all in a fi ne grained silty matrix. Reduced iron rich groundwaters derived from source rocks in the headwaters of the channel carried iron in solution to these channel sediments possibly over a distance of hundreds of metres to kilometres. There, the iron was reprecipitated resulting in replacement of the silty matrix and the wood fragments by goethite. After formation of the CID, the channels were either inverted to mesas, or covered by younger detrital ores, colluvium and/or alluvium. Concealment occurred in areas where the bedrock comprised hard BIF, while inversion to mesas was favoured by softer basement rocks such as basalt or shale. The fi nal textures of the iron (hydroxides) of the CID do not resemble that of the BIF, because solution and reprecipitation has all but destroyed the initial texture of the iron (hydr)oxides. Exploration for CID in the Hamersley province began in the early 1960s, even before recognition of the signifi cance of the high-grade haematite deposits. The fi rst deposits brought to the attention of RTZ by Hancock in early 1961 were in fact channel deposits, the Beasley River limonites and the Duck Creek CID’s, both of which remain unmined today. Recognition of the Robe River and Yandicoogina deposits followed soon. These early discovered deposits were mesas, channel systems where the CID profi le has been inverted through later erosion during the ongoing aridifi cation of the Australian continent. The Bungaroo Creek system was the fi rst CID system with a very large concealed resource, although it still has signifi cant outcrops in the upper reaches of the channel. CID exploration by Rio Tinto from 2000 onwards focused on this concealed aspect of the CID, either below recent alluvials or below calcrete of the Oakover formation (Figure 6). The exploration model was simple, and encompassed an interpretation that CID deposits after their fi nal accumulation stage could be entirely concealed in their channels. Inversion to mesas would only occur in areas where modern drainages follow the ancient, and have signifi cantly incised their current bedrock. Application of this model by Rio Tinto and others recently led to discovery of an entirely new CID district in the Central Hamersley Ranges, more than 40 years after the fi rst mesas were discovered. This district encompasses the Caliwingina, Serenity and Kings CID systems. Total CID mineralisation in this area is of the order of several billions of tonnes and is of comparative size to the premining resources at Robe/Bungaroo Creek and slightly smaller than Yandicoogina (Dalstra et al, 2010). The potential to discover signifi cant new outcropping CID systems in the Pilbara is limited. Any future exploration should focus on the concealed systems. The task is made more diffi cult because most large drainage channels of the Hamersley Range have now been tested by drilling. The discovery of the Solomon CID deposit in the northern Hamersley Range demonstrates that understanding landscape evolution and (re) interpreting palaeodrainage patterns is crucial for targeting new CID systems in the province (Clarke et al, 2009). CONCENTRATE IRON ORES THROUGH CRUSHING, MILLING AND BENEFICIATION OF BANDED IRON FORMATION The appearance of mines dedicated to the mining of unmineralised iron formation as a source of magnetite or haematite concentrate is a relative new development in Western Australia. At the moment this activity is focused in the extreme northwestern part of the Hamersley province where proximity to the ocean avoids the high transportation costs of projects further inland. Geological factors that determine the economics of a concentrate operation from BIF include the amount of ore and ore to waste ratio during mining, the overall iron grade of the BIF, the minimum grind size to obtain a high-grade concentrate, the recovery of iron oxide from the BIF and the hardness of the ore. In general, soft, coarse grained ores with a relatively high in-ground iron grade are more likely to yield an economic concentrate than hard, fi ne grained and low iron grade ores. Ore to waste ratios during mining are largely determined by the amount of overburden, the thickness and dips ofthe ore (BIF) bands and the relative percentage of intercalated waste bands. The minimum grind size is determined by the grain size of the oxides, their textures and the presence of inclusions such as apatite or pyrite. Recoveries are generally determined by the head grade of the ore (the amount of iron oxide in the rock), the mineralogy and texture of the ore and the grain size. Ore hardness on the other hand is largely determined by weathering, and to a lesser degree by mineralogy and metamorphic grade. Another important factor is the performance of the concentrating plant, which is largely defi ned by consistency of the ore feed. In extreme cases, feeding a coarse grained ore into a plant that was designed for fi ner grained material can lead to poorer plant performance. Concentrate ore processing plants utilise either a magnetite circuit or a haematite circuit. Both haematite and magnetite circuits involve either: three (and four) stage crushing followed by primary and secondary milling to the required grain size (for fi ne grained ores <25 μm); primary crushing followed by semi-autogenous or autogenous milling; or air swept autogenous milling (Dowson, Connely and Yan, 2009). High pressure grinding rolls are a relatively new, but cost-effective technology to crush magnetite ores and is a technology based on interparticle breakage more than direct compression (Povey, 2009). Ultra-fi ne grinding is required for some ores, however, this is an energy intensive operation that needs to be well optimised and needs specialised magnetic separators (Li et al, 2009). In haematite circuits gangue minerals are rejected through a combination of fl occulation, desliming and fl otation processes. The concentrate is then thickened, fl ux is added and subsequently moulded into small pellets in a balling drum. These are baked in a kiln, before dispatch to the blast furnaces. Magnetite circuits are similar, but ore is concentrated through magnetic separation rather than fl otation. Magnetic separation can be achieved by low intensity magnetic separation (LIMS) using conventional or rare earth magnets in a rotating drum, or wet high intensity magnetic separation (WHIMS), using extremely strong magnetic fi elds to remove weakly magnetic particles from the processing stream. Recent innovations are machines that utilise the combined forces of magnetism, pulsating fl uid and gravity to continuously benefi ciate fi ne weakly magnetic minerals. Production of the pellets is similar to haematite circuits. Benefi ciation operations will generally result in the production of three materials: a salable concentrate, a low- grade product that is either reprocessed or stockpiled and tailings (Dowson, Connely and Yan, 2009). IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 FROM BANDED IRON FORMATION TO IRON ORE – GENETIC MODELS AND THEIR APPLICATION IN IRON ORE EXPLORATION 81 Until today there has been relatively little exploration effort focused on BIF suitable for concentrate iron ore in the Hamersley province. Most activity has been in the northwestern part where weathering profi les are generally thinner and magnetite-rich BIF occurs closer to surface. The province is host to four major BIF’s, the Marra Mamba, Brockman, Weeli Wolli and Boolgeeda iron formations with a combined thickness of over 1000 m. Work by Rio Tinto and others (Ewers and Morris, 1980, 1981; McConchie, 1987) demonstrates that BIF’s (excluding shales bands) of the Dales Gorge Member have the highest iron contents (approximately 32.5 per cent Fe), compared to Joffre (28 - 31.3 per cent Fe), Marra Mamba Newman Member (25.1 per cent Fe) and Weeli Wolli (21 - 25.6 per cent Fe). No data is currently available for the Boolgeeda BIFs. The average magnetite content of the Dales Gorge and Joffre BIFs is comparable at about 28 - 31 per cent, which is signifi cantly higher than the Marra Mamba BIF, which contains more iron in silicates and carbonates. The Brockman Iron Formation covers an outcrop area of approximately 10 000 km2. Even if less than ten per cent of the outcropping material could be mined and benefi ciated, this would still imply 1000 Bt of potential BIF source for magnetite concentrate and potentially 300 Bt of concentrate (at weight recoveries of approximately 30 per cent). The Balmoral project in the northwestern part of the Hamersley Province has reported a primary iron grade in the Joffre member of the Brockman Iron Formation of 31.3 per cent Fe, producing a high-grade concentrate of about 69 per cent Fe. Recovery of the iron is relatively low (approx 75 per cent of total iron recovered for a Davis Tube recovery of 32.1 per cent), possibly because of the presence of iron in non-magnetic minerals. Pilot studies by Rio Tinto and others in other parts of the Province suggest that total iron recoveries of other iron formations are generally lower (<50 per cent), and the produced concentrates of poorer quality than those at Balmoral. Exploration for magnetite or magnetite concentrate by Rio Tinto in Western Australia has been modest. Two projects resulted from analysis of regional magnetic data in the Hamersley Province; B26E in the Western Turner syncline targeted the Dales Gorge member and Silvergrass Peak in the northwestern Hamersley province targeted both the Joffre and Dales Gorge members. Both projects focused on BIF with anomalously high magnetic susceptibility. A third project targeted concealed eastern extensions to the Southdown deposit in the Albany Fraser Belt. This project resulted in delineation of signifi cant magnetite-concentrate resources, which were subsequently sold to Grange Resources. Opportunistic work was carried out on areas of the Hamersley province where fresh diamond core obtained in the search for high-grade deposits was available, such as North Deposit and Southern Ridge at Mt Tom Price, the Turner Syncline, Giles Mini and other parts of the Rhodes Ridge area. The Silvergrass Peak project incorporated drilling two deep diamond holes on separate intense magnetic anomalies (up to 140 000 nT) associated with a late NNE trending gabbroic dyke (Figure 7). The Silvergrass Dyke is an approximately 30 - 40 m thick hypersthene-gabbro, with a SHRIMP zircon age of 764 ± 10 Ma, and is a member of the Neoproterozoic Mundine Well dyke swarm of NW Australia (Wingate and Giddings, 2000). Drilling of the magnetic targets identifi ed signifi cant recrystallisation of the Joffre Member BIF adjacent to the gabbro dyke (Figure 7), however the lateral extent of this away from the contact was only 10 m. In the contact zone, the BIF is recrystallised into a mosaic aggregate of quartz, magnetite and amphiboles (magnesioriebeckite and cummingtonite). The latter comprise poikiloblastic textures, with grain sizes up to 5 mm. The main iron oxide was magnetite with a polygonal texture, which equated about 29 per cent by weight, which is similar to the magnetite content of other Joffre BIF in the province (McConchie, 1987). Up to half the reduced Fe was in DD00SGP002 0 40 80m Silvergrass Dyke (764+/-10Ma) Contact zone Joffre J6 Joffre J1 Joffre J2 Joffre J3 Joffre J4 Joffre J5 Joffre Sill 100 RL 200 RL 300 RL 400 RL 7 ,5 5 6 ,0 0 0 m N 482,000 mE480,000 mE 480,000 mE 478,000 mE 7 ,5 5 6 ,0 0 0 m N 7 ,5 5 8 ,0 0 0 m N 7 ,5 5 8 ,0 0 0 m N 7 ,5 6 0 ,0 0 0 m N DD00SGP002 0 0.5 1km WESTERN AUSTRALIA Perth Map Area 437.3m V V V V V V V V V V V V V V V V V V V V V V FIG 7 - Map and cross-section of the Silvergrass Peak magnetite project. Transparent magnetic image (ASVI, analytical signal of the vertical integral) draped over aerial photography. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 H J DALSTRA 82 silicates and carbonates. A 15 cm interval of massive coarse magnetite occursat the contact with the dyke. Because the drilling failed to identify signifi cant high-grade magnetite- rich BIF, the project was abandoned. Diamond drilling at the B26E project also failed to identify magnetite enriched BIF associated with the Dales Gorge member. Opportunistic mineralogical and metallurgical test work has been carried out on BIF of the Dales Gorge and Joffre members from a number of prospects in the Hamersley province. This work has shown that the mineralogy of unoxidised iron formation is dominated by silica and magnetite, with accessory haematite, siderite, riebeckite/crocidolite and ankerite/dolomite and traces of stilpnomelane and talc. Results from magnetic separation (Davis Tube) of BIF from these prospects are very similar to those reported at Balmoral and indicate that high quality concentrates suitable for blast furnace pellets with iron grades of around 69 per cent with low Al and P contents can be achieved from normal BIF at a grinding size of about 45 microns. Iron recoveries are relatively low (around 70 per cent, resulting in a total mass recovery of about 30 per cent) which is most likely due to the presence of iron in non-magnetic minerals such as siderite, iron silicate and haematite. Other problems associated with benefi ciation of Brockman BIF to a high-grade concentrate product are the great hardness of the rocks, and the widespread presence of fi brous minerals, particularly crocidolite. Future exploration for magnetite-concentrates in the Hamersley province could focus on the enriched magnetite- carbonate-silicate proto-ores predicted by both syngenetic and hypogene ore genesis models. However, work carried out to date suggests that these occurrences are small, and that in general the BIF’s show little chemical variation across the province. If future exploration fails to fi nd such deposits, focus should go to the mineralogically most attractive protores. These could include softer or coarser grained parts of the Brockman Iron Formation which would limit grinding costs, areas where iron occurs dominantly in the form of oxides increasing recovery, or areas where the absence of riebeckite in BIF limits the costs and hazards associated with fi brous minerals. ACKNOWLEDGEMENTS Special thanks to members of the RTX iron ore exploration team and the former Hamersley Iron Resources Task Force for stimulating discussions which were essential to form the ideas in this paper. Rio Tinto Exploration Pty Ltd, and Rio Tinto Iron Ore are thanked for permission to publish this paper. REFERENCES Clarke, N, Kepert, D, Simpson, C and Edwards, D, 2009. Discovery of the Solomon iron deposits, in Proceedings Iron Ore 2009, pp 51-57 (The Australasian Institute of Mining and Metallurgy: Melbourne). Dalstra, H J, Gill, T, Faragher, A, Scott, B and Kakebeeke, V, 2010. Channel iron deposits, a major new district around the Caliwingina Creek, central Hamersley Ranges, Western Australia, Transactions of the Institutions of Mining and Metallurgy , Applied Earth Science, 119(1):B12-B20. Dowson, N, Connely, D and Yan, D, 2009. Trends in magnetite ore processing and test work, in Proceedings Iron Ore 2009, pp 231-241 (The Australasian Institute of Mining and Metallurgy: Melbourne). Ewers, W E and Morris, R C, 1980. Chemical and mineralogical data from the uppermost section of the upper BIF member of the Marra Mamba Iron Formation, CSIRO report no FP23, Perth. Ewers, W E and Morris, R C, 1981. Studies of the Dales Gorge Member of the Brockman Iron Formation, Western Australia, Economic Geology, 76:1929-1953. Flis, M, Butt, A L and Hawke, P J, 1998. Mapping the range front with gravity, are the corrections up to it?, Exploration Geophysics , 29:378-383. Harms, J E and Morgan, B D, 1964. Pisolitic limonite deposits in northwest Australia, in Proceedings Australasian Institute of Mining and Metallurgy, 212:91-124. Killick, M F, Churchward, H M and Anand, R R, 2008. Regolith terrain analysis for iron ore exploration in the Hamersley province, Western Australia, fi nal report; CRC LEME open fi le report no 214, Bentley, Western Australia, 94 p. Lascelles, D F, 2006a. The Mount Gibson banded iron formation hosted magnetite deposit, two distinct processes for the origin of high-grade ore, Economic Geology, 101:651-666. Lascelles, D F, 2006b. The genesis of the Hope Downs Iron Ore Deposit, Hamersley Province, Western Australia, Economic Geology, 101:1359-1376. Li, Q, Tong, Z, Wang, X and Gao, M, 2009. A new magnetic drum separator for superfi ne magnetite, in Proceedings Iron Ore 2009, pp 255-258 (The Australasian Institute of Mining and Metallurgy: Melbourne). Lobato, L M, Figueiredo e Silva, R C, Hagemann, S, Thorne, W and Zucchetti, M, 2008. Hypogene alteration associated with high-grade banded iron formation related iron ore, Reviews in Economic Geology , pp 107-128 (Society of Economic Geologists Inc: Littleton). MacLeod, W N, 1966. The geology and iron deposits of the Hamersley Range area, Western Australia: Geological Survey of Western Australia, Bulletin 117, 1:170. McConchie, D M, 1987. The geology and geochemistry of the Joffre and Whaleback Shale Members of the Brockman Iron Formation, Western Australia, Precambrian Iron Formations (eds: P W Appel and G L LaBerge), pp 541-597 (Theophrastus Publications: Athens). Morris, R C, 1985. Genesis of iron ore in banded iron-formation by supergene and supergene-metamorphic processes: A conceptual model, Handbook of Strata-bound and Stratiform Ore Deposits (ed: K H Wolff), pp 73-235 (Elsevier: Amsterdam). Morris, R C, 1997. Iron ore: Is there ‘new’ life for old models, in Advances in Understanding the Hamersley Province , short course, pp 1-9 (The University of Western Australia: Nedlands, Western Australia). Morris, R C and Ramanaidou, E R, 2007. Genesis of the channel iron deposits (CID) of the Pilbara of Western Australia, Australian Journal of Earth Sciences, 54:735-759. Povey, B C, 2009. The use of high pressure grinding rolls for crushing magnetite, in Proceedings Iron Ore 2009 , pp 301-308 (The Australasian Institute of Mining and Metallurgy: Melbourne). Taylor, D, Dalstra, H J, Harding, A E, Broadbent, G and Barley, M E, 2001. Genesis of high-grade hematite orebodies of the Hamersley Province, Western Australia, Economic Geology, 96:837-873. Thorne, W S, Hagemann, S G and Barley, M E, 2004. Petrographic and geochemical evidence for hydrothermal evolution of the North Deposit, Mt Tom Price, Western Australia, Mineralium Deposita, 39:766-783. Wingate, M T D and Giddings, J W, 2000. Age and palaeomagnetism of the Mundine Well dyke swarm, Western Australia: Implications for an Australia – Laurentia connection at 755 Ma, Precambrian Research, 100:335-357. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 83 INTRODUCTION In this pilot study, we apply (U-Th)/He dating in combination with other analytical methods to investigate channel iron deposits (CID) in Western Australia. Despite their economic importance, models of CID genesis are the subject of debate due to a paucity of geochronological data that could constrain the timing of their formation (MacLeod et al , 1963; Harms and Morgan, 1964; Campana et al , 1964; Butler, 1976; Hall and Kneeshaw, 1990; Morris, Kneeshaw and Ramanaidou, 2007; Stone, 2005; Heim et al , 2006; Morris and Ramanaidou, 2007). Age estimates based on palinological data could not provide a precise age determination and it is currently accepted that f lling of the existing paleochannels could have taken place from Late Eocene to Middle Miocene times (MacPhail and Stone, 2004; Balme in Morris, Ramanaidou and Horwitz, 1993; Morris, 1994; Morris and Ramanaidou, 2007; Morris, Kneeshaw and Ramanaidou, 2007). The only radiometric age constraints were presented by Heim et al (2006) who applied combined (U-Th)/He and 4He/3He methods to date late stage authigenic goethite fromten samples collected from 1. Senior Research Fellow, The University of Waikato, Department of Earth and Oceanic Science, Faculty of Science & Engineering, Private Bag 3105, Hamilton 3240, New Zealand. Email: m.danisik@waikato.ac.nz 2. MAusIMM, Research Stream Leader - Geometallurgy of Carbon Steel Materials, Minerals Down Under Flagship, Commodity Leader for Iron Ore, CSIRO Earth Science and Resource Engineering, ARRC PO Box 1130, Bentley WA 6102. Email: Erick.Ramanaidou@csiro.au 3. Principal Research Scientist, CSIRO Earth Science and Resource Engineering, ARRC PO Box 1130, Bentley WA 6102. Email: Noreen.Evans@csiro.au 4. Technical Offi cer, CSIRO Earth Science and Resource Engineering, ARRC PO Box 1130, Bentley WA 6102. Email: Brad.Mcdonald@csiro.au 5. Technical Offi cer, CSIRO Earth Science and Resource Engineering, ARRC PO Box 1130, Bentley WA 6102. Email: Celia.Mayers@csiro.au 6. Research Professor, Director, John de Laeter Centre for Isotope Research, John de Laeter Centre for Isotope Research, Department of Applied Physics, Curtin University, GPO Box U1987, Perth WA 6845. Email: B.McInnes@curtin.edu.au (U-Th)/He Geochronology of Channel Iron Deposits, Robe River, Hamersley Province, Australia – Implications for Ore Genesis M Danišík1, E R Ramanaidou2, N J Evans3, B J McDonald4, C Mayers5 and B I A McInnes6 ABSTRACT Two drill core samples of haematite/goethite from the Robe River (Western Australia) channel iron ore deposits (CID) were dated using (U-Th)/He methods in order to constrain the timing of iron oxide formation and thereby provide a temporal context for CID genesis. (U-Th)/He ages (He ages) from these samples range from the late Oligocene to Late Miocene and despite a high degree of scatter, they corroborate relationships expected from the internal ooidal stratigraphy: For individual ooids, the ages from haematitic core are older than or indistinguishable from the ages of the surrounding goethitic cortex. The goethitic cortices are, in turn, older than the ferruginised wood fragments recovered from the cementing goethitic matrix. The data suggest the following succession of ore formation phases: Haematitic cores in ooids of both samples formed in the Early to Middle Miocene. Goethitic cortices of both samples formed in the late Middle to early Late Miocene. This appears to be the age of goethite cortex formation regardless of depth in the core, which does not support the top-down inf ll model, genetic model proposed by Heim et al (2006). Wood fragments form a prominent component of the matrix and were ferruginised during the Late Miocene. Thus the data suggest that the unique environmental conditions for the CID formation existed during the Miocene. A methodological implication of this study is that the temperature utilised for He-extraction from iron oxides has a critical impact on the mobility of parent nuclides. The typical ~1100°C laser heating used for crystalline minerals like apatite or zircon induces loss of U and Th and results in erroneously old ages. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 M DANIŠÍK et al 84 a vertical section through the Yandi CID in the Hamersley Province (Western Australia). These authors found that the He ages were all Miocene and progressively decreased with depth, suggesting that precipitation of goethite cement was controlled by water table drawdown during the Neogene (Heim et al , 2006). However, despite having reported ages consistent with the generally accepted Neogene formation age of the CID, the model of Heim et al (2006) was challenged by Morris, Kneeshaw and Ramanaidou (2007), who questioned the sampling strategy and statistical treatment of the data (for details see Morris, Kneeshaw and Ramanaidou, 2007 and reply by Vasconcelos et al, 2007). Here we aim to derive new age constraints on the formation of CID in the Hamersley Province and re-evaluate the existing genetic models in the light of the new data. SAMPLES AND METHODS Two CID samples (G-82 and G-328) were collected from a diamond drill core (J1136 generously made available to CSIRO by Robe River Mining) located at Mesa J in the Robe River Valley from vertical depths of 8.2 and 32.8 m below the present surface, respectively (Figure 1). Polished thin sections of the samples of the samples were prepared for vital petrological work underpinning the dating analysis. Textural and in situ chemical analyses were respectively completed with optical and scanning electron microscopes equipped with an EDS system. For (U-Th)/He dating, the samples were coarsely crushed to isolate intact ooids, haematitic core and goethite cortex shards, and ferruginised wood fragments from the matrix; these were then handpicked under a binocular microscope and ultrasonically cleaned. The samples were then analysed for 4He, 238U and 232Th using isotope-dilution mass spectrometry (quadrupole and ICP-MS, respectively) at the John de Laeter Centre for Isotope Research in Perth (Australia) following the procedures described in Danišík et al (submitted). The total analytical uncertainty (TAU) was calculated as a square root of sum of squares of weighted uncertainties on U, Th, and He measurements. TAU was typically less than ~6 per cent (1 sigma) and was used to calculate the uncertainty of He ages. Given the large size and polycrystalline character of dated samples, (U-Th)/He ages were not corrected for alpha ejection (Farley, Wolf and Silver, 1996). The ages were not corrected for diffusive loss (Shuster et al , 2005) that might result to a slight underestimation of true age. RESULTS Sample characterisation: microscopy The petrological study of the two samples revealed textures typical of a granular CID as de f ned by Ramanaidou, Morris and Horwitz (2003). The samples depict an ooidal-dominated texture with haematitic nuclei surrounded by a goethitic cortex and cemented by a goethitic matrix containing wood fragments (Figure 1). Under re f ected light, the ooids (0.25 - 2 mm) haematitic nuclei can be either simple or complex; cracks are widespread and the internal texture shows compact white or more porous haematite, some nuclei contain haematitised wood fragments (Figure 2). The combination of ref ected and transmitted light (Figure 3) highlights the three major components: 1. dark red nuclei in transmitted light, 2. yellow cortices, and 3. matrix goethite appearing grey in ref ected light. FIG 1 - (A) Ooidal texture of a sample from the investigated J1136 drill core in Mesa J where three typical components are visible: haematitic core (1), goethitic cortex (2) and matrix (3); (B) ferruginised wood in the matrix; (C) SEM image of the wood with a typical porous structure; (D) SEM results with major element contents. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 (U-TH)/HE GEOCHRONOLOGY OF CHANNEL IRON DEPOSITS, ROBE RIVER, HAMERSLEY PROVINCE, AUSTRALIA 85 The matrix contains goethitised wood fragments (Figures 1 to 3). (U-Th)/He results Our preliminary (U-Th)/He data suggest the following four relationships: 1. The He ages of the cores are older than those of the corresponding cortices, which is in agreement with their internal stratigraphy. 2. The wood fragment from the matrix of the deeper sample (G-328) yielded Late Miocene ages, clearly younger than He ages of the cores and cortices from that sample. The Late Miocene ages of wood from the matrix of the shallower core are also consistently younger than the cores and cortices from this depth. This age relationship corroborates internal stratigraphic relationships, where the matrix should be the last phase of the CID to form. 3. There is a difference between the samples in terms of the He ages of ooid cores. Core He ages of the shallower sample G-82 are Middle Miocene, younger than Early Miocene He ages yielded by the deeper sample G-328. 4. He ages of cortices from both samples are indistinguishable,clustering at Middle/Late Miocene boundary. INTERPRETATION AND PRELIMINARY CONCLUSIONS Assuming the He ages represent the time of mineral formation, our He dating results suggest the following succession of ore forming processes: formation of ooid cores of the deeper sample (G-328) in the Early Miocene, formation of ooid cores of the shallower sample (G-82) in the Middle Miocene, FIG 2 - Microphotograph in refl ected light of sample G - 82 portraying the ooidal texture, the haematitic nuclei with some wood fragments (W - Hm), the goethite cortices (Co - Go) and matrix (Ma - Go) with goethitised wood fragment (W - Go). FIG 3 - Microphotograph in refl ected light and transmitted light of a selected area of sample G – 82 showing the white and reddish haematite nuclei in refl ected light and the dark reddish colour in transmitted light. The goethitic cortex and matrix are also highlighted. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 M DANIŠÍK et al 86 formation of goethitic cortex that coated already existing ooids of both samples at Middle/Late Miocene boundary, and ferruginisation of the wood fragments in the Late Miocene. The ages of the cores imply that the dated ooids formed in the Early to Middle Miocene. The inverse age-depth relationship between the samples may suggest that the ooids represent components derived either from two sources of different age or from the same regolith pro f le which became inverted during the erosion, transport and re-sedimentation. The deeper (older He ages) and shallower (younger He ages) ooids thus represent the older, near-surface and younger, deeper regolith levels, respectively. The formation of the goethitic cortex in the late Middle to early Late Miocene, in contrast, appears to be a fast process lasting maximally a few million years as inferred from indistinguishable He ages. Despite the fact that the timing seems to be well constrained by the He data, the location of goethitic cortices formation is somewhat arguable. Whereas Morris and Ramanaidou (2007) favoured formation of the goethitic cortices during the colluvium stage, before accumulation of the ooids in the river channels, Heim et al (2006) proposed that the goethitic cortex formed after the channel aggradation had cemented the cores. Heim et al (2006) also found a downward younging trend in He ages measured over a ~30 m deep discontinuous pro f le. These authors argued that the process of iron cementation occurred at the groundwater-atmosphere interface and was driven by water table drawdown during the Neogene. Although we cannot discern from our data which model is correct, we can say that our data do not support the interpretation of Heim et al (2006). The two cortex samples, with a vertical separation of 23 metres, collected in the same borehole do not show any variation in He age. Therefore, the top-down in f ll model driven by water table drawdown cannot apply to the locality investigated in this study. The last process recorded by He data is the ferruginisation of wood fragments, in which the organic wood tissues were replaced by mobilised ferrous iron. Although the mechanism of this process is not well understood (Morris, Ramanaidou and Horwitz, 1993; Morris and Ramanaidou, 2007; Morris, Kneeshaw and Ramanaidou, 2007), it most likely occurred in the Late Miocene to Early Pliocene, provided the ages record the time of goethite/haematite replacement. This result clearly shows that river aggradation must have been completed in the Late Miocene. Our data f t well the Miocene climatic optimum for the CID formation proposed by Morris and Ramanaidou (2007). ACKNOWLEDGEMENTS We thank Michael Verrall for help with the SEM, C Scadding and A Thomas for assistance with ICP-MS, and Richard Morris for constructive suggestions on the CID genesis. This project was funded by the Minerals Down Under Flagship, CSIRO. MD received f nancial support from the WA Geothermal Centre of Excellence. REFERENCES Butler, R J T, 1976. Geology of the Tertiary ironstones in the middle and upper Robe River area, Pilbara Region, Western Australia, MSc thesis (unpublished), University of Western Australia, Perth. Campana, B, Hughes, F E, Burns, W G, Whitcher, I G and Muceniekas, E, 1964. Discovery of the Hamersley iron deposits (Duck Creek-Mt. Pyrton-Mt. Turner Area), The AusIMM Proceedings, 210:1-30. Danišík, M, Ramanaidou, E R, Evans, N J, McDonald, B J, Mayers, C and McInnes, B I A, submitted. (U-Th)/He geochronology of channel iron deposits, Hamersley Province, Western Australia: Implications for ore genesis and landscape evolution, Submitted to Chemical Geology. Farley, K A, Wolf, R A and Silver, L T, 1996. The effects of long alpha- stopping distances on (U-Th)/He ages, Geochim Cosmochim Acta, 60:4223-4229. Hall, G C and Kneeshaw, M, 1990. Yandicoogina-Marillana pisolitic iron deposits, in Geology of the Mineral Deposits of Australia and Papua New Guinea (ed: F E Hughes), pp 1581-1586 (The Australasian Institute of Mining and Metallurgy: Melbourne). Harms, J E and Morgan, B D, 1964. Pisolitic limonite deposits in northwest Australia, The AusIMM Proceedings, 212:91-124. Heim, J A, Vasconcelos, P M, Shuster, D L, Farley, K A and Broadbent, G C, 2006. Dating palaeochannel iron ore by (U-Th)/He analysis of supergene goethite, Hamersley Province, Australia, Geology, 34/3: 173-176. MacLeod, W N, de la Hunty, L E, Jones, W R and Halligan, R, 1963. A preliminary report on the Hamersley Iron Province, North- West Division, Geological Survey of Western Australia, Annual Report for 1962, pp 44-54. MacPhail, M K and Stone, M S, 2004. Age and palaeoenvironmental constraints on the genesis of the Yandi channel iron deposits, Marillana Formation, Pilbara, northwestern Australia, Australian Journal of Earth Sciences, 51:497-520. Morris, R C, 1994. AMIRA Project P75G – Detrital iron deposits of the Hamersley Province, CSIRO Exploration and Mining Restricted Report 76R. Morris, R C, Kneeshaw, M and Ramanaidou, E R, 2007. Dating paleochannel iron ore by (U-Th)/He analysis of supergene goethite, Hamersley province, Australia: Comment, Geological Society of America, e118. Morris, R C and Ramanaidou, E R 2007. Genesis of the channel iron deposits (CID) of the Pilbara region, Western Australia, Australian Journal of Earth Sciences, 54/5:733-756. Morris, R C, Ramanaidou, E R and Horwitz, R C, 1993. Channel iron deposits of the Hamersley Province, CSIRO Australia, Exploration and Mining Report 399R. Ramanaidou, E R, Morris, R C and Horwitz, R C, 2003. Channel iron deposits of the Hamersley Province, Western Australia, Australian Journal of Earth Sciences, 50:669–690. Shuster, D L, Vasconcelos, P M, Heim, J A and Farley, K A, 2005. Weathering geochronology by (U-Th)/He dating of goethite, Geochim Cosmochim Acta, 69:659-673. Stone, M S, 2005. Depositional history and mineralisation of Tertiary iron deposits at Yandi, Eastern Pilbara, Australia, PhD thesis (unpublished), University of Western Australia, Perth. Vasconcelos, P M, Heim, J A, Farley, K A, Shuster, D L and Broadbent, G, 2007. Dating paleochannel iron ore by (U-Th)/He analysis of supergene goethite, Hamersley province, Australia: Reply, Geological Society of America, e118. 87IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 INTRODUCTION Large, high-grade (>55 wt per cent Fe) iron ore deposits in the Hamersley Province and Yilgarn Craton of Western Australia are commonly the combined product of several distinct types of Fe ore. For example, the Mt. Tom Price deposit in the Hamersley Province hosts goethite-haematite ore overlying magnetite ± haematite ore (Taylor et al , 2001), whereas Fe deposits in the Koolyanobbing Fe camp, Yilgarn Craton, contain a combination of goethite-, haematite-, and magnetite-rich ores (Angerer and Hagemann, 2010). Each ore type has distinct physical and chemical characteristics, suchas ore and gangue mineralogy, grain size, Fe grade, and contaminant elemental suites, which together causes substantial heterogeneity within a single deposit and inf uences benef ciation processes and exploration strategies. For these reasons, it is vital to understand the key relationships between different Fe ore types. The Weld Range greenstone belt, in the Murchison Domain of the Yilgarn Craton, hosts two Archean, high-grade Fe deposits, Madoonga (68 Mt resource at 57.7 wt per cent Fe) and Beebyn (62 Mt resource at 59.6 wt per cent Fe, ASX announcement 2008). These deposits contain up to f ve different types of Fe ore that are heterogeneously distributed in the deposits, but are important contributors to the overall resource estimate for the deposits. This paper summarises the geological setting of the Weld Range greenstone belt before documenting the location, properties, and relative timing of the f ve types of Fe ore. These results are then discussed in terms of their implications for exploration within the Weld Range greenstone belt. GEOLOGICAL SETTING OF THE WELD RANGE GREENSTONE BELT The Weld Range greenstone belt is located in the Murchison Domain of the Youanmi Terrane, Yilgarn Craton, Western Australia. The oldest supracrustal rocks exposed in the 1. Assistant Professor, Centre for Exploration Targeting, The University of Western Australia, Crawley WA 6009. Email: paul.duuring@uwa.edu.au 2. Professor, Centre for Exploration Targeting, The University of Western Australia, Crawley WA 6009. Email: steff en.hagemann@uwa.edu.au Contrasting Styles of High-Grade Iron Mineralisation at Weld Range, Western Australia P Duuring1 and S G Hagemann2 ABSTRACT Late-Archean banded iron formation (BIF)-hosted deposits in the Yilgarn Craton of Western Australia are less well understood compared to the larger Paleoproterozoic, Superior-type BIF- hosted deposits of the Hamersley Province. The Weld Range greenstone belt, in the Murchison Domain of the Yilgarn Craton, hosts two Archean, high-grade deposits, Madoonga (68 Mt resource at 57.7 wt per cent Fe) and Beebyn (62 Mt resource at 59.6 wt per cent Fe, ASX announcement 2008). Five main types of high-grade (>55 wt per cent Fe) iron mineralisation at Weld Range each display characteristic grades, tonnage, and contaminant levels, which affect exploration strategies and benef ciation methods: 1. ‘Residual’ ore formed as a result of two generations of hypogene alteration of BIF. The f rst alteration phase replaced silica-rich bands with siderite and/or Fe-rich dolomite; the second phase involved the removal of carbonate gangue minerals and the concentration of residual Fe oxide-rich bands in the BIF via volume reduction. The product is a high-grade, high-tonnage Fe orebody, with minor contaminants. 2. Magnetite-bearing shear and fault zones cut BIF along lithological contacts. These zones of secondary magnetite formed as a result of the addition of hypogene magnetite via the circulation of Fe-rich, hypogene hydrothermal f uids through BIF. This type of mineralisation produces narrow (low-tonnage), high-grade magnetite-rich ore zones with high levels of contaminants (eg SiO2, Al2O3) due to the diff culty in mining these zones. 3. Specular haematite ± quartz-bearing shear and fault zones cut residual orebodies and magnetite- bearing structures. They share similar characteristics to magnetite-bearing structures. 4. Goethite-haematite supergene ore zones are controlled by brittle faults that cut BIF. These faults promoted the f ow of supergene f uids through BIF and resulted in large ore zones with variable Fe grades and contaminants. 5. Detrital deposits comprise transported BIF fragments and are intensely goethite-haematite supergene-altered. These orebodies are locally extensive, with moderate Fe grades. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 P DUURING AND S G HAGEMANN 88 Weld Range greenstone belt include steeply S-dipping, S-facing komatiite, komatiitic basalt, and tholeiitic basalt that together represent part of the 2800 to 2730 Ma Polelle Group (stratigraphic associations def ned by Van Kranendonk and Ivanic, 2009). These komatiite f ows are overlain by andesitic to rhyolitic volcanic and volcaniclastic rocks of the Greensleeves Formation, which are in turn overlain by BIF, tuffaceous siltstones, and felsic rocks of the Wilgie Mia Formation that are intruded by dolerite to gabbro sills. The Wilgie Mia Formation coincides with a 3 - 5 km-wide, ~70 km-long, series of parallel ridges that trend mainly ENE but curves to a more northerly trend in eastern areas of the district. The Madoonga and Beebyn Fe deposits are hosted by discrete BIF sequences within the formation (Figure 1). Farther south, younger felsic volcanic and volcaniclastic rocks are overlain by pelite and psammite of the Ryansville Formation, which are intruded by gabbronorite, gabbro, and dolerite of the Yalgowra Suite (Ivanic, 2009). Supracrustal rocks in the Weld Range greenstone belt are metamorphosed to upper-greenschist to lower-amphibolite facies (300 ± 50°C) at pressures of <2 - 3 kbars (Gole, 1980). District-scale structures in the belt include ENE-trending, isoclinal, f rst-generation (F1) folds that have an axial planar foliation oriented subparallel to bedding in supracrustal rocks (Spaggiari, 2006) (Figure 1). The folding of bedding contacts and a bedding-parallel foliation (axial planar to F 1 folds) in rocks of the Ryansville Formation (Ivanic, 2009) de f ne a moderately SW-plunging F 2 syncline located to the south of the main series of ENE-trending ridges (Figure 1). The NNE-trending Carbar fault (Spaggiari, 2006) truncates the northwestern limb of the regional F2 syncline. METHODOLOGY Detailed lithological, structural, and alteration outcrop mapping were performed at a 1:2000 scale over the individual ~8 km-strike lengths of the Beebyn and Madoonga deposits. At each deposit locality, outcrop is contained within <150 m-wide, <100 m-high, ENE-trending ridges. Core from 12 diamond drill holes that cover the respective strike lengths of each deposit was studied with emphasis placed on the relationship between unweathered rock types, structures, hydrothermal alteration, and iron mineralisation. The holes were mostly drilled from surface to the NNW at moderate to steep angles. Examples of least-altered/weathered rocks were collected in conjunction with their more altered and weathered variants for the purpose of thin-section, carbonate-staining, geochemical, and spectral (analytical spectral device) studies. GEOLOGICAL OVERVIEW OF THE BEEBYN AND MADOONGA DEPOSITS Beebyn deposit The Beebyn deposit stratigraphy trends ENE, is steeply SSE-dipping, and includes BIF, basalt, dolerite, and gabbro, with minor chloritic shale or siltstone interbedded with the BIF. Three main, <80 thick, BIF units (informally labelled the ‘North’, ‘Central’, and ‘South’ BIF) in the deposit are FIG 1 - Solid geology map and cross-section for the Weld Range study area. Volcanic, volcano-sedimentary, and sedimentary rocks defi ne a regional, moderately SW-plunging syncline, with the Weld Range area defi ning the northeast limb (modifi ed after Van Kranendonk and Ivanic, 2009). Note the location of the Beebyn and Madoonga Fe deposits. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 CONTRASTING STYLES OF HIGH-GRADE IRON MINERALISATION AT WELD RANGE, WESTERN AUSTRALIA 89 bounded by ma f c volcanic rocks (Figure 2a). All major lithological contacts between BIF and maf c volcanic rocks are deformed. Only narrow (<3 m-thick) basalt or dolerite sills in the North BIF preserve their intrusive contacts. Chloritic shale or siltstones are minor constituents of the North and Central BIF. Stratigraphic younging directions are not clearly preserved in any rock types at Beebyn. The North BIF is the thickest BIF and hosts the widest zones of high-grade iron mineralisation.These zones are most commonly located along the stratigraphic footwall contact of the North BIF. The depth of weathering varies over the strike length of the Beebyn deposit, averaging about 120 m below the present surface, but extending to considerably greater depths (~200 m) along lithological contacts or within steeply-dipping fault zones. Least-altered BIF mostly comprises equal proportions of 0.5 - 3 cm-thick, alternating bands of quartz and Fe oxide minerals (Figure 3a). Five main deformation events are preserved at Beebyn. The f rst deformation event (D 1) involved E-W shortening and resulted in the formation of isoclinal, recumbent F 1 folds that presently have axial planes oriented subparallel to the ENE- trending, multiply-folded stratigraphy. F 1 fold axes observed within the BIF have variable plunge directions, however, they mainly plunge moderate to steeply to the NE. Reverse shear zones or faults occur along folded limbs and locally displace fold hinges. The second deformation event (D 2) coincided with N-S shortening and caused the refolding of F 1 folds. These F 2 folds are tight, upright, ENE-trending, and mainly plunge shallow to moderately to the WSW. Rare centimetre- scale examples of refolded F 1 folds are exposed in the North BIF. Asymmetric, Z-shaped parasitic F 2 folds (in plan) are commonly def ned by mesobands in BIF and correspond with asymmetric, north-limb-down F2 folds in cross-section. These parasitic fold relationships are consistent with the existence of a district-scale, synclinal fold hinge to the south of the broadly S-facing Beebyn deposit stratigraphy (perhaps corresponding with the synclinal fold hinge within the Ryansville Formation mapped to the south of the Weld Range by Ivanic, 2009). A third deformation event (D 3) involving E-W shortening resulted in re-folding of the stratigraphy and the formation of F 3 folds in BIF. These folds are open to tight, trend N-S, and plunge steeply to the N or S. The F 3 folds contribute to the large variation in the orientation of F 1 and F 2 fold hinges at Beebyn. Subsequent deformation at Beebyn (D 4 and D 5) corresponds with the transition from ductile to brittle styles of deformation. North-south shortening during D 4 resulted in NNW- to NNE-trending, subvertical, brittle faults that cut the folded Beebyn stratigraphy. These faults commonly host extensional quartz veins and are spatially associated with zones of intense goethite-weathering of BIF horizons. Displacement indicators are rare, but where they exist they indicate mostly dextral displacements of up to 20 m. Based on the interpretation of aeromagnetic data, it is possible that dextral fault displacements may be even greater (<400 m). A resumption of E-W shortening during D 5 resulted in the centimetre-scale, dextral displacement of N-trending faults and extensional quartz veins by ENE-trending, bedding- parallel, brittle faults. Madoonga deposit The Madoonga deposit stratigraphy strikes ENE and dips steeply SE. From oldest to youngest, the SE-facing sequence includes rhyolite, dolerite, and gabbro overlain by a <60 m-thick BIF (hereafter referred to as the ‘North BIF’), a volcaniclastic or (volcanogenic)-sedimentary rock, a <150 m-thick southern BIF (ie ‘South BIF’), pyritic mudstone, and dolerite/gabbro. These steeply dipping rocks are unconformably overlain by a f at-lying, poorly-sorted, BIF clast-rich breccia along the southern margin of the main ridge at Madoonga (Figure 2b). All major lithological contacts between BIF and surrounding rocks are deformed. The limit of supergene alteration extends to vertical depths of up to 300 m below surface in some areas of the deposit. Deformation events interpreted for the Madoonga deposit are comparable to those described for the Beebyn deposit. Isoclinal, f rst-generation (F1) folds are rare at Madoonga, whereas magnetite-bearing shear zones are commonly located along the margins of the North and South BIF. Locally, the shear zones anastomose and transgress banding in the BIF as well as lithological contacts at an acute angle, clockwise to contacts. Magnetite-bearing shear zones, bands, and lithological contacts are folded in response to N-S shortening during the regional D2 event. These F2 folds are tight, upright and mainly plunge moderately (40° to 60°) to the W. The folds have asymmetric, S- or Z-shaped geometries in plan view, and south- or north-side-down geometries in cross-section. Specular haematite ± quartz veins cut banding in BIF at acute angles and are folded by a third generation of folds (F3). East- west shortening resulted in N-trending, open, low-amplitude, F3 folds that warp the previously folded tectono-stratigraphy. FIG 2 - Representative cross-sections for the (A) Beebyn; and (B) Madoonga deposits; showing the relationships between rock types and ore zones. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 P DUURING AND S G HAGEMANN 90 The F3 folds are cut by NNW- to NNE-trending, subvertical, conjugate faults and quartz veins (D 4). East-trending, brittle faults occur along major stratigraphic contacts and result in the disruption of folds and the reactivation of existing, bedding-parallel structures (D5). CONTRASTING STYLES OF HIGH-GRADE IRON ORE AT WELD RANGE Hypogene ‘residual’ magnetite-martite ore The type locality for this style of mineralisation is the Beebyn deposit, where magnetite-martite-rich ore occurs beneath the base of supergene weathering to vertical depths of at least 250 m in the North and Central BIF units (Figure 2a). The ore zones are preferentially located along the sheared footwall contact of the North BIF, but may also occur at various stratigraphic positions within the BIF. In the centre of the Beebyn deposit, high-grade magnetite-martite ore zones are <50 m-thick and extend continuously for about 500 m along strike. In more distal areas, the ore zones are narrower (<15 m-thick), shorter (<50 m-long), and are sporadically distributed up to one kilometre from the main magnetite- martite orebody. The ore zones are genetically associated with banding-parallel shear zones that are folded by F 2 folds. In hand specimen, high-grade magnetite-martite ore is black, thinly-banded (<3 mm-thick), and comprises >70 volume percent Fe oxide bands (Figure 3b). Locally, the rock displays brecciation of Fe oxide-rich bands and the centimetre-scale crenulation of bands. In thin-section, primary Fe oxide bands comprising subhedral magnetite are rimmed by secondary, euhedral magnetite. Minor (<30 vol per cent) gangue minerals include f ne-grained primary quartz and coarse-grained, hypogene siderite and ferroan dolomite. Relative to least- altered BIF, magnetite-martite ore is enriched in Fe and P, and depleted in SiO2. The product is a high-grade (>55 per cent Fe), high-tonnage orebody, with minor contaminants. An outer alteration halo of hypogene siderite and ferroan dolomite surrounds the magnetite-martite ore. A two-stage, hypogene hydrothermal alteration process is interpreted for the genesis of the ‘residual’ magnetite-martite ore type. The f rst stage of hydrothermal alteration involved the replacement of existing silica-rich bands in least-altered BIF by hypogene siderite and ferroan dolomite, with minor addition of hypogene magnetite. The product is a BIF that has retained its primary texture and iron content, but has experienced substitution of quartz with carbonate gangue FIG 3 - Photoplate displaying examples of the least-altered banded iron formation and main ore types at Weld Range; (A) least-altered banded iron formation, (B) hypogene ‘residual’ magnetite-martite ore with minor preservation of earlier ferroan dolomite alteration, (C) hypogene magnetite-rich vein with fragments of magnetite-altered, banded iron formation wall rock, (D) crystalline specular haematite intergrown with quartz in a vein cutting banded iron formation,(E) supergene goethite-haematite alteration replacing the primary and hypogene minerals and textures in banded iron formation; and (F) detrital ore containing banded iron formation fragments cemented by goethite. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 CONTRASTING STYLES OF HIGH-GRADE IRON MINERALISATION AT WELD RANGE, WESTERN AUSTRALIA 91 minerals (Figure 3b). This rock has lower silica abundance than least-altered BIF, but has about the same concentration of Fe. This Stage 1 hypogene alteration style is preserved in the outer halo surrounding high-grade magnetite-martite ore at Beebyn. Although the Fe content of this carbonate- altered BIF has not changed signi f cantly, the replacement of quartz bands by carbonate minerals aids benef ciation. Hence, this type of altered BIF is considered to be low-grade (40 to 55 wt per cent Fe) ore at Weld Range. The reactivation of shear zones along the footwall contact of the North BIF at Beebyn encouraged the repeated focusing of hydrothermal f uids along the contact, resulting in the (partial) replacement of Stage 1 alteration minerals by Stage 2 alteration minerals to form magnetite-martite ore. The timing of this ore-forming event is pre-D2. Fault or shear zone-hosted, hypogene magnetite-martite ore Magnetite-martite veins associated with faults or shear zones cut BIF at the Madoonga and Beebyn deposits. At Madoonga, <3 m-thick, brittle-ductile shear zones are located along major lithological contacts, including footwall and hanging wall margins of the North and South BIF units. These magnetite- martite-rich shear zones are oriented subparallel to banding, apart from in dilational jogs, where subsidiary shear zones are oriented up to 30° clockwise from the main ENE-trending, en echelon shear zones. Within the jogs, magnetite-martite veins de f ne a network amongst magnetite-martite-altered BIF, which is now largely oxidised to haematite (Figure 3c). Magnetite-martite veins, faults, and shear zones are locally folded by F 2 folds and thus predate the D 2 event. At the Beebyn deposit, <1 m-thick, mylonite zones are located along the footwall contact of the North BIF. The mylonites contain hypogene magnetite enveloped by zones with f attened and rotated clasts of BIF wall rock. No cross-cutting relationships were observed between magnetite-martite veins and the hypogene ‘residual’ magnetite-martite ore at Beebyn, although both are folded by F2 folds. Magnetite-martite ore associated with veins, faults, and shear zones indicate the addition of Fe to least-altered BIF, without signi f cant removal of silica-rich bands from BIF. Consequently, high-grade ore zones are narrow and have the potential to be contaminated by SiO 2 from nearby BIF-wall rock. The thickest ore zones coincide with dilational jogs and splays to the ENE-trending shear and fault zones. Hypogene specular haematite ore Specular haematite ± quartz veins cut least-altered BIF, hypogene ‘residual’ magnetite-martite ore zones, and fault or shear zone-hosted hypogene magnetite-martite ore zones at Madoonga and Beebyn. The thickest specular haematite ± quartz veins are at Madoonga, where they are 10 - 20 m thick and coincide with dilational jog zones to ENE-trending, fault-hosted veins. The proportion of haematite relative to quartz varies in the veins. At one locality at Madoonga, the proportion of quartz in veins increases with distance from a dominant specular haematite vein. In hand specimen examples, randomly oriented specular haematite crystals are <4 cm long, euhedral and intergrown with crystalline quartz (Figure 3d). At the Beebyn deposit, randomly-oriented, euhedral specular haematite crystals are concentrated in the hinges of asymmetric F 2 folds. These cigar-shaped lenses strike ENE and plunge moderately to the WSW, that is, in the same plunge direction as F 2 folds. The limbs of the folds and specular haematite veins are refolded by F 3 folds. Elsewhere at Beebyn, specular haematite and chlorite- f lled shear zones oriented at a shallow angel to banding cut hypogene ‘residual’ magnetite-martite ore. Structural relationships indicate that the specular haematite ore formation event took place syn- to post-F2 folding, but before F3 folding. Hypogene specular haematite ore zones have similar characteristics to the magnetite-martite veins in that they formed by the addition of Fe to BIF. Specular haematite high- grade zones are narrow, with variable SiO 2 contamination due to the presence of coeval hypogene quartz and the incorporation of silica-rich, BIF wall rock in the vein. Locally, ore zones are thicker where they coincide with dilational jogs associated with ENE-trending faults. Supergene goethite-haematite ore Goethite-haematite ore is best developed at the Madoonga deposit where it is 400 m long × 150 m wide, and extends to depths of about 300 m (Figure 2b). The ore is structurally controlled in that it coincides with the intersection between the sheared hanging wall contact of the South BIF and later, cross-cutting NNW- to NNE-trending, subvertical brittle faults. Within these highly deformed areas, least-altered BIF and earlier hypogene magnetite-martite veins are replaced by strong goethite-haematite alteration, which destroys existing bands in the BIF and results in a cavity-rich, mottled texture (Figure 3e). Compared with least-altered BIF, the goethite- haematite-rich ore is enriched in Fe and P, with depletion in SiO2. Elsewhere at Weld Range, goethite-haematite-altered BIF shows similar genetic associations with NNW- to NNE- trending, subvertical faults, but without the same magnitude of alteration. These subvertical faults cut F 3 folds and offset the ENE-trending strata with dextral displacements of up to 200 m. Goethite-haematite ore zones are interpreted to be the product of supergene alteration, whereby near-surface oxidised f uids circulated down and along NNW- to NNE- trending, subvertical brittle faults during the D 4 event. The supergene f uids removed SiO2 from the BIF via leaching of silica-rich bands, resulting in the consolidation of Fe oxide- rich bands and an upgrade in Fe. The intensity and magnitude of supergene enrichment of BIF is primarily controlled by f uid permeability through the BIF via the late faults. The signif cance of existing hypogene magnetite-martite veins as contributors to the size and quality of the goethite-haematite ore is probably minor due to their narrow widths. Detrital accumulation of goethite-haematite ore Accumulations of goethite-haematite-rich detrital sediments occur along the southern side of the main ENE-trending ridge at the Madoonga deposit (Figure 2b). These poorly- consolidated concentrations contain large fragments of least-altered and hypogene-altered BIF that are cemented by supergene goethite and haematite (Figure 3f). The concentrations extend for about 3 km in strike, are <200 m wide, and <100 m deep. The detrital ore zones vary in grade and width considerably along strike and with depth. Detrital accumulations of goethite-haematite ore formed as a result of the erosion and transport of Fe-enriched BIF exposed along the ridge at Madoonga. These fragments were transported short distances due to gravity and f uvial processes, and were deposited in palaeotopographic depressions adjacent to the ridge. Once accumulated, the poorly-sorted fragments were then partly cemented by goethite and haematite during the circulation of supergene f uids. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 201192 P DUURING AND S G HAGEMANN IMPLICATIONS FOR EXPLORATION The most economically signif cant ore types in the Weld Range greenstone belt are hypogene ‘residual’ magnetite-martite ore (ie at the Beebyn deposit) and supergene goethite-haematite ore (Madoonga deposit). These two ore types are responsible for stand-alone orebodies that have low contamination from SiO 2, Al 2O3, or P. Thesmall Fe prospects in the belt generally host narrow, hypogene magnetite veins or specular haematite veins, whereas comparatively larger Fe prospects have coincident ore zones. For example, specular haematite ore zones are locally cut by N-trending faults near Madoonga, resulting in the supergene modif cation of hypogene ore zones. Each ore type has a speci f c physical and chemical characteristic (eg Fe grade, contaminants, magnetism, density), relative timing with respect to regional deformation events, and controls for ore formation. These differences have direct implications for exploration, such as when interpreting geophysical anomalies in BIF (ie in the recognition of magnetic/dense magnetite-rich ore versus less-magnetic/ less dense supergene goethite-haematite ore), or during the identif cation of important structures in the belt (ie mylonite zones verses NNW- to NNE-trending brittle faults). The early identif cation of ore type from a newly identi f ed prospect helps to anticipate the likely Fe ore quality, orebody size, and controls on ore formation for the occurrence. The ranking of exploration targets based on their ore type is an effective strategy for reducing the number of potential targets in a district and for focusing exploration activities. CONCLUSIONS The Weld Range greenstone belt hosts f ve main types of high-grade (>55 wt per cent Fe) mineralisation. Each ore type displays key differences in physical and chemical characteristics, such as Fe grade, tonnage, and contaminant levels. In order of formation: 1. Hypogene ‘residual’ magnetite-martite ore formed as a result of two generations of hypogene alteration of BIF. The f rst alteration phase replaced silica-rich bands with siderite and/or Fe-rich dolomite; the second phase involved the removal of carbonate gangue minerals and the concentration of residual Fe oxide-rich bands in the BIF via volume reduction. The product is a high-grade, high-tonnage Fe orebody, with minor contaminants of SiO2, Al2O3, and P. 2. Magnetite-martite veins and associated faults or shear zones cut BIF along lithological contacts. These zones of secondary magnetite formed as a result of the addition of hypogene magnetite via the circulation of Fe-rich, hypogene hydrothermal f uids through BIF. This type of mineralisation produces narrow (low-tonnage), high- grade magnetite-rich ore zones with high levels of contaminants due to the diff culty in mining these zones. 3. Hypogene specular haematite±quartz veins cut residual orebodies and magnetite-bearing structures. They share similar characteristics to magnetite-bearing structures. 4. Supergene goethite-haematite ore zones are controlled by brittle faults that cut BIF. These faults promoted the f ow of supergene f uids through BIF and resulted in large ore zones with variable Fe grades and contaminants. 5. Detrital deposits comprise transported BIF fragments and are intensely goethite-haematite supergene-altered. These orebodies are locally extensive, with moderate Fe grades. The contrasting properties of the f ve ore types have direct relevance to exploration strategies in the belt and impacts on benef ciation methods for the ore. The ranking of exploration targets based on their ore type is an effective strategy for reducing the number of potential targets in a district and for consolidating exploration activities. ACKNOWLEDGEMENTS This study is f nancially supported by Sinosteel Midwest Corporation. Weld Range geologists and f eld assistants are gratefully acknowledged for their generous f eld support. REFERENCES Angerer, T and Hagemann, S G, 2010. The BIF-hosted high-grade iron ore deposits in the Archean Koolyanobbing greenstone belt, Western Australia: Structural control on synorogenic- and weathering-related magnetite-, hematite-, and goethite-rich iron ore, Economic Geology, 105:917-945. Gole, M J, 1980. Mineralogy and petrology of very-low-metamorphic grade Archaean banded iron-formations, Weld Range, Western Australia, American Mineralogist, 65:1-2. Ivanic, T, 2009. Madoonga, WA Sheet 2444 - 1:100 000 Geological Series, Geological Survey of Western Australia. Spaggiari, C V, 2006. Interpreted bedrock geology of the northern Murchison Domain, Youanmi Terrane, Yilgarn Craton, Western Australian Geological Survey, Record 2006/10. Taylor, D, Dalstra, H J, Harding, A E, Broadbent, G C and Barley, M E, 2001. Genesis of high-grade hematite orebodies of the Hamersley Province, Western Australia, Economic Geology , 96:837-873. Van Kranendonk, M J and Ivanic, T J, 2009. A new lithostratigraphic scheme for the northeastern Murchison Domain, Yilgarn Craton, Geological Survey of Western Australia, Annual Review 2007-08. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 93 INTRODUCTION The McPhee Creek iron deposit lies 30 km north of the town of Nullagine and 220 km southeast of Port Hedland in the northeastern Pilbara region of Western Australia (Figure 1). The deposit is located adjacent (5 km east) to the Marble Bar road, which links to the Great Northern Highway. The road from Port Hedland to the Nullagine turn-off is sealed while the remainder of the road to the project is unsealed (approximately 60 km). Giralia holds a number of exploration licences in the McPhee Creek area with the McPhee Creek deposits situated 1. MAusIMM, General Manager – Business Development, Gascoyne Resources Ltd, PO Box 1449, West Perth WA 6872. Email: julian@gascoyneresources.com.au 2. MAusIMM, Former Director, Giralia Resources NL, PO Box 1665, West Perth WA 6872. Email: mjoyce@zenithminerals.com.au 3. Project Geologist, Atlas Iron Limited, PO Box 7071, Cloisters Square WA 6850. Email: Paul.Bonato@Atlasiron.com.au 4. Project Geologist, Zenith Minerals Limited, PO Box 1426, West Perth WA 6872. Email: alan@zenithminerals.com.au Discovery and Geology of the McPhee Creek Iron Deposit, Northern Pilbara, Western Australia J D Goldsworthy1, R M Joyce2, P Bonato3 and A D’Hulst4 ABSTRACT The McPhee Creek bedded iron deposit is a recent discovery made by Giralia Resources NL (Giralia) in the northern Pilbara of Western Australia. The deposit lies 30 km north of the town of Nullagine along the southeastern margin of the East Pilbara Granite-Greenstone Terrane (EPGGT). The McPhee Creek area is located in the Kelly Greenstone Belt in the southeastern part of the EPGGT. The Archaean aged greenstone belt consists of volcanic and sedimentary sequences including the Warrawoona Group and the Gorge Creek Group. The McPhee Creek iron ore deposit lies within banded iron formation (BIF) rocks of the Gorge Creek Group. The structure of the McPhee Creek area is dominated by a northeast trending, upright synform (Sandy Creek Syncline) and associated folding that is truncated by northeast trending faults in the east. Iron ore mineralisation is predominantly stratabound and follows the dip of the bedding – however, in some areas, particularly in the southwest of the deposit, mapped steep to moderate dips of bedding planes are at odds with underlying f at mineralised zones in drill sections. Zones within the deposit that contain substantial thickness of iron ore correspond to areas of complex folding suggesting structural control and iron enrichment in fold hinges. Petrographic analyses con f rm mineralisation is goethite dominant and the deposit is strongly supergene enriched. Giralia initially identif ed iron ore potential in the McPhee Creek area through the presence of a small known channel iron deposit (CID) mesa. Giralia began exploration in 2008 by re-drilling a portion of the CID (subsequently named Crescent Moon) and reported a small low-grade Inferred Mineral Resource. Target generation in the wider area utilising Geological Society of Western Australia maps and Ikonos satellite images identif ed strongly ferruginous outcrops associated with major structures along an 8 km long range located 2.5km to the west north-west of the Crescent Moon CID deposit. In late July 2008, a total of 62 rock chip samples were collected during a helicopter supported sampling program conducted at McPhee Creek. Samples taken from haematite-goethite enriched BIF and canga zones outcropping intermittently over the 8 km length of the western and central areas of the prominent range assayed up to 63 per cent Fe. These zones represent the discovery outcrops and surface expression of the McPhee Creek main range iron ore deposit. Follow up sampling, geological mapping, bulldozing of access tracks and ramps and reverse circulation (RC) drilling commenced in September 2009. A maiden Inferred Mineral Resource was announced by Giralia to the Australasian Securities Exchange (ASX) on 15 December 2009. The current Indicated and Inferred Mineral Resource at December 2010 stands at 260 Mt grading 56.2 per cent Fe, 0.12 per cent P, 6.7 per cent SiO2, 2.3 per cent Al2O3 and 9.5 per cent LOI at a 50 per cent Fe cut-off. McPhee Creek is one of the largest iron deposits found in Archaean BIF in the northern Pilbara. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 J D GOLDSWORTHY et al 94 on exploration licence 46/733-I. The company’s tenement package is located on both Vacant Crown Land and the Bonnie Downs pastoral lease. EXPLORATION HISTORY The McPhee Creek region has been subject to prospecting, mining and exploration for over 100 years. The focus of past explorers and prospectors has been predominantly for gold, base metals and asbestos. The Lionel Mining Centre is located 6 km to the south of the McPhee Creek iron deposit where a number of small asbestos (chrysotile) occurences have been mined. The asbestos occurs in layered ultrama f c rocks associated with a complex fault system between the Kelly and McPhee greenstone belts. Further south, copper has been mined at the Lionel and Hendersons copper deposits associated with narrow veins in ultramaf c and gabbroic rocks. To the east, gold has been found in quartz veins at the McPhee’s and Gold Show Hill gold prospects. At Quartz Circle (12 km SE of McPhee Creek, Figure 2) explorers from the 1970s onwards have intersected in drilling, zones of massive and vein associated Cu-Zn-Ag mineralisation in predominantly felsic rocks. The only documented prior iron ore exploration in the area was in 1979 - 1980 when Amoco Minerals Australia Company (Amoco) held an iron ore Temporary Reserve No 7173H which covered an area of 93 km 2 at McPhee Creek. Amoco’s main focus was a small east-west trending Channel iron deposit (CID) mesa where it conducted rock chip sampling, reporting values between 51 per cent and 62 per cent Fe, and shallow vacuum drilling. A total of 22 holes were drilled along a 1350 m long section of the CID mesa with the deepest hole reaching 54 m. The drilling intersected goethite and maghemite enriched pisolites with characteristic fossil wood fragments. Iron enrichment was reported in the top 10 - 14 m of the CID with FIG 1 - Location of the McPhee Creek iron ore deposit with respect to other known iron deposits (and owners) in the region. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 DISCOVERY AND GEOLOGY OF THE MCPHEE CREEK IRON DEPOSIT, NORTHERN PILBARA, WESTERN AUSTRALIA 95 modest grade intersections returned including 12 m @ 53.7 per cent Fe, 10 m @ 53.4 per cent Fe and 14 m @ 51.5 per cent Fe. Amoco conducted minor reconnaissance sampling in the wider area away from the CID mesa including an area in the northwest of the Temporary Reserve (TR), outside Giralia’s current tenure, where ten rock chip samples were described as CID type ore. Seventeen samples were also collected from the southwest of the TR with values returned varying between 43 per cent and 51 per cent Fe. The samples were described as being associated with banded iron formations (BIFs). Amoco concluded that although its assessment of the potential of the TR was not completed due to rugged terrain and unseasonal FIG 2 - McPhee Creek regional geology. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 J D GOLDSWORTHY et al 96 rainfall, its exploration work had not identif ed large tonnages of iron ore (Purkait, 1980) and it subsequently relinquished the TR in 1980. DISCOVERY OF MCPHEE CREEK IRON DEPOSIT In November 2007, exploration licence E46/733-I was granted to Giralia. A review of the GSWA geology maps in particular the Nullagine 1:100 000 sheet revealed the presence in the tenement area of BIFs of the Gorge Creek Group which hosts iron ore deposits elsewhere in the West and East Pilbara Granite-Greenstone Terrane. The GSWA 1:100 000 Nullagine sheet also recorded the small McPhee Creek CID hosted iron occurrence. Research of the GSWA WAMEX database located Amoco’s 1980 McPhee Creek iron exploration report, which documented the vacuum drill testing of the CID mesa and the potential presence of iron enriched BIF’s 2 - 4 km further west. A f eld reconnaissance trip was undertaken in late November 2007 when the CID was visited and sampled. Outcrops of Gorge Creek Group iron formations in the ranges to the west were brie f y inspected, but oncoming bush f res thwarted detailed examination. In 2008, Giralia began exploration by drilling the CID (subsequently named Crescent Moon). A total of 43 RC holes were drilled targeting the central 1.6 km section of the Crescent Moon CID, which was partially tested by Amoco in 1980. The Crescent Moon mesa is an elongate east-west crescent shaped body of channel iron up to 140 m wide. To the west a number of smaller mesas dissected by drainages occur over a combined length of 900 m. Drilling intersected pisolitic, goethite and maghemite-rich CID from surface down to a vertical depth of 16 m; below which a mixture of clayey goethite and chert- silica-rich zone was encountered. At a depth of between 20 - 24 m, a zone of ‘puggy’ white to purple clay was intersected at the base of the channel, with residual clay zones grading into saprolitic basement Archaean ultrama f c rocks below. Assay results from the goethite – maghemite zones (from surface to 8 - 16 m in depth) average >50 per cent Fe; below this point Fe grades are signif cantly reduced. Better intersections included, 14 m @ 55.9 per cent Fe and 12 m @ 55.3 per cent Fe. The drill density at 100 × 50 m spacings and the f at lying continuous nature of the Crescent Moon mesa allowed the estimation of an Inferred Mineral Resource of 5.17 Mt grading 53.6 per cent Fe, 0.03 per cent P, 7.2 per cent SiO 2, 6.1 per cent Al2O3 and 11.3 per cent LOI (Louw, 2008). In late July 2008, a helicopter-supported sampling program was conducted at McPhee Creek. Targets for the survey were: 1. an approximately 8 km long range 2 - 3 km west northwest of the Crescent Moon CID – where newly acquired Ikonos satellite images identi f ed strongly ferruginous outcrops associated with major structures in mapped (BIFs), and 2. reported 1980 Amoco Fe-rich rock chip samples from the area – although their exact location was not known (preGPS). A total of 62 rock chip samples were collected, assaying up to 63 per cent Fe. The samples were taken from haematite-goethite enriched BIF and canga zones outcropping intermittently along the western and central areas of the prominent range. These zones represent the discovery outcrops and surface expression of the McPhee Creek main range iron ore deposit. Outcrop examination of the mineralised zones indicated a northeast strike with shallow to steep southeast dips. After a period of follow up sampling, geological mapping, bulldozing of access tracks and ramps, RC drilling on the main range commenced in September 2009. An initial program of 47 angled RC holes was completed on nominal line spacings of 200 m targeting mineralised outcrops on the western side of the main range. Very encouraging results were obtained from almost every drillhole. Better intersections included 90 m @ 58.6 per cent Fe, 62 m @ 57.3 per cent Fe and 58 m @ 59 per cent Fe. A further drill program commenced in November 2009 and 24 previously permitted angled RC drill holes were completed. The drilling returned similar haematite – goethite rich Fe intersections and con f rmed the continuity of iron ore mineralisation between and along the lines of drillholes. Results from the drilling at this point con f rmed that the mineralisation dipped shallowly to the southeast and extended south into a synformal hinge zone. Based on the f rst 71 drill holes completed, a maiden Inferred Mineral Resource of 52.1 Mt grading 56 per cent Fe, 0.08 per cent P, 6.7 per cent SiO2, 3.2 per cent Al 2O3 and 9.2 per cent LOI was estimated (Louw, 2010a) and announced by Giralia to the ASX on 15 December 2009. Subsequent mineral resource estimates were publicly reported on 26 July 2010 and 9 September 2010, with the current 260 Mt estimate reported on 3 December 2010. On 21 December 2010, Atlas Iron Limited announced an off-market takeover bid for Giralia. REGIONAL GEOLOGY The McPhee Creek deposit is located in the Kelly Greenstone Belt in the southeastern part of the East Pilbara Granite Greenstone Terrane (EPGGT). The Archaean aged greenstone belt consists of volcanic and sedimentary sequences including the Warrawoona Group and the Gorge Creek Group (Figure 2). Unassigned ultrama f c rocks intrude the southern area of the Kelly Greenstone Belt and are mapped as serpentinised metadunites by the GSWA in the Lionel Mining Centre. West of the Kelly Greenstone Belt is the Corunna Downs Granitoid Complex. Abutting to the east is the domal McPhee Greenstone Belt, which is intruded by prominent gabbro, and dolerite dykes. To the south of the McPhee Dome lies sediments of the Mosquito Creek Basin. Unconformally overlying the Kelly Greenstone Belt, Mosquito Creek Basin and the McPhee Dome are sediments and volcanics of the Neo Archaean Fortescue Group. A series of northeast faults occur between the Gorge Creek and Warrawoona Groups in the Kelly Greenstone Belt, and form terrane boundaries between the Gorge Creek Group and McPhee Greenstone Belt on the western margin of the McPhee Dome (Bagas, 2005). MCPHEE CREEK IRON DEPOSIT Geology T he McPhee Creek bedded iron ore deposit lies in the faulted Sandy Creek Syncline within rocks of the Gorge Creek Group. The Gorge Creek Group has an age estimate of c.3020 Ma (Van Kranendonk et al, 2006). The Gorge Creek Group is subdivided into the Farrel Quartzite and Cleaverville Formation. In the McPhee Creek area the Farrel Quartzite consists of banded chert, black carbonaceous shale and siltstone. The Cleaverville Formation, which hosts the McPhee Creek main range deposit, consists of thinly bedded BIF and ferruginous chert. Outcrops of haematite and goethite enriched BIF and canga form the surface expression of the McPhee Creek deposit. The western margin of the deposit is marked by a package of shale and chert and is interpreted to be part of the Farrel Quartzite (Figure 3). The shale-chert sequence appears to be conformable with the BIF, and a similar sequence also underlies the BIF to the east, however in the southeastern area of the main range deposit, east of a prominent northeast trending fault, high magnesium IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 DISCOVERY AND GEOLOGY OF THE MCPHEE CREEK IRON DEPOSIT, NORTHERN PILBARA, WESTERN AUSTRALIA 97 basalt has been intersected in drilling at depth below the BIF. This unit does not outcrop in the near vicinity. A large area of silcrete, which contains fragments of BIF, chert and shale, outcrops in the central area of the range. Further zones of haematite are mapped in the southwest of the range. Structural geology The structure of the McPhee Creek area is dominated by a northeast trending, upright synform and associated folding that is truncated by a northeast trending fault de f ning the eastern edge of the Cleaverville Formation (Noble and Beeson 2010). The upright folding deforms earlier formed recumbent folds. Bedding usually strikes northeast-southwest with moderate dips to both the west and east. Northwest-southeast trending faults, with associated joints, fractures and open folding, overprint and cross-cut the McPhee Creek area (Noble and Beeson, 2010). Early recumbent folding (D1) Detailed geological mapping identi f ed several inclined to recumbent folds in the project area (Figure 4). The folds are tight to isoclinal with transposed limbs and in some cases form intrafolial folds. The recumbent folds are observed at the outcrop scale but not mappable at the project scale. If present however, large recumbent folds would be responsible for substantial thickening and local overturning of the BIF sequence (Noble and Beeson, 2010). Upright folding (D2) North-northeast trending upright folds occur throughout the project area (Figure 5). The folds vary from open to tight and have subvertical to steeply inclined axial planes and plunge moderately to both the northeast and southwest. The overall structure of the McPhee Creek deposit is a large northeast trending upright synform where the east limb has been truncated by the eastern fault zone. The hinge zone of the synform is best observed in the south of the project where it has a shallow plunge to the northeast (approximately 20° towards 042°). The upright folds refold earlier recumbent folding (Noble and Beeson, 2010). FIG 3 - McPhee Creek geological interpretation. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 J D GOLDSWORTHY et al 98 Nor theast trending faults (D1 and D2) A large northeast trending fault zone marks the eastern margin of the range. The fault zone is up to 50 m wide with silicif cation of the host rocks and minor quartz veining and is characterised by strong shearing and variably developed lineations. There is an increase in strain towards the eastern fault with zones of complex folding seen in BIF outcrops just to the west of the fault suggesting the upright and possibly the early recumbent folding are related or contemporaneous with movement along the eastern fault (Noble and Beeson, 2010). Other parallel northeast trending fault zones occur in the north and south of the project (Figure 3). Northwest trending faults and jointing (D3) Cross-cutting the project area and earlier structures is a series of northwest trending faults with associated joints and fractures. The faults have steep dips to the northeast and southwest and appear to be responsible for a number of breaks and offsets in the iron ore mineralisation. Iron ore mineralisation Goethite-haematite iron ore mineralisation on the main range at McPhee Creek is hosted in BIF and in ferruginous laterite/canga. Mineralised outcrops occur along almost the entire western margin of the BIF (approximately 8 km) near the contact with underlying shale and chert. Outcropping mineralisation is also present in the south of the project in the position of the synformal hinge zone. Iron ore mineralisation is predominantly stratabound and follows the dip of the bedding – however in some areas, particularly in the southwest of the deposit, mapped steep to moderate dips of bedding planes are at odds with underlying f at mineralised zones in drill sections (Figure 6), indicating near surface supergene enrichment of the iron rich BIF. This supergene remobilisation and enrichment has created mineralised domains orientated subparallel to a now partially dissected palaeosurface, evident in the distribution of the canga – ferruginous laterite. This style of mineralisation maybe akin to ‘crustal ores’ that occur in the Nimingarra – Shay Gap – Yarri deposits in the northeast Pilbara (Podmore, 1990). Areas within the deposit that contain substantial thickness of iron ore (drill intersections include 154 m @ 57.8 per cent Fe) correspond toareas of complex folding suggesting structural control and iron enrichment in fold hinges. Northeast trending faults bound and offset the iron ore mineralisation. The major eastern fault zone bounds the (A) (B) FIG 4 - Recumbent folding: (A) small recumbent folds (203226 mE, 7612937 mN); (B) view to southeast of west verging recumbent folds (201256 mE, 7609719 mN). FIG 5 - Upright folding. Large upright synform. View looking to the north (photo taken from 201505 mE, 7609948N). IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 DISCOVERY AND GEOLOGY OF THE MCPHEE CREEK IRON DEPOSIT, NORTHERN PILBARA, WESTERN AUSTRALIA 99 eastern extent of mineralisation. Another northeast fault in the south of the deposit bounds and offsets the western mineralised zone. Other breaks in the deposit correspond to mapped and inferred northwest trending faults (Figure 3). Petrography Petrographic and mineragraphic analyses of a number of samples of PQ drill-core from various locations within the McPhee Creek main range deposit indicate that most samples FIG 6 - Geological cross-sections through the McPhee Creek Deposit. Sections show measured dip and dip directions along the drill section lines. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 J D GOLDSWORTHY et al 100 are strongly goethite rich with goethite up to 90 per cent (Teale, 2011). Goethite occurs in many textural styles and habits. It can be massive, banded, colloform to botryoidal and pseudomorphous after martitised magnetite (Figure 7). The martitised magnetite is observed occurring in bands intercalated with goethite only or goethite-haematite bands (Teale, 2011). The magnetite is interpreted as a signi f cant component of the original primary BIF. In some samples goethite is intercalated with lepidocrocite in colloform, rhythmically banded aggregates. Lepidocrocite dominates in some samples (Teale, 2011). The haematite occurs as described above in relict martitised magnetite as earthy aggregates, as platy to bladed grains, as coarse angular grains and micro-veins cutting goethite. Wherever present, haematite is ‘cemented’ by goethite (Teale, 2011) The petrographic analysis indicates that the McPhee Creek main range deposit is a strongly supergene enriched iron deposit, with several phases of enrichment of the BIF evident. Current resource Subsequent to the initial Inferred Mineral Resource announced in December 2009, exploration drilling has been ongoing. The current Mineral Resource at 3 December 2010 stands at 260 Mt grading 56.2 per cent Fe, 0.12 per cent P, 6.7 per cent SiO2, 2.3 per cent Al2O3 and 9.5 per cent LOI at a 50 per cent Fe cut-off (Louw, 2010b) based on 361 RC holes and three diamond drill holes and is classi f ed as Indicated and Inferred (Table 1). The resource was estimated by CSA Global Pty Ltd using Ordinary Kriging with model block sizes of 20 m × 20 m × 5 m with subcells down to 4 m × 4 m × 2 m. The majority of samples were collected as 2 m composites; the modelled mineralisation was grouped into zones bounded by interpreted structures for statistical analyses. The results of the grade estimation were validated by means of visual comparison along sections, statistical analyses and trend plots comparing the estimated block grades and drill hole sampling grades (Louw, 2010b). A bulk density of 3.1 t/m 3 was applied to the mineralised zones based on analyses of results of 48 density measurements taken from within mineralised zones DEVELOPMENT PLAN Giralia commissioned Promet Engineering Consultants (ProMet Engineers Pty Ltd, 2010) to prepare a scoping study for the McPhee Creek project in early 2010, soon after the de f nition of the maiden JORC resource of 52.1 Mt in December 2009. A start-up mining rate of 2 Mt/a was selected as the Base Case based on public road haulage (approximately 265 km) to Port Hedland, with the current 260 Mt resource clearly able to support signif cantly higher mining rates. A number of variations on the base case mining, processing and transport options were considered, with superior f nancial model results returned from alternatives incorporating increased production rates and private haul roads or rail (A) (B) (C) (D) FIG 7 - Photomicrographs – refl ected light: (A) colloform and botryoidal goethite containing intercalations of lepidocrocite (white); (B) colloform banded goethite with coarse grained acicular goethite crystals perpendicular to banding; (C) goethite, haematite and martitised magnetite (former BIF with greater than 20 per cent magnetite); (D) goethite pseudomorphing martitised magnetite surrounded by haematite (white) and goethite. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 DISCOVERY AND GEOLOGY OF THE MCPHEE CREEK IRON DEPOSIT, NORTHERN PILBARA, WESTERN AUSTRALIA 101 spurs linking to third party rail. The scoping study indicated that the McPhee Creek project has potential for attractive returns under a number of different development scenarios. Further drilling, metallurgical test work and environmental studies as part of a prefeasibility study are needed to con f rm these results, to enable selection of the optimum development model. CONCLUSIONS The McPhee Creek bedded iron ore deposit in the northern Pilbara has progressed rapidly from the f rst identif cation of mineralised outcrops in late 2008, to the delineation of the current resource of 260 Mt just over two years later. The iron ore enrichment at McPhee Creek is similar to the haematite-goethite mineralisation of other documented iron deposits in the Archaean east and west Pilbara Granite- Greenstone Terrain. However, at McPhee Creek main range the combination of moderately dipping stratigraphy and low angle plunging folds cut by near vertical structures is interpreted to have enhanced the enrichment process and created exceptionally thick zones of relatively f at-lying, near- surface mineralisation. ACKNOWLEDGEMENTS The authors wish to acknowledge the hard work of the f eld and off ce personnel of Giralia Resources NL, consultants CSA Global Pty Ltd and Jigsaw Geoscience Pty Ltd. REFERENCES Bagas, L, 2005. Geology of the Nullagine 1:100,000 sheet, 33 p, Western Australia Geological Survey, 1:100,000 Geological Series Explanatory Notes. Louw, G, 2008. Crescent Moon Mineral Resource Estimate Summary Report, unpublished consulting report for Giralia Resources NL, CSA Global Pty Ltd. Louw, G, 2010a. McPhee Creek Mineral Resource Report, unpublished consulting report for Giralia Resources NL, CSA Global Pty Ltd. Louw, G, 2010b. McPhee Creek Mineral Resource Estimate, Technical Summary, unpublished consulting report for Giralia Resources NL, CSA Global Pty Ltd. Noble, M and Beeson, J, 2010. Observations and results of geological mapping in the McPhee Creek project, Pilbara Region, Western Australia, Australia, unpublished consulting report for Giralia Resources NL, Jigsaw Geoscience. Podmore, D C, 1990. Shay Gap-Sunrise Hill and Nimingarra iron ore deposits, in Geology of the Mineral Deposits of Australia and Papua New Guinea (ed: F E Hughes), pp 137-140 (The Australasian Institute of Mining and Metallurgy: Melbourne). ProMet Engineers Pty Ltd, 2010. McPhee Creek Iron Ore Project – Scoping Study, unpublished consulting report for Giralia Resources NL. Purkait, P K, 1980. Final report McPhee Creek, Temporary Reserve 7173, Western Australia, GSWA open f le report item 1312, A9416. Teale, G S, 2011. A mineragraphic investigation of a suite of drill-core samples from the McPhee Creek iron deposit, Western Australia, Teale and Associates, unpublished consulting report for Giralia Resources NL. Van Kranendonk, M J, Hickman, A H, Smithies, R H, Williams, I R, Bagas, L and Farrell, T R, 2006. Revised lithostratigraphy of Archaean supracrustal and intrusive rocks in the northern Pilbara Craton, Western Australia: Western Australia Geological Survey,Record 2006/15, 57 p. Deposit cut-off grade Category Tonnes (Mt) Fe % P % SiO 2 % Al 2 O 3 % LOI% Fe calcined % Total >50% Fe Indicated 65.3 56.3 0.11 6.2 2.6 9.7 62.3 Total >50% Fe Inferred 194.7 56.2 0.13 6.9 2.2 9.4 62.1 Total >50% Fe Combined 260 56.2 0.12 6.7 2.3 9.5 62.1 TABLE 1 Mineral resource estimate – results for McPhee Creek deposit. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 103 INTRODUCTION The McCamey’s North project is located 50 km east of Newman and just 3 km from the Jimblebar Mine (Figure 1). The project is wholly contained within the exploration Lease E52/2303 (the tenement), which was granted to Warwick Resources Ltd on 2 November 2009. During December 2009, Warwick Resources Ltd and Atlas Iron Limited (Atlas) successfully merged. To date 38.9 Mt of haematite-martite and goethite iron mineralisation has been identi f ed within the Boolgeeda Iron Formation at McCamey’s North. The Boolgeeda Iron Formation stratigraphy is well exposed in the southern portion of the tenement but disappears beneath colluvial and alluvial cover to the north. Atlas commenced exploration at McCamey’s North in December 2009, with 1:10 000 scale mapping and rock chip sampling. Drilling commenced in August 2010 with 184 reverse circulation drill holes totalling 16 886 m drilled as of 3 February 2011, when a maiden inferred resource was released (Table 1). Drilling has been completed at 50 m centres on 100 - 200 m spaced lines (Figure 2). Previous work in the area includes the GSWA 1:250 000 Robertson Sheet SF51-13 (Williams and Tyler, 1991); which shows the tenement area as being dominated by north-dipping 1. MAusIMM, Senior Exploration Geologist, Atlas Iron Limited, Level 9, Alluvion, 58 Mounts Bay Road, Perth WA 6000. Email: Paul.Howard@atlasiron.com.au 2. Exploration Manager, Atlas Iron Limited, Level 9, Alluvion, 58 Mounts Bay Road, Perth WA 6000. Email: Pip.Darvall@atlasiron.com.au Realising the Potential of the Boolgeeda Iron Formation – Stratigraphy and Iron Mineralisation at McCamey’s North, Hamersley Province, Western Australia P J Howard1 and P Darvall2 ABSTRACT Atlas Iron Limited’s McCamey’s North project lies at the eastern end of the Hamersley Basin, approximately 50 km east of Newman, Western Australia, and 3 km northeast of BHP Billiton’s Jimblebar Mine. The presence of signi f cant surface iron mineralisation identi f ed during f eld reconnaissance, has subsequently been further def ned by detailed mapping and RC drilling. The project area is dominated by outcrops of moderate to steeply north and south dipping banded iron formation, cherts and shales of the Boolgeeda Iron Formation overlying rhyolites and rhyodacites of the Woongarra Volcanics. In lower lying areas recent colluvium and alluvium mask the Archaean geology. Drilling and downhole geophysics has allowed a composite stratigraphic section to be compiled through almost the entire Boolgeeda Iron Formation. Surface orientations and subsurface stratigraphic correlations using natural gamma logs indicate large scale open folding about east-west trending fold axes across the project area; while small scale tight to isoclinal folding with similar fold axis orientations are visible at the outcrop scale. These folds are cut by a number of moderate to steeply south-dipping normal faults de f ning a series of north-dipping fault blocks which repeat the stratigraphy across the project area. Bedded iron mineralisation consists mainly of haematite-martite and goethite ores with best results of 78 m @ 60.5 per cent Fe. Vitreous goethite is observed at the surface of the mineralised horizons. The mineralisation exhibits a strong stratigraphic control and extend down-dip up to 120 m below surface. The strike extent of the mineralisation is still to be determined. An inferred resource of 39 Mt at 58 per cent Fe has been def ned to date (ASX: AGO 3 February 2011). The f ndings at McCamey’s North indicate that there is potential for economic iron mineralisation to exist in other areas of Boolgeeda Iron Formation within the Hamersley Basin. Class Mt Grade % Fe SiO 2 Al 2 O 3 P LOI S Inferred 38.9 57.96 4.94 4.81 0.169 6.27 0.012 Fifty-three per cent fe cut-off . TABLE 1 McCamey’s North Inferred Resource – February 2011. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 P J HOWARD AND P DARVALL 104 units of the Archaean-Proterozoic Woongarra Volcanics and the Boolgeeda Formation extending north under Recent cover material. Also visible on the 1:250 000 mapping are a signif cant number of northeast trending faults extending onto the tenement area from the vicinity of the Jimblebar iron ore mine. Such structures (including the Whaleback and nearby Wheelarra Faults) are regarded as important in controlling the location of iron enrichment in the Newman area (eg Kneeshaw, 2004). REGIONAL SETTING The McCamey’s North project is located at the eastern end of the Hamersley Province, Western Australia (Figure 1). Archaean granitoid-greenstone sequences of the Sylvania Inlier, the Fortescue Group and Hamersley Group successions dominate the region (Tyler, 1991), covered by Quaternary and Recent cover. Up to f ve deformation events have been recognised across the Hamersley Province, with the Capricorn and Ashburton Orogenies being the main episodes in the southern part of the Province (Tyler, 1991; Kneeshaw, 2004). In this southern region of the Hamersley Province the Capricorn or Ophthalmian Orogeny is characterised by south over north directed thrusting and folds with tight inter-limb angles and southerly dipping fold axes. The later Ashburton Orogeny is characterised by large-scale, upright E-W trending folds that def ne the regional outcrop pattern. Approximately 6 km south of the tenement area, granitic basement of the Sylvania Inlier is unconformably overlain by volcanic and sedimentary units of the Archaean Fortescue Group, conformably overlain by the entire Hamersley Group succession. The Hamersley Group stratigraphy dips and youngs to the north, with only the uppermost units; the Woongarra Volcanics and Boolgeeda Iron Formation (‘Boolgeeda’) exposed in the tenement area (eg Tyler, 1991; Williams and Tyler, 1991). STRATIGRAPHY A schematic stratigraphic column for the McCamey’s North project is presented in Figure 3. Woongarra Volcanics Units correlated with the Archaean Woongarra Volcanics form the lowermost stratigraphic unit encountered at McCamey’s North. These volcanics are seen to outcrop along the southern margin of the project area and where uplifted in normal fault blocks in the central portion of the tenement (Figure 2). This unit consists of approximately 300 m of massive to locally f ow banded rhyolite and rhyodacite, with several 1 - 5 m thick jaspilitic banded iron-formation (BIF) and chert horizons and discontinuous 2 - 5 m thick dolerite sills in the central portion. The felsic units typically have a pale orange to brown microcrystalline groundmass with 1 - 2 per cent 1 - 2 mm euhedral phenocrysts of feldspar ± quartz. A f nely layered tuffaceous unit was observed in one location suggesting an extrusive origin for at least some of the unit. The reported thickness for the Woongarra Volcanics in the area is 260 m (Williams and Tyler, 1991). Boolgeeda Iron Formation Conformably overlying these volcanic units is a package of BIF, cherts and shales of the Boolgeeda Iron Formation, which dominate the project area. Immediately overlying the Woongarra Volcanics are 5 - 10 m of chaotically folded and brecciated BIF, commonly jaspilitic (see BG1); overlain in turn by a f nely laminated, blocky chert and BIF unit approximately 50 m thick, and 30 - 40 m of calcareous/dolomitic shales capped by ochreous goethite and calcrete. A series of cherts, BIF and shales make up the remainder of the unit, with an estimated overall thickness of 250 m. A total thickness of up to 340 m has been inferredFIG 1 - McCamey’s North location plan, surrounding geology and infrastructure. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 REALISING THE POTENTIAL OF THE BOOLGEEDA IRON FORMATION – STRATIGRAPHY AND IRON MINERALISATION AT MCCAMEY’S NORTH, WA 105 for the Boolgeeda Formation in this location. Williams and Tyler (1991) give an approximate thickness of 200 m but acknowledge the top of the formation was not observed. A 254 m composite stratigraphic drill hole through a large part of the Boolgeeda Iron Formation at McCamey’s North has allowed the identi f cation of 11 distinct units (BG1-11) as outlined in Figure 3. The lowermost two units were not intersected in drilling and are based on f eld mapping only, while the remainder were intersected in RC drilling and extensive downhole natural gamma data. A combination of geological logging, assay interpretation and downhole geophysics, have allowed these units to be correlated across the project area. The following is a more detailed description of the 11 units outlined in Figure 3 and discussed above: BG1 – brecciated and chaotically folded BIF. This 5 - 10 m thick unit is a distinct marker horizon and will be referred to as a jaspilite for it exhibits a brilliant red haematite banding, interbedded with a white silica rich chert, very different to the other BIF horizons seen within the Boolgeeda at McCamey’s North. BG2 – blocky chert and BIF unit approximately 50 m thick. BG3 – a shaley-BIF; the lowermost unit encountered in drilling, displaying an increased silica and alumina geochemical signature and has been logged as thinly laminated BIF interbedded with shale. Iron values are generally 35 - 40 per cent within this unit. It has an estimated total thickness of 40 m, although only 15 m of this unit was intersected in drilling. BG4 – logged as an oxidised BIF where magnetite has been oxidised to martite. This commonly mineralised unit is up to 70 m thick with iron mineralisation consistently above 62 per cent. Increased shale bands towards the base of this unit decreases iron values to ~57 per cent for the lowermost 20 m. BG5 – this thin shale unit is approximately 10 m thick and is high in alumina (7 - 12 per cent Al 2O3). It has a cream/ beige, f ne grained appearance with minor fragments of silica present. BG6 – A 20 m thick BIF with numerous thin interbedded shale and chert bands showing up in the ‘high background’ natural gamma log. BG7 – is a 40 m thick cherty-shale band. This unit has been correlated with a green chert zone mentioned by Kneeshaw (2004). It is easily recognisable in drilling and is a useful marker horizon throughout the project area. BG8 – a 20 m shaley-BIF unit, logged as interbedded haematite-goethite and shale. Alumina is elevated through this unit and iron values are typically 53 - 54 per cent. Minor jaspilite bands are common; red and rich in silica. BG9 – a 30 m thick BIF unit, with little or no interbedded shale and chert bands, and a very ‘clean (low background)’ natural gamma log, which indicates that this BIF is not a structural repetition of BG4. Commonly exhibiting strong iron enrichment to haematite-martite. BG10 – similar to BG8, this 20 m shaley-BIF is mineralised and could be bene f ciated. Geochemical and natural gamma signatures differ enough to conclude that this unit is not a structural repetition of BG8. BG11 – is the uppermost Boolgeeda Iron Formation unit encountered at McCamey’s North. It is a f ne grained yellow/orange shale with a thickness of at least 35 m thick. The top of this unit has not yet been identif ed. Quaternary and recent sediments At McCamey’s North, the more resistant units of the Boolgeeda Iron Formation form low, east-west trending ridges, with lower lying shalier areas (BG9) are blanketed in Quaternary colluvium and alluvium. The colluvium, consisting of FIG 2 - Geological map of the McCamey’s North Project. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 P J HOWARD AND P DARVALL 106 FIG 3 - Schematic stratigraphic column for the McCamey’s North project. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 REALISING THE POTENTIAL OF THE BOOLGEEDA IRON FORMATION – STRATIGRAPHY AND IRON MINERALISATION AT MCCAMEY’S NORTH, WA 107 subangular to subrounded fragments of adjacent lithologies, typically drapes the lower portions of slopes. Alluvium occurs as well sorted, f ne grained sands and soils along the margins of the present Jimblebar Creek drainage. STRUCTURE Units at McCamey’s North strike generally east-west, swinging to a more northwest-southeast orientation at the eastern extent of the project area. The exposed ridges towards the south exhibit a moderate to steep dip to the north, while isolated ‘islands’ of outcrop among the Quaternary cover in the north display a moderate to steep dip to the south. Natural gamma logs from numerous downhole surveys, coupled with assay and geological interpretation, support the surface observations, which def ne an open syncline/anticline pair (Figure 4). Numerous small-scale, tight to isoclinal folds are also visible at the outcrop scale. Brittle deformation represented by large-scale normal faults with up to 350 m of offset are also seen throughout McCamey’s North. These east-west trending, south dipping, normal faults expose the underlying Woongarra Volcanics (Figure 4). The monotonous nature of the Boolgeeda outcrop (no obvious marker horizons) means that there may be several other similarly oriented smaller scale faults not noted at the scale of mapping. These faults may be observed in diamond drilling or more detailed prospect scale mapping. The change in strike orientation across the project area, mentioned above, is interpreted to be due to a younger, northeast trending dextral strike-slip fault cutting the prospect at the location of the Jimblebar Creek. Offset across this fault is inferred to be approximately 200 m. MINERALISATION We have de f ned iron mineralisation at McCamey’s North as material with greater than 53 per cent Fe and consists of haematite-martite and goethite ores. The high-grade mineralisation (~60 per cent Fe) is generally limited to the upper (BG9) and lower (BG4) BIF units (Figure 3) with the thinner middle (BG6) BIF unit containing subeconomic DSO grade material (45 - 53 per cent Fe). Table 2 contains some of the better intercepts from McCamey’s North. The lower BIF unit (BG4) is overlain by barren shales and is approximately 70 m thick. Mineralisation extends to depths greater than 120 m below surface. The upper BIF (BG9) is bound by mineralised shaley-BIF. These shalier units are approximately 20 m thick but have a higher alumina content of 7 - 12 per cent than the high grade unit, which is approximately 30 m thick and has an alumina content of three to six per cent. The bedded haematite-martite ore is capped by a goethite- rich hydrated zone. The ore exhibits a tight stratigraphic control and is open at depth towards the core of the interpreted syncline. Iron mineralisation at surface is characterised by siliceous or vitreous goethite with minor ochreous goethite and clay, and vuggy and breccia textures. There are also minor detrital/ canga outcrops at the base of slopes. These outcrops comprise angular to subangular ore clasts in a haematitic clay matrix (Archer, 2009; Darvall, 2010). At depths of up to 120 m below surface the mineralisation appears as dense haematite-martite ore. Dark grey/ blue haematite and chocolate brown goethite alternate in mineralised bands of varying thicknesses ranging from 1 cm to 15 m. Conchoidal fracturing is apparent on larger goethite chips. DISCUSSION These f ndings show that the Boolgeeda Iron Formation holds signi f cant potential for economic iron mineralisation at McCamey’s North and throughout the Hamersley Basin. Further work to extend the current resource via RC and diamonddrilling, and more detailed prospect scale mapping will aid in unravelling the structural complexities of McCamey’s North. The available data suggests a much thicker Boolgeeda Iron Formation section than previously documented. However, there is a strong possibility that some structural thickening of the section has occurred. The additional work planned will enable this to be con f rmed or otherwise. A more comprehensive and detailed stratigraphic and natural gamma section for the unit will be compiled once the information becomes available. FIG 4 - Schematic cross-section on 212850mE at the McCamey’s North project. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 P J HOWARD AND P DARVALL 108 CONCLUSIONS Extensive exploration completed to date at the McCamey’s North project has resulted in the de f nition of signi f cant Boolgeeda Iron Formation-hosted Fe mineralisation. Additional work designed to test the undercover potential has commenced and will assist in an even more detailed understanding of the stratigraphy and potential of the Boolgeeda as a whole across the Hamersley Province. ACKNOWLEDGEMENTS The authors wish to acknowledge the valuable contributions made by the entire Atlas Iron Exploration team and in particular Steve Warner who contributed signi f cantly to the development of the geological model. The shareholders, Board and Management at Atlas are acknowledged for their ongoing support of Exploration activities and the production of this paper. REFERENCES Archer, D A, 2009. McCamey’s North Project – DSO potential initial f eld review, Warwick Resources consultant report, internal company report, pp 9-13. Darvall, P, 2010. McCamey’s North mapping report, Atlas Iron Limited, internal company report, pp 3-5. Kneeshaw, M, 2004. Guide to the Geology of the Hamersley and North East Pilbara Iron Ore Provinces (‘The Blue Book’) (BHP Billiton Iron Ore Exploration Western Australia). Tyler, I M, 1991. The Geology of the Sylvania Inlier and the Southeast Hamersley Basin (Geological Survey of Western Australia: Perth). Williams, I R and Tyler, I M, 1991. Robertson 1:250 000 Sheet SF51- 13 (Geological Survey of Western Australia: Perth). Hole_Id mFrom mTo Intercept (Fe %) SiO 2 % Al 2 O 3 % P % S % LOI % JMRC044 36 92 56 m @ 58.61 % 3.36 3.77 0.21 0.01 8 JMRC052 18 68 50 m @ 60.26 % 3.08 4.2 0.17 0.01 5.56 JMRC058 16 94 78 m @ 60.50 % 2.25 4.49 0.18 0.01 5.67 JMRC064 0 78 78 m @ 59.02 % 5.1 4.04 0.15 0.01 5.36 JMRC065 24 76 52 m @ 60.03 % 4.14 4.62 0.13 0.01 4.52 JMRC144 46 120 74 m @ 59.82 % 3.63 4.58 0.19 0.01 5.33 JMRC208 18 86 68 m @ 59.76 % 3.75 4.71 0.2 0.01 5.09 JMRC209 64 128 64 m @ 61.69 % 2.33 4.05 0.2 0.01 4.6 JMRC210 48 114 66 m @ 58.92 % 3.77 4.56 0.2 0.01 6.29 JMRC221 4 64 60 m @ 58.94 % 4.53 4.35 0.15 0.01 5.79 JMRC228 20 70 50 m @ 57.36 % 5.26 5.56 0.2 0.01 5.87 JMRC229 52 108 56 m @ 57.81 % 5.4 5.03 0.18 0.01 5.84 Fifty-three per cent Fe cut-off , 2 m max internal waste. TABLE 2 Best intercepts at McCamey’s North as of February 2011. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 109 INTRODUCTION Geophysics assists iron ore exploration where the effect of the varying physical properties of the rocks can be detected in a geophysical measurement. Iron ore deposits may be strongly, weakly or non-magnetic. They may or may not be electrically conducting or associated with electrically conductive or polarisable rocks. Generally, however, they can be relied on to have a positive density contrast and, consequently, gravity techniques are valuable in iron ore exploration. Historically, many iron ore deposits have been discovered as a result of their extensive outcrop combined with relatively thin soil cover and sparse vegetation (Blockley, Reid and Trendall, 1990; Morris, 1998). Undiscovered outcropping deposits may still exist but the growth in demand and the preference for deposits near existing infrastructure means that there is growing opportunity for discovery under cover using geophysics (Butt, Hawke and Flis, 2001). In the past, ground gravity has been used but very good quality terrain corrections are required (Flis, Butt and Hawke, 1998) and this is dif f cult in the generally rugged terrains associated with iron ore provinces. In any case, it is slow and laborious to collect. Airborne gravity gradiometry has been used since late 1999. This offers the advantages of rapid and complete coverage, excellent terrain corrections if light detection and ranging (LIDAR) data are collected simultaneously, and, usually, coincident aeromagnetics. DEPOSIT STYLES The iron ore mineral fact sheet (Geoscience Australia, 2010b) says: In the Hamersley Province in the Pilbara district of Western Australia there are three main types of deposit: iron oxide enrichments within BIFs; iron oxides deposited along ancient, mainly Tertiary age river channels (palaeochannels); and iron oxide deposits formed from the erosion of existing orebodies (detrital iron ore deposits). BIF enrichment iron ore deposits can be split into three broad groups comprising leached BIF, haematite-goethite and martite-microplaty haematite. However, leached BIF deposits tend to be found in areas of high rainfall, such as Brazil and India, and not the arid Hamersley Basin where the 1. Senior Geoscientist, Fugro Airborne Surveys Pty Ltd, 435 Scarborough Beach Road, Osborne Park WA 6017. Email: rmiller@fugroairborne.com.au 2. Chief Geophysicist, Fugro Airborne Surveys Pty Ltd, 435 Scarborough Beach Road, Osborne Park WA 6017. Email: mdransfi eld@fugroairborne.com.au Airborne Gravity Gradiometry and Magnetics in the Search for Economic Iron Ore Deposits R Miller1 and M Dransfi eld2 ABSTRACT The enrichment of magnetite to haematite and haematite-goethite leads to a coincident magnetic low and gravity high within the banded iron formation. Palaeochannel deposits of pisolitic limonite can be expected to provide a relative magnetic high and gravity low in a sinuous geometry. Detrital iron deposits of conglomerate, scree or ‘canga’ might have indistinct magnetic response but will usually have a relative gravity high. These signatures provide clear discriminators detectable by a joint gravity and magnetic survey. The combination of airborne gravity gradiometry and magnetometry is particularly powerful in detecting and discriminating targets, as well as mapping lithologies and structure, across a wide variety of iron ore deposit styles. It provides detection capabilities in a platform capable of rapid, complete coverage with minimal access issues. This approach has been used in FALCON™ airborne surveys for iron ore exploration in the Great Lakes, USA; the Middleback Ranges, South Australia; and the Hamersley Basin, Western Australia. The complex magnetic properties of iron formations (particularly remanence, anisotropy and depth of weathering) prevent this approach from being simple. The use of vector residual magnetic intensity (VRMI), calculated from the measured total magnetic intensity (TMI), assists by reducing the complexity due to the different directions of the remanent and induced magnetic f elds. Estimations of the density to magnetisation ratio via the pseudo-lithology calculated from the VRMI and gravity gradients provide a useful method of capturing the discriminatory power of joint magnetic and gravity gradient data. IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 R MILLER AND M DRANSFIELD 110 principal deposits (eg Mount Whaleback, Yarrie, Mount Tom Price, Paraburdoo, Channar) are of the supergene enrichment haematite-goethite and martite-microplaty haematite style (Blockley, Reid and Trendall, 1990; Blockley, 1990; Morris, 1998). The martite-microplaty haematite ore type is particularly important in regard to resources and production as a result of the low phosphorous content often preferred for export specif cations (Morris, 1998). Extensive discussionsof the formation of supergene BIF enrichment deposits in the Hamersley Basin can be found in literature (eg Blockley, Reid and Trendall, 1990; Blockley, 1990; Morris, 1998) and a detailed discussion will not be presented here. However, it has been shown that supergene enrichment of BIF and, in some cases, subsequent burial metamorphism is the only mechanism that can explain the available data (Morris, 1998). Haematite-goethite ore is produced by the oxidation of magnetite and metasomatic replacement of gangue minerals by goethite. Continual groundwater leaching or surface exposure can modify this ore producing a range of different ore types, from porous to extremely dense. This type of Mesozoic aged, non-metamorphosed ore constitutes over 90 per cent of the resources in the Hamersley Province (Morris, 1998). The high-grade ores, such as Mount Tom Price and Mount Whaleback, are thought to have been buried at a depth of approximately 4 km, resulting in low grade metamorphism and generating haematite-rich ores from goethite. A second stage of groundwater leaching, resulting from erosion in the Mesozoic, removed the bulk of the residual goethite leaving high-grade, low phosphorous, haematite ore (Morris, 1998). Channel iron deposits (CIDs) or palaeochannel deposits comprised of pisolitic limonite (eg Pannawonica (Mesa A and Mesa J), Yandicoogina) are the next in importance. The CIDs formed in predominantly Early to mid-Tertiary palaeochannels with the concentration of possible Oligocene to Miocene aged f uvial iron particles from weathered iron- rich source rocks (Ramanaidou, Morris and Horwitz, 2003). The palaeochannels typically occur as mesas or benches preserved by preferential weathering (Blockley, Reid and Trendall, 1990; Blockley, 1990; Ramanaidou, Morris and Horwitz, 2003) and though deposits range from <1 m to 100 m thick with channel widths generally less than 1 km they can extend for several kilometres, the CID of the Robe River Formation (formerly the Robe Pisolite) can be traced for 80 km along the Marillana palaeochannel near Yandi (Blockley, 1990; Ramanaidou, Morris and Horwitz, 2003). Whilst regionally iron concentration ranges from 40 - 60 per cent Fe, mining is generally restricted to deposits of anomalously high Fe, averaging 57 - 58 per cent (Blockley, 1990). Although the iron concentration tends to be lower than that of enrichment ores, low impurities (particularly phosphorous), lack of cementation, and shallow depth of burial make CIDs attractive targets. Detrital iron ore deposits (eg Brockman Syncline No 2 Deposit, Brockman Southwest Extension), composed of deposits of conglomerate, scree and ‘canga’, are derived from, and are usually found close to, enriched BIF deposits (Blockley, Reid and Trendall, 1990; Butt, Hawke and Flis, 2001). Leaching f uids that result in the ferruginisation of the matrix also tend to reduce the phosphorous content, making this type of deposit more attractive than it would otherwise be (Blockley, Reid and Trendall, 1990; Butt, Hawke and Flis, 2001). Butt, Hawke and Flis (2001) present a geological cross- section through Brockman Syncline No 2 Deposit Pit 5 showing a sequence of immature detrital material (partially cemented, poorly sorted subangular clasts of predominantly BIF, chert and haematite) overlying and masking the underlying mature detritals. These mature deposits tend to be subrounded to rounded clasts of predominantly haematite with minor BIF and chert in a matrix of ferruginous clay. Pisolites are identif ed by a higher proportion of ‘small ball-bearing type clasts’ in comparison to the mature detritals. ‘Canga’ is comprised of cemented detrital haematite clasts forming a hard rock at the base of the detrital material whilst a thin basal layer of limonite (mainly hydrated ‘canga’) separates the deposit from the underlying hydrated bedrock. GEOPHYSICAL SIGNATURES OVER KNOWN IRON ORE DEPOSITS One of the earliest geophysical successes in Australia was the discovery by gravity and magnetic surveys of the buried Iron Princess (Race Course) deposit in the Middleback Ranges (Bubner et al , 2003). The same authors note that the ‘iron formations in the Middleback Ranges are both dense and highly magnetic when compared with other lithologies in the area’ but the ‘iron ores are in general denser, but less magnetic, than the iron formation’. Examples of the geophysical responses over iron ore regions and known iron ore deposits can be found in a number of publications (eg Dentith, Frankcombe and Trench, 1994; Kerr et al, 1994; Hawke and Flis, 1997; Flis, Butt and Hawke, 1998; Flis, Hawke and McMillan, 1998; Butt, Hawke and Flis, 2001; Bubner et al , 2003; Dentith, 2003). These examples predominantly discuss the results of magnetic or gravity surveys though Hawke and Flis (1997) discuss the application of electrical techniques for exploration in the Hamersley Basin and Flis, Hawke and McMillan (1998) present results from a helicopter-borne frequency domain electromagnetic survey. Regional mapping is extremely important for exploration and airborne magnetic data can be used to map the structural and stratigraphic controls on mineralisation, providing targets for more detailed exploration (Dentith, Frankcombe and Trench, 1994; Kerr et al , 1994; Morris, 1998; Bubner et al, 2003). The host iron formations tend to be the most magnetic units present, the iron ores being much less magnetic (Bubner et al, 2003). As a result mineralisation can sometimes be associated with magnetic lows within an otherwise high amplitude background (Dentith, Frankcombe and Trench, 1994; Kerr et al , 1994; Bubner et al , 2003). However, identifying such responses can be dif f cult due to the large dynamic range usually present in the data, requiring careful processing to enhance the subtle features that might be present (Kerr et al , 1994), whilst anisotropic magnetic susceptibilities and the effects of remanence can further complicate the response (Dentith, Frankcombe and Trench, 1994). Magnetic responses can also be dependent on the depth of weathering as haematite is the dominant iron oxide in the weathered zone with magnetite dominating below it (Bubner et al, 2003). The iron formations are generally remanently magnetised and the varying direction of this magnetisation with respect to the induced magnetisation means that the same formation can have a positive, negative or zero magnetic intensity as the formation’s orientation changes. Iron ores tend to be the densest materials present, and in general the presence of dense haematite ore makes gravity an attractive exploration tool (Morris, 1998; Bubner et al, 2003) with positive gravity anomalies anticipated over signi f cant IRON ORE CONFERENCE / PERTH, WA, 11 - 13 JULY 2011 AIRBORNE GRAVITY GRADIOMETRY AND MAGNETICS IN THE SEARCH FOR ECONOMIC IRON ORE DEPOSITS 111 orebodies. In the BIF-enrichment deposit style, the density of iron formation host rocks can overlap with that of the orebodies so that the gravity method is a good detector but can be limited as a discriminator. Thus the combination of magnetic and gravity data are particularly important in exploration for the enriched BIF style of mineralisation. Buried palaeochannel deposits of pisolitic limonite can be expected to provide a relative magnetic high and gravity low in a typical sinuous geometry. Detrital iron deposits (DIDs) of conglomerate, scree or ‘canga’ are considered to have an indistinct magnetic response but a relative gravity high (Butt, Hawke and Flis, 2001). Underlying geology can further complicate the geophysical response. Butt, Hawke and Flis (2001) describe the discovery of a detrital iron orebody using gravity. The application of airborne gravity gradiometry technology to iron exploration provides several advantages in comparison with current gravity data. Ground access is limited by the rugged terrain